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Enhanced electrochemical cooling through a cascade Brayton refrigeration cycle: theoretical and practical insights

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  • Sha, Yingyin
  • Tang, Xin
  • Li, Guiqiang

Abstract

Effective and eco-friendly refrigeration technologies have been sought for years because vapor compression contributes largely to the global warming potential. Electrochemical refrigeration is a promising alternative due to the merits of zero-GWP, high efficiency, direct electrical-to-heat conversion, etc. However, it falls short of ultralow temperatures with significant temperature lift (ΔT). Here, we propose a novel cascade electrochemical Brayton refrigeration cycle that effectively enhances electrochemical deep refrigeration by cascading thermocells, integrating regenerative heat exchange, charging and discharging, and heat absorption and dissipation to increase ΔT, which is unique in utilizing the inherent entropy change of redox couples for refrigeration. Mathematical formulas and analytical models based on experimental data are derived and developed. Results show that with six cells cascaded and optimized parameters, the temperature lift of electrochemical cooling is enhanced from 16.27 to 109.79 K. More cells, higher regenerative efficiency, lower current, and larger temperature coefficient favor ΔT values of 30.52 K, 85.05 K, 30.54 K, and 109.79 K, respectively. Temperature coefficient affects the most on ΔT. This research broadens the scope for electrochemical deep refrigeration and provides a clear framework for optimization.

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  • Sha, Yingyin & Tang, Xin & Li, Guiqiang, 2025. "Enhanced electrochemical cooling through a cascade Brayton refrigeration cycle: theoretical and practical insights," Energy, Elsevier, vol. 325(C).
    • Handle: RePEc:eee:energy:v:325:y:2025:i:c:s0360544225018298
    DOI: 10.1016/j.energy.2025.136187
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    References listed on IDEAS

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    1. Li, Baode & Long, Rui & Liu, Zhichun & Liu, Wei, 2016. "Performance analysis of a thermally regenerative electrochemical refrigerator," Energy, Elsevier, vol. 112(C), pages 43-51.
    2. Tang, Xin & Li, Guiqiang & Zhao, Xudong, 2021. "Performance analysis of a novel hybrid electrical generation system using photovoltaic/thermal and thermally regenerative electrochemical cycle," Energy, Elsevier, vol. 232(C).
    3. Dawahdeh, Ahmad I. & Al-Nimr, Moh'd.A., 2023. "A novel energy harvesting and battery thermal management in hybrid vehicles using a thermally regenerative electrochemical device," Energy, Elsevier, vol. 270(C).
    4. Abdollahipour, Armin & Sayyaadi, Hoseyn, 2022. "A novel electrochemical refrigeration system based on the combined proton exchange membrane fuel cell-electrolyzer," Applied Energy, Elsevier, vol. 316(C).
    5. Aravindh Rajan & Ian S. McKay & Shannon K. Yee, 2022. "Continuous electrochemical refrigeration based on the Brayton cycle," Nature Energy, Nature, vol. 7(4), pages 320-328, April.
    6. Huang, Yuewu & Li, Danyi & Chen, Zhuo, 2022. "Potential analysis of a system hybridizing dye-sensitized solar cell with thermally regenerative electrochemical devices," Energy, Elsevier, vol. 260(C).
    7. F. Greibich & R. Schwödiauer & G. Mao & D. Wirthl & M. Drack & R. Baumgartner & A. Kogler & J. Stadlbauer & S. Bauer & N. Arnold & M. Kaltenbrunner, 2021. "Elastocaloric heat pump with specific cooling power of 20.9 W g–1 exploiting snap-through instability and strain-induced crystallization," Nature Energy, Nature, vol. 6(3), pages 260-267, March.
    8. Enescu, Diana & Virjoghe, Elena Otilia, 2014. "A review on thermoelectric cooling parameters and performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 903-916.
    9. Seok Woo Lee & Yuan Yang & Hyun-Wook Lee & Hadi Ghasemi & Daniel Kraemer & Gang Chen & Yi Cui, 2014. "An electrochemical system for efficiently harvesting low-grade heat energy," Nature Communications, Nature, vol. 5(1), pages 1-6, September.
    10. Long, Rui & Li, Baode & Liu, Zhichun & Liu, Wei, 2016. "Performance analysis of a dual loop thermally regenerative electrochemical cycle for waste heat recovery," Energy, Elsevier, vol. 107(C), pages 388-395.
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