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Mixtures of rubber tyre and plastic wastes pyrolysis: A kinetic study

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  • Miranda, Miguel
  • Cabrita, I.
  • Pinto, Filomena
  • Gulyurtlu, I.

Abstract

The study performed aimed at analysing possible routes for pyrolysis reaction mechanisms of polymeric materials namely RT (rubber tyre) and plastic wastes (PE (polyethylene), PP (polypropylene) and PS (polystyrene)). Consequently, and seeking sustainable transformation of waste streams into valuable chemicals and renewable liquid fuels, mixture of 30% RT, 20% PE, 30% PP and 20% PS was subjected to pyrolysis. Different kinetic models were studied using experimental data. None of the mechanisms found in literature led to a numerical adjustment and different pathways were investigated. Kinetic studies were performed aiming to evaluate direct conversions into new solid, liquid and gaseous products and if parallel reactions and/or reversible elementary steps should be included. Experiments were performed in batch system at different temperatures and reaction times. Kinetic models were evaluated and reaction pathways were proposed. Models reasonably fit experimental data, allow explaining wastes thermal degradation. Kinetic parameters were estimated for all temperatures and dependence of Ea and pre-exponential factor on temperature was evaluated. The rate constant of some reactions exhibited nonlinear temperature dependence on the logarithmic form of Arrhenius law. This fact strongly suggests that temperature has a significant effect on reaction mechanism of pyrolysis of mixtures of rubber tyre and plastic wastes.

Suggested Citation

  • Miranda, Miguel & Cabrita, I. & Pinto, Filomena & Gulyurtlu, I., 2013. "Mixtures of rubber tyre and plastic wastes pyrolysis: A kinetic study," Energy, Elsevier, vol. 58(C), pages 270-282.
  • Handle: RePEc:eee:energy:v:58:y:2013:i:c:p:270-282
    DOI: 10.1016/j.energy.2013.06.033
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    References listed on IDEAS

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    1. Li, A.M & Li, X.D & Li, S.Q & Ren, Y & Shang, N & Chi, Y & Yan, J.H & Cen, K.F, 1999. "Experimental studies on municipal solid waste pyrolysis in a laboratory-scale rotary kiln," Energy, Elsevier, vol. 24(3), pages 209-218.
    2. Mani, M. & Nagarajan, G. & Sampath, S., 2011. "Characterisation and effect of using waste plastic oil and diesel fuel blends in compression ignition engine," Energy, Elsevier, vol. 36(1), pages 212-219.
    3. Wallman, P.H & Thorsness, C.B & Winter, J.D, 1998. "Hydrogen production from wastes," Energy, Elsevier, vol. 23(4), pages 271-278.
    4. Lee, Jung Soo & Kim, Sang Done, 1996. "Gasification kinetics of waste tire-char with CO2 in a thermobalance reactor," Energy, Elsevier, vol. 21(5), pages 343-352.
    5. Singhabhandhu, Ampaitepin & Tezuka, Tetsuo, 2010. "The waste-to-energy framework for integrated multi-waste utilization: Waste cooking oil, waste lubricating oil, and waste plastics," Energy, Elsevier, vol. 35(6), pages 2544-2551.
    6. Tabasová, Andrea & Kropáč, Jiří & Kermes, Vít & Nemet, Andreja & Stehlík, Petr, 2012. "Waste-to-energy technologies: Impact on environment," Energy, Elsevier, vol. 44(1), pages 146-155.
    7. Chiarioni, A. & Reverberi, A.P. & Fabiano, B. & Dovì, V.G., 2006. "An improved model of an ASR pyrolysis reactor for energy recovery," Energy, Elsevier, vol. 31(13), pages 2460-2468.
    8. Mani, M. & Nagarajan, G., 2009. "Influence of injection timing on performance, emission and combustion characteristics of a DI diesel engine running on waste plastic oil," Energy, Elsevier, vol. 34(10), pages 1617-1623.
    9. Dai, Xianwen & Yin, Xiuli & Wu, Chuangzhi & Zhang, Wennan & Chen, Yong, 2001. "Pyrolysis of waste tires in a circulating fluidized-bed reactor," Energy, Elsevier, vol. 26(4), pages 385-399.
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