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Separate production of hydrogen and methane from biodiesel wastewater with added glycerin by two-stage anaerobic sequencing batch reactors (ASBR)

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  • Tangkathitipong, Pranee
  • Intanoo, Patcharee
  • Butpan, Janyawan
  • Chavadej, Sumaeth

Abstract

The objective of this study was to investigate hydrogen and methane production from biodiesel wastewater with added glycerin by using two-stage anaerobic sequencing batch reactors (ASBR) under 37 °C with a recycle ratio of the effluent from the methane ASBR unit-to-the feed flow rate of 1:1. Hydrogen ASBR unit was operated at a constant pH of 5.5 whereas the pH of methane ASBR unit was not controlled. Glycerin was added into biodiesel wastewater having 2330 mg/l COD to obtain a constant feed chemical oxygen demand (COD) of 45,000 m/l. At optimum COD loading rate 11.3 kg/m3d (based on feed COD load and methane ASBR volume), the system provided the highest overall hydrogen and methane production performance (75.15 ml H2/g glycerin removed) which was consistent with the maximum overall COD removal of 76.7% and the highest overall glycerin uptake of 90%. Most of added glycerin was converted to gaseous products with small amounts of organic acids and 1,3 propanediol. The low volumetric ratio of hydrogen ASBR unit-to-methane ASBR unit of 1:6 resulted in low hydrogen yields with high methane yields. Process performance of the two-stage ASBR system was limited by the inhibition of total volatile organic acids produced in both bioreactors.

Suggested Citation

  • Tangkathitipong, Pranee & Intanoo, Patcharee & Butpan, Janyawan & Chavadej, Sumaeth, 2017. "Separate production of hydrogen and methane from biodiesel wastewater with added glycerin by two-stage anaerobic sequencing batch reactors (ASBR)," Renewable Energy, Elsevier, vol. 113(C), pages 1077-1085.
  • Handle: RePEc:eee:renene:v:113:y:2017:i:c:p:1077-1085
    DOI: 10.1016/j.renene.2017.06.056
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    References listed on IDEAS

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    1. Abbasi, Tasneem & Tauseef, S.M. & Abbasi, S.A., 2012. "Anaerobic digestion for global warming control and energy generation—An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3228-3242.
    2. Ayoub, Muhammad & Abdullah, Ahmad Zuhairi, 2012. "Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2671-2686.
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    2. Seneesrisakul, Kessara & Jantaruksa, Todsapon & Jiraprasertwong, Achiraya & Pornmai, Krittiya & Rangsunvigit, Pramoch & Chavadej, Sumaeth, 2021. "Effects of the reactor volumetric ratio and recycle ratio on the methane and energy productivity of a three-step anaerobic sequencing batch reactor (3S-ASBR) treating ethanol wastewater," Energy, Elsevier, vol. 227(C).
    3. Kessara Seneesrisakul & Twarath Sutabutr & Sumaeth Chavadej, 2018. "The Effect of Temperature on the Methanogenic Activity in Relation to Micronutrient Availability," Energies, MDPI, vol. 11(5), pages 1-17, April.
    4. Laura, Mitrea & Monica, Trif & Dan-Cristian, Vodnar, 2020. "The effect of crude glycerol impurities on 1,3-propanediol biosynthesis by Klebsiella pneumoniae DSMZ 2026," Renewable Energy, Elsevier, vol. 153(C), pages 1418-1427.
    5. Mohammed Ali Musa & Syazwani Idrus & Che Man Hasfalina & Nik Norsyahariati Nik Daud, 2018. "Effect of Organic Loading Rate on Anaerobic Digestion Performance of Mesophilic (UASB) Reactor Using Cattle Slaughterhouse Wastewater as Substrate," IJERPH, MDPI, vol. 15(10), pages 1-19, October.

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