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System analysis of hydrogen production from gasified black liquor

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  • Andersson, E.
  • Harvey, S.

Abstract

Hydrogen produced from renewable biofuel is both clean and CO2 neutral. This paper evaluates energy and net CO2 emissions consequences of integration of hydrogen production from gasified black liquor in a chemical pulp mill. A model of hydrogen production from gasified black liquor was developed and integration possibilities with the pulp mill's energy system were evaluated in order to maximize energy recovery. The potential hydrogen production is 59000 tonnes per year if integrated with the KAM reference market pulp mill producing 630000 Air dried tonnes (ADt) pulp/year. Changes of net CO2 emissions associated with modified mill electric power balance, biofuel import and end usage of the produced hydrogen are presented and compared with other uses of gasified black liquor such as electricity production and methanol production. Hydrogen production will result in the greatest reduction of net CO2 emissions and could reduce the Swedish CO2 emissions by 8% if implemented in all chemical market pulp mills. The associated increases of biofuel and electric power consumption are 5% and 1.7%, respectively.

Suggested Citation

  • Andersson, E. & Harvey, S., 2006. "System analysis of hydrogen production from gasified black liquor," Energy, Elsevier, vol. 31(15), pages 3426-3434.
    • Handle: RePEc:eee:energy:v:31:y:2006:i:15:p:3426-3434
    DOI: 10.1016/j.energy.2006.03.015
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    Citations

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    Cited by:

    1. Naqvi, Muhammad & Yan, Jinyue & Dahlquist, Erik, 2012. "Synthetic gas production from dry black liquor gasification process using direct causticization with CO2 capture," Applied Energy, Elsevier, vol. 97(C), pages 49-55.
    2. Naqvi, Muhammad & Yan, Jinyue & Dahlquist, Erik, 2012. "Bio-refinery system in a pulp mill for methanol production with comparison of pressurized black liquor gasification and dry gasification using direct causticization," Applied Energy, Elsevier, vol. 90(1), pages 24-31.
    3. Abánades, A. & Rubbia, C. & Salmieri, D., 2012. "Technological challenges for industrial development of hydrogen production based on methane cracking," Energy, Elsevier, vol. 46(1), pages 359-363.
    4. Johansson, Daniella & Franck, Per-Åke & Berntsson, Thore, 2012. "Hydrogen production from biomass gasification in the oil refining industry – A system analysis," Energy, Elsevier, vol. 38(1), pages 212-227.
    5. Darmawan, Arif & Ajiwibowo, Muhammad W. & Biddinika, Muhammad Kunta & Tokimatsu, Koji & Aziz, Muhammad, 2019. "Black liquor-based hydrogen and power co-production: Combination of supercritical water gasification and syngas chemical looping," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    6. Pio, D.T. & Tarelho, L.A.C. & Pinto, P.C.R., 2020. "Gasification-based biorefinery integration in the pulp and paper industry: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
    7. Cao, Changqing & Guo, Liejin & Jin, Hui & Cao, Wen & Jia, Yi & Yao, Xiangdong, 2017. "System analysis of pulping process coupled with supercritical water gasification of black liquor for combined hydrogen, heat and power production," Energy, Elsevier, vol. 132(C), pages 238-247.
    8. Pettersson, Karin & Harvey, Simon, 2010. "CO2 emission balances for different black liquor gasification biorefinery concepts for production of electricity or second-generation liquid biofuels," Energy, Elsevier, vol. 35(2), pages 1101-1106.
    9. Wetterlund, Elisabeth & Pettersson, Karin & Harvey, Simon, 2011. "Systems analysis of integrating biomass gasification with pulp and paper production – Effects on economic performance, CO2 emissions and energy use," Energy, Elsevier, vol. 36(2), pages 932-941.
    10. Qi, Xingang & Chen, Yunan & Zhao, Jiuyun & Su, Di & Liu, Fan & Lu, Libo & Jin, Hui & Guo, Liejin, 2023. "Thermodynamic and environmental assessment of black liquor supercritical water gasification integrated online salt recovery polygeneration system," Energy, Elsevier, vol. 278(PA).
    11. Darmawan, Arif & Ajiwibowo, Muhammad W. & Yoshikawa, Kunio & Aziz, Muhammad & Tokimatsu, Koji, 2018. "Energy-efficient recovery of black liquor through gasification and syngas chemical looping," Applied Energy, Elsevier, vol. 219(C), pages 290-298.
    12. Naqvi, Muhammad & Yan, Jinyue & Dahlquist, Erik, 2013. "System analysis of dry black liquor gasification based synthetic gas production comparing oxygen and air blown gasification systems," Applied Energy, Elsevier, vol. 112(C), pages 1275-1282.
    13. Akbari, Maryam & Oyedun, Adetoyese Olajire & Kumar, Amit, 2018. "Ammonia production from black liquor gasification and co-gasification with pulp and waste sludges: A techno-economic assessment," Energy, Elsevier, vol. 151(C), pages 133-143.
    14. Andersson, E. & Harvey, S., 2007. "Comparison of pulp-mill-integrated hydrogen production from gasified black liquor with stand-alone production from gasified biomass," Energy, Elsevier, vol. 32(4), pages 399-405.
    15. Pettersson, Karin & Harvey, Simon, 2012. "Comparison of black liquor gasification with other pulping biorefinery concepts – Systems analysis of economic performance and CO2 emissions," Energy, Elsevier, vol. 37(1), pages 136-153.
    16. Cao, Changqing & Xie, Yupeng & Mao, Liuhao & Wei, Wenwen & Shi, Jinwen & Jin, Hui, 2020. "Hydrogen production from supercritical water gasification of soda black liquor with various metal oxides," Renewable Energy, Elsevier, vol. 157(C), pages 24-32.
    17. Yang, F. & Meerman, J.C. & Faaij, A.P.C., 2021. "Carbon capture and biomass in industry: A techno-economic analysis and comparison of negative emission options," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).

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