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Numerical study of hydrogen peroxide enhancement of ammonia premixed flames

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  • Wu, Fang-Hsien
  • Chen, Guan-Bang

Abstract

NH3 is considered a promising alternative for hydrocarbon-based fuels. However, NH3/air combustion has many challenges, including a high ignition temperature and low flame speed. Hydrogen peroxide can be used to overcome these defects. The effects of hydrogen peroxide on the NH3/air premixed flames are numerically investigated using a detailed chemical mechanism. When using hydrogen peroxide to replace partial air, the laminar burning velocity and adiabatic flame temperature are substantially increased. For higher replacement of hydrogen peroxide, the laminar burning velocity is dominated by hydrogen peroxide reactions related to OH. In addition, addition of hydrogen peroxide increases the species concentration and enhances reaction rates. The dominant reactions for species reaction rates are shifted, especially for OH and H2O. H2O is mainly formed from the reaction of hydrogen peroxide attacked with radical OH after the amount of added hydrogen peroxide exceeds 40%. As for NO emissions, it also increases due to the presence of NH3 and the higher flame temperature. Since hydrogen peroxide can substantially increase the combustion speed of NH3, thereby extending the flammability limit, it is feasible to control NO emissions by adjusting the replacement percentage of hydrogen peroxide and operating at a lower equivalence ratio.

Suggested Citation

  • Wu, Fang-Hsien & Chen, Guan-Bang, 2020. "Numerical study of hydrogen peroxide enhancement of ammonia premixed flames," Energy, Elsevier, vol. 209(C).
    • Handle: RePEc:eee:energy:v:209:y:2020:i:c:s0360544220312251
    DOI: 10.1016/j.energy.2020.118118
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    References listed on IDEAS

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    1. Honzawa, Takafumi & Kai, Reo & Okada, Akiko & Valera-Medina, Agustin & Bowen, Philip J. & Kurose, Ryoichi, 2019. "Predictions of NO and CO emissions in ammonia/methane/air combustion by LES using a non-adiabatic flamelet generated manifold," Energy, Elsevier, vol. 186(C).
    2. Ting, David S.-K. & Reader, Graham T., 2005. "Hydrogen peroxide for improving premixed methane–air combustion," Energy, Elsevier, vol. 30(2), pages 313-322.
    3. Li, Jun & Huang, Hongyu & Deng, Lisheng & He, Zhaohong & Osaka, Yugo & Kobayashi, Noriyuki, 2019. "Effect of hydrogen addition on combustion and heat release characteristics of ammonia flame," Energy, Elsevier, vol. 175(C), pages 604-617.
    4. Morgan, Eric & Manwell, James & McGowan, Jon, 2014. "Wind-powered ammonia fuel production for remote islands: A case study," Renewable Energy, Elsevier, vol. 72(C), pages 51-61.
    5. Valera-Medina, Agustin & Marsh, Richard & Runyon, Jon & Pugh, Daniel & Beasley, Paul & Hughes, Timothy & Bowen, Phil, 2017. "Ammonia–methane combustion in tangential swirl burners for gas turbine power generation," Applied Energy, Elsevier, vol. 185(P2), pages 1362-1371.
    6. Xiao, Hua & Valera-Medina, Agustin & Bowen, Philip J, 2017. "Study on premixed combustion characteristics of co-firing ammonia/methane fuels," Energy, Elsevier, vol. 140(P1), pages 125-135.
    7. Li, Jun & Huang, Hongyu & Kobayashi, Noriyuki & He, Zhaohong & Osaka, Yugo & Zeng, Tao, 2015. "Numerical study on effect of oxygen content in combustion air on ammonia combustion," Energy, Elsevier, vol. 93(P2), pages 2053-2068.
    8. Woo, Mino & Choi, Byung Chul & Ghoniem, Ahmed F., 2016. "Experimental and numerical studies on NOx emission characteristics in laminar non-premixed jet flames of ammonia-containing methane fuel with oxygen/nitrogen oxidizer," Energy, Elsevier, vol. 114(C), pages 961-972.
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    Cited by:

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    3. Liu, Xing & Wang, Ying & Bai, Yuanqi & Yang, Wenxu, 2023. "Development of reduced and optimized mechanism for ammonia/ hydrogen mixture based on genetic algorithm," Energy, Elsevier, vol. 270(C).

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