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Research on the gas storage properties of ice and water conversion into methane hydrates in silica gel with various pore sizes

Author

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  • Liu, Jun
  • Lan, Jiang-Chen
  • Wang, Bei-Fu
  • Liang, Yan-Yan
  • Liang, De-Qing

Abstract

Hydrates can effectively store cooling energy and gases, showing great potential in the field of gas storage, separation and transportation. Three kinds of silica gel were used to strengthen the formation of methane hydrate. The structural and morphological characteristics of ice crystals, as well as the decomposition process of hydrates, were investigated utilizing a Powder X-ray Diffractometer, a stereoscopic microscope, a Differential Scanning Calorimeter, and a cryo-Scanning Electron Microscope. The results showed that the freezing point is transferred to 262.4 K in the pores of silica gel. Hexagonal ice and cubic ice are formed in the pores and on the surface, and ice film is formed on the surface. In the temperature of 253.1–268.1 K and the initial pressure of 4.0–6.0 MPa, the temperature increase or the pressure reduction enhance the methane dissolution and the initial methane hydrate formation rate. In the pore size of 9.31 nm–40.3 nm, with the increase of pore size, the lower the hydrate formation pressure, and the higher the gas consumption and consumption rate. Within the range of 40.3 nm–77.14 nm for pore size and 42.6 m2/g to 188.1 m2/g for specific surface area, the influence of these parameters on gas consumption and the rate of consumption during hydrate formation is minimal. The optimal conditions for methane hydrate formation are identified as 268.1 K, 4.0 MPa, utilizing silica gel type III. The gas storage ratio reached 50.09 V/V, and the final pressure was 2.5 MPa, which is advantageous for the application of hydrate-based gas storage and the utilization of cooling energy.

Suggested Citation

  • Liu, Jun & Lan, Jiang-Chen & Wang, Bei-Fu & Liang, Yan-Yan & Liang, De-Qing, 2025. "Research on the gas storage properties of ice and water conversion into methane hydrates in silica gel with various pore sizes," Energy, Elsevier, vol. 320(C).
    • Handle: RePEc:eee:energy:v:320:y:2025:i:c:s0360544225010680
    DOI: 10.1016/j.energy.2025.135426
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    References listed on IDEAS

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    1. Xie, Yan & Zheng, Tao & Zhu, Yujie & Sun, Changyu & Chen, Guangjin & Feng, Jingchun, 2024. "H2 promotes the premature replacement of CH4–CO2 hydrate even when the CH4 gas-phase pressure exceeds the phase equilibrium pressure of CH4 hydrate," Renewable and Sustainable Energy Reviews, Elsevier, vol. 200(C).
    2. Liu, Yingying & Xu, Huazheng & Sun, Lintao & Ma, Xuening & Li, Hongwei & Jiang, Lanlan & Zheng, Jia-nan & Song, Yongchen, 2024. "CO2 hydrate formation characteristics inside seawater residual/saturated sediments under marine CO2 storage scenes," Energy, Elsevier, vol. 309(C).
    3. Hong, Bingyuan & Qiao, Dan & Li, Yichen & Sun, Xiaoqing & Yang, Baolong & Li, Li & Gong, Jing & Wen, Kai, 2023. "Supply-demand balance of natural gas pipeline network integrating hydraulic and thermal characteristics, energy conservation and carbon reduction," Energy, Elsevier, vol. 283(C).
    4. Takeya, Satoshi & Mimachi, Hiroko & Murayama, Tetsuro, 2018. "Methane storage in water frameworks: Self-preservation of methane hydrate pellets formed from NaCl solutions," Applied Energy, Elsevier, vol. 230(C), pages 86-93.
    5. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    6. Wen, Kai & Gao, Wei & Hui, Xuchao & Li, Li & Yang, Baolong & Nie, Chaofei & Miao, Qing & Li, Yichen & Li, Cuicui & Hong, Bingyuan, 2024. "Allocation of transportation capacity for complex natural gas pipeline network under fair opening," Energy, Elsevier, vol. 291(C).
    7. Fang, Zhenhua & Pan, Zhen & Ma, Guiyang & Yu, Jingxian & Shang, Liyan & Zhang, Zhien, 2023. "Exergoeconomic, exergoenvironmental analysis and multi-objective optimization of a novel combined cooling, heating and power system for liquefied natural gas cold energy recovery," Energy, Elsevier, vol. 269(C).
    8. Li, Gang & Li, Xiao-Sen & Lv, Qiu-Nan & Xiao, Chang-Wen & Liu, Jian-Wu, 2023. "Full implicit simulator of hydrate (FISH) and analysis on hydrate dissociation in porous media in the cubic hydrate simulator," Energy, Elsevier, vol. 280(C).
    9. Xu, Jiuping & Tang, Min & Liu, Tingting & Fan, Lurong, 2024. "Technological paradigm-based development strategy towards natural gas hydrate technology," Energy, Elsevier, vol. 289(C).
    10. Qiao, Yan & Jiang, Wenquan & Li, Yang & Dong, Xiaoxiao & Yang, Fan, 2024. "Design and analysis of steam methane reforming hydrogen liquefaction and waste heat recovery system based on liquefied natural gas cold energy," Energy, Elsevier, vol. 302(C).
    11. Lin, Decai & Lu, Jingsheng & Liu, Jia & Liang, Deqing & Li, Dongliang & Jin, Guangrong & Xia, Zhiming & Li, Xiaosen, 2023. "Numerical study on natural gas hydrate production by hot water injection combined with depressurization," Energy, Elsevier, vol. 282(C).
    12. Tongu, Daiki & Obara, Shin'ya, 2024. "Formation temperature range expansion and energy storage properties of CO2 hydrates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    13. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
    14. Liu, Jun & Ding, Jia-Xiang & Liang, De-Qing, 2018. "Experimental study on hydrate-based gas separation of mixed CH4/CO2 using unstable ice in a silica gel bed," Energy, Elsevier, vol. 157(C), pages 54-64.
    15. Wang, Fei & Song, Yuan-Mei & Liu, Guo-Qiang & Guo, Gang & Luo, Sheng-Jun & Guo, Rong-Bo, 2018. "Rapid methane hydrate formation promoted by Ag&SDS-coated nanospheres for energy storage," Applied Energy, Elsevier, vol. 213(C), pages 227-234.
    16. Li, Gang & Englezos, Peter & Sun, Duo & Li, Xiao-Sen & Lv, Qiu-Nan & Weng, Yi-Fan, 2024. "Simulation of CO2 hydrate formation in porous medium and comparison with laboratory trial data," Energy, Elsevier, vol. 310(C).
    17. Babu, Ponnivalavan & Kumar, Rajnish & Linga, Praveen, 2013. "Pre-combustion capture of carbon dioxide in a fixed bed reactor using the clathrate hydrate process," Energy, Elsevier, vol. 50(C), pages 364-373.
    18. Kou, Xuan & Li, Xiao-Sen & Wang, Yi & Wan, Kun & Chen, Zhao-Yang, 2021. "Pore-scale analysis of relations between seepage characteristics and gas hydrate growth habit in porous sediments," Energy, Elsevier, vol. 218(C).
    19. Sa, Jeong-Hoon & Sum, Amadeu K., 2019. "Promoting gas hydrate formation with ice-nucleating additives for hydrate-based applications," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
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