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Simultaneous molecular and process design for waste heat recovery

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  • Palma-Flores, Oscar
  • Flores-Tlacuahuac, Antonio
  • Canseco-Melchorb, Graciela

Abstract

Processing streams featuring low temperatures are common in industrial systems. Because of low temperatures it turns out to be a challenge to use these type of streams for energy recovery. This is especially true if water is used as the main fluid for energy recovery since large amounts of energy are required for water vaporization. To cope with this energy problem different types of organic fluids used in Rankine-like thermodynamic cycles have been proposed. However, high cost and sustainability issues (i.e. large toxicity) related to organic fluids call for the design of a new type of working fluids suitable for low-temperature energy recovery. This generation of new working fluids should feature target properties such as high vapor pressure and low flammability and toxicity values. Moreover, the performance of these new working fluids also depends on the operating conditions of the thermodynamic cycle where such working fluids will be used. In this work we address the simultaneous product and process design problem of working fluids for energy recovery from low-temperature energy sources in Rankine-like cycles to obtain improved optimal solutions. We compare the energy recovery performance of both the new family of working fluids and processing conditions against similar energy performance obtained using organic fluids previously used for the same aim. By using a system of coupled cycles, work production was increased. Moreover, the new working fluids feature improved safety margins. The results indicate the benefits of the simultaneous product and process design approach and permit us to identify a family of working fluids with better sustainability characteristics.

Suggested Citation

  • Palma-Flores, Oscar & Flores-Tlacuahuac, Antonio & Canseco-Melchorb, Graciela, 2016. "Simultaneous molecular and process design for waste heat recovery," Energy, Elsevier, vol. 99(C), pages 32-47.
    • Handle: RePEc:eee:energy:v:99:y:2016:i:c:p:32-47
    DOI: 10.1016/j.energy.2016.01.024
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    References listed on IDEAS

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    Cited by:

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    2. Azizi, Saeid & Shakibi, Hamid & Shokri, Afshar & Chitsaz, Ata & Yari, Mortaza, 2023. "Multi-aspect analysis and RSM-based optimization of a novel dual-source electricity and cooling cogeneration system," Applied Energy, Elsevier, vol. 332(C).
    3. Luo, Xianglong & Wang, Yupeng & Liang, Junwei & Qi, Ji & Su, Wen & Yang, Zhi & Chen, Jianyong & Wang, Chao & Chen, Ying, 2019. "Improved correlations for working fluid properties prediction and their application in performance evaluation of sub-critical Organic Rankine Cycle," Energy, Elsevier, vol. 174(C), pages 122-137.
    4. Fanxiao, Meng & Enhua, Wang & Bo, Zhang, 2021. "Possibility of optimal efficiency prediction of an organic Rankine cycle based on molecular property method for high-temperature exhaust gases," Energy, Elsevier, vol. 222(C).
    5. Shakibi, Hamid & Shokri, Afshar & Assareh, Ehsanolah & Yari, Mortaza & Lee, Moonyong, 2023. "Using machine learning approaches to model and optimize a combined solar/natural gas-based power and freshwater cogeneration system," Applied Energy, Elsevier, vol. 333(C).
    6. Su, Wen & Zhao, Li & Deng, Shuai, 2017. "Group contribution methods in thermodynamic cycles: Physical properties estimation of pure working fluids," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 984-1001.
    7. van Kleef, Luuk M.T. & Oyewunmi, Oyeniyi A. & Markides, Christos N., 2019. "Multi-objective thermo-economic optimization of organic Rankine cycle (ORC) power systems in waste-heat recovery applications using computer-aided molecular design techniques," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    8. Martin T. White & Abdulnaser I. Sayma, 2018. "A Generalised Assessment of Working Fluids and Radial Turbines for Non-Recuperated Subcritical Organic Rankine Cycles," Energies, MDPI, vol. 11(4), pages 1-26, March.

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