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Exergy analysis of PEM fuel cells for marine applications

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  • Leo, T.J.
  • Durango, J.A.
  • Navarro, E.

Abstract

Fuel cells have a promising potential use in stationary and mobile power generation systems, as well as in automotive, aerospace or marine industries. At present, the main field of marine applications of fuel cells is submarines. Hydrogen/oxygen polymer electrolyte membrane (PEM) fuel cells are commonly used in this field. Storage of oxygen in liquid form is the optimal solution. Hydrogen can be stored in carbon-nanofibres or metallic hydrides, for example, or in liquid fuels, as alcohols, with further generation of the hydrogen required on-board. The objective of this study is to perform an exergetic analysis of two possibilities of using PEM fuel cells on surface ships and submarines: hydrogen/oxygen PEM fuel cells fed with hydrogen generated by reforming of methanol, and Direct Methanol Fuel Cells directly fed with liquid methanol. To do this, exergy losses and exergetic efficiencies are calculated for both configurations at selected optimal operation points.

Suggested Citation

  • Leo, T.J. & Durango, J.A. & Navarro, E., 2010. "Exergy analysis of PEM fuel cells for marine applications," Energy, Elsevier, vol. 35(2), pages 1164-1171.
    • Handle: RePEc:eee:energy:v:35:y:2010:i:2:p:1164-1171
    DOI: 10.1016/j.energy.2009.06.010
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    References listed on IDEAS

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    2. S. M. Seyed Mahmoudi & Niloufar Sarabchi & Mortaza Yari & Marc A. Rosen, 2019. "Exergy and Exergoeconomic Analyses of a Combined Power Producing System including a Proton Exchange Membrane Fuel Cell and an Organic Rankine Cycle," Sustainability, MDPI, vol. 11(12), pages 1-25, June.
    3. Jessie R. Smith & Savvas Gkantonas & Epaminondas Mastorakos, 2022. "Modelling of Boil-Off and Sloshing Relevant to Future Liquid Hydrogen Carriers," Energies, MDPI, vol. 15(6), pages 1-32, March.
    4. Burel, Fabio & Taccani, Rodolfo & Zuliani, Nicola, 2013. "Improving sustainability of maritime transport through utilization of Liquefied Natural Gas (LNG) for propulsion," Energy, Elsevier, vol. 57(C), pages 412-420.
    5. Sharaf, Omar Z. & Orhan, Mehmet F., 2014. "An overview of fuel cell technology: Fundamentals and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 810-853.
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    8. Yifan Wang & Laurence A. Wright, 2021. "A Comparative Review of Alternative Fuels for the Maritime Sector: Economic, Technology, and Policy Challenges for Clean Energy Implementation," World, MDPI, vol. 2(4), pages 1-26, October.
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    10. Salemme, Lucia & Menna, Laura & Simeone, Marino, 2013. "Calculation of the energy efficiency of fuel processor – PEM (proton exchange membrane) fuel cell systems from fuel elementar composition and heating value," Energy, Elsevier, vol. 57(C), pages 368-374.
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    14. Oh, Taek Hyun & Gang, Byeong Gyu & Kim, Hyuntak & Kwon, Sejin, 2015. "Sodium borohydride hydrogen generator using Co–P/Ni foam catalysts for 200 W proton exchange membrane fuel cell system," Energy, Elsevier, vol. 90(P1), pages 1163-1170.
    15. Lee, Chi-Hung & Chen, Szu-Hsien & Wang, Yen-Zen & Lin, Chao-Chien & Huang, Chih-Kai & Chuang, Ching-Nan & Wang, Chih-Kuang & Hsieh, Kuo-Huang, 2013. "Preparation and characterization of proton exchange membranes based on semi-interpenetrating sulfonated poly(imide-siloxane)/epoxy polymer networks," Energy, Elsevier, vol. 55(C), pages 905-915.
    16. Zhang, Nan & Lu, Yiji & Kadam, Sambhaji & Yu, Zhibin, 2023. "A fuel cell range extender integrating with heat pump for cabin heat and power generation," Applied Energy, Elsevier, vol. 348(C).
    17. Yuan, Zhenyu & Zhang, Yufeng & Fu, Wenting & Li, Zipeng & Liu, Xiaowei, 2013. "Investigation of a small-volume direct methanol fuel cell stack for portable applications," Energy, Elsevier, vol. 51(C), pages 462-467.
    18. Li, Dazi & Yu, Yadi & Jin, Qibing & Gao, Zhiqiang, 2014. "Maximum power efficiency operation and generalized predictive control of PEM (proton exchange membrane) fuel cell," Energy, Elsevier, vol. 68(C), pages 210-217.
    19. Lorenzo, Charles & Bouquain, David & Hibon, Samuel & Hissel, Daniel, 2021. "Synthesis of degradation mechanisms and of their impacts on degradation rates on proton-exchange membrane fuel cells and lithium-ion nickel–manganese–cobalt batteries in hybrid transport applicati," Reliability Engineering and System Safety, Elsevier, vol. 212(C).
    20. Sun, Zhe & Wang, Ning & Bi, Yunrui & Srinivasan, Dipti, 2015. "Parameter identification of PEMFC model based on hybrid adaptive differential evolution algorithm," Energy, Elsevier, vol. 90(P2), pages 1334-1341.
    21. Hui Xing & Charles Stuart & Stephen Spence & Hua Chen, 2021. "Fuel Cell Power Systems for Maritime Applications: Progress and Perspectives," Sustainability, MDPI, vol. 13(3), pages 1-34, January.
    22. Authayanun, Suthida & Saebea, Dang & Patcharavorachot, Yaneeporn & Arpornwichanop, Amornchai, 2014. "Effect of different fuel options on performance of high-temperature PEMFC (proton exchange membrane fuel cell) systems," Energy, Elsevier, vol. 68(C), pages 989-997.
    23. Cha, Dowon & Ahn, Jae Hwan & Kim, Hyung Soon & Kim, Yongchan, 2015. "Effects of clamping force on the water transport and performance of a PEM (proton electrolyte membrane) fuel cell with relative humidity and current density," Energy, Elsevier, vol. 93(P2), pages 1338-1344.
    24. Oh, Taek Hyun, 2016. "A formic acid hydrogen generator using Pd/C3N4 catalyst for mobile proton exchange membrane fuel cell systems," Energy, Elsevier, vol. 112(C), pages 679-685.
    25. Hyunyong Lee & Inchul Jung & Gilltae Roh & Youngseung Na & Hokeun Kang, 2020. "Comparative Analysis of On-Board Methane and Methanol Reforming Systems Combined with HT-PEM Fuel Cell and CO 2 Capture/Liquefaction System for Hydrogen Fueled Ship Application," Energies, MDPI, vol. 13(1), pages 1-25, January.

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