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Releasing behavior of chlorine and fluorine during agricultural waste pyrolysis

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  • Du, Shenglei
  • Wang, Xianhua
  • Shao, Jingai
  • Yang, Haiping
  • Xu, Guangfu
  • Chen, Hanping

Abstract

The releasing behavior of chlorine (Cl) and fluorine (F) during agricultural waste pyrolysis was investigated using a fixed-bed pyrolysis system with pyrohydrolytic-ion chromatography and thermodynamic equilibrium calculation. Agricultural waste contains a large amount of Cl-bearing species, among which approximately 30% is easily released with biomass drying. During biomass pyrolysis, Cl-bearing species evolve out rapidly to the gas phase, and higher temperature is favorable for the releasing. The releasing process can be divided into two ranges: the fast evaporating range (200–600 °C) and slow evaporating range (600–1000 °C). F shows similar transforming behavior. However, higher temperature is preferred for the release. Thermodynamic simulation shows that Cl mainly exists as KCl(g) at higher temperatures (>600 °C) with some HCl(g) and K2Cl2(g) as intermediate species at lower temperatures (<600 °C), whereas F mainly releases as SiF4 at higher temperatures (>500 °C) with SF5Cl being the dominant F-bearing species at lower temperatures (<500 °C).

Suggested Citation

  • Du, Shenglei & Wang, Xianhua & Shao, Jingai & Yang, Haiping & Xu, Guangfu & Chen, Hanping, 2014. "Releasing behavior of chlorine and fluorine during agricultural waste pyrolysis," Energy, Elsevier, vol. 74(C), pages 295-300.
    • Handle: RePEc:eee:energy:v:74:y:2014:i:c:p:295-300
    DOI: 10.1016/j.energy.2014.01.012
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    1. Lund, Henrik, 2007. "Renewable energy strategies for sustainable development," Energy, Elsevier, vol. 32(6), pages 912-919.
    2. Wu, C.Z. & Yin, X.L. & Yuan, Z.H. & Zhou, Z.Q. & Zhuang, X.S., 2010. "The development of bioenergy technology in China," Energy, Elsevier, vol. 35(11), pages 4445-4450.
    3. Wang, Wenfeng & Qin, Yong & Wang, Junyi & Li, Jian & Weiss, Dominik J., 2010. "A preliminary method for determining acceptable trace element levels in coal," Energy, Elsevier, vol. 35(1), pages 70-76.
    4. Lee, Jong-Min & Kim, Down-Won & Kim, Jae-Sung & Na, Jeong-Geol & Lee, See-Hoon, 2010. "Co-combustion of refuse derived fuel with Korean anthracite in a commercial circulating fluidized bed boiler," Energy, Elsevier, vol. 35(7), pages 2814-2818.
    5. Díaz-Ramírez, Maryori & Sebastián, Fernando & Royo, Javier & Rezeau, Adeline, 2012. "Combustion requirements for conversion of ash-rich novel energy crops in a 250 kWth multifuel grate fired system," Energy, Elsevier, vol. 46(1), pages 636-643.
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