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Chemical effect of hydrogen peroxide addition on characteristics of methane–air combustion

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  • Chen, Guan-Bang
  • Li, Yueh-Heng
  • Cheng, Tsarng-Sheng
  • Chao, Yei-Chin

Abstract

The effects of hydrogen peroxide addition on the reaction pathway of premixed methane/air flames are numerically investigated using the PREMIX code with the GRI-Mech 3.0 chemical kinetic mechanisms and detailed transport properties. Hydrogen peroxide is used as the oxidizer substituent of air. Results show that the laminar burning velocity and adiabatic flame temperature of premixed methane–air flame are significantly increased with H2O2 addition. The addition of hydrogen peroxide increases not only all the reaction rates of intermediate species, but also the concentrations of intermediate species. The traditional reaction pathways of CH4/air flame are altered by the addition of hydrogen peroxide, due to the enhanced production of OH and HO2. The enhanced OH radicals promote HO2 productions through reaction (R89). The increased HO2 accelerates the progressive reaction of CH3 to form CH3O and then CH2O.

Suggested Citation

  • Chen, Guan-Bang & Li, Yueh-Heng & Cheng, Tsarng-Sheng & Chao, Yei-Chin, 2013. "Chemical effect of hydrogen peroxide addition on characteristics of methane–air combustion," Energy, Elsevier, vol. 55(C), pages 564-570.
    • Handle: RePEc:eee:energy:v:55:y:2013:i:c:p:564-570
    DOI: 10.1016/j.energy.2013.03.067
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    References listed on IDEAS

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    1. Wang, Shuofeng & Ji, Changwei & Zhang, Jian & Zhang, Bo, 2011. "Comparison of the performance of a spark-ignited gasoline engine blended with hydrogen and hydrogen–oxygen mixtures," Energy, Elsevier, vol. 36(10), pages 5832-5837.
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    Cited by:

    1. Li, Yueh-Heng & Chen, Guan-Bang & Lin, Yi-Chieh & Chao, Yei-Chin, 2015. "Effects of flue gas recirculation on the premixed oxy-methane flames in atmospheric condition," Energy, Elsevier, vol. 89(C), pages 845-857.
    2. Chen, Guan-Bang & Li, Yueh-Heng & Chen, Guan-Lin & Wu, Wen-Teng, 2017. "Effects of catalysts on pyrolysis of castor meal," Energy, Elsevier, vol. 119(C), pages 1-9.
    3. Cai, Peng & Liu, Zhenyi & Li, Pengliang & Zhao, Yao & Li, Mingzhi & Li, Ranran & Wang, Chen & Xiu, Zihao, 2023. "Effects of fuel component, airflow field and obstacles on explosion characteristics of hydrogen/methane mixtures fuel," Energy, Elsevier, vol. 265(C).
    4. Li, Yueh-Heng & Reddy, Sareddy Kullai & Chen, Chun-Han, 2021. "Effects of the nitrous oxide decomposition reaction on soot precursors in nitrous oxide/ethylene diffusion flames," Energy, Elsevier, vol. 235(C).
    5. Guan-Bang Chen & Jia-Wen Li & Hsien-Tsung Lin & Fang-Hsien Wu & Yei-Chin Chao, 2018. "A Study of the Production and Combustion Characteristics of Pyrolytic Oil from Sewage Sludge Using the Taguchi Method," Energies, MDPI, vol. 11(9), pages 1-17, August.
    6. Neshat, Elaheh & Saray, Rahim Khoshbakhti, 2014. "Development of a new multi zone model for prediction of HCCI (homogenous charge compression ignition) engine combustion, performance and emission characteristics," Energy, Elsevier, vol. 73(C), pages 325-339.

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