IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v319y2025ics0360544225006899.html
   My bibliography  Save this article

Effects of ASR on combustion performance, GHG emissions and economic efficiency of ammonia/biodiesel dual-fuel low-carbon engine

Author

Listed:
  • Liu, Junheng
  • Zhao, Wenyao
  • Ji, Qian
  • Wang, Zichun
  • Ma, Hongjie
  • Sun, Ping
  • Ao, Chengcheng

Abstract

Ammonia, as a green and carbon-free hydrogen energy carrier, plays an important role in clean energy applications, while the addition of biofuel can also reduce the carbon footprint of engine. Therefore, the ammonia/biodiesel dual-fuel (ABDF) combustion mode is a new green and low-carbon combustion technology. In this study, the experimental investigation of ABDF engine performance at different ammonia substitution ratios (ASRs) and loads based on a modified four-cylinder common-rail engine has been conducted. The results indicate that the peak in-cylinder pressure decreased and occurred earlier as ASR increased, and the combustion duration increased with load, limited by ammonia inert combustion and inhibition. With the increase of ASR, the IMEP decreased, while the coefficient of variation increased. In addition, ammonia exacerbated incomplete combustion, leading to a rise in NH3, CO and HC emissions. The reduction in NOx and GHG emissions reached the maximum at ASR = 60 %. Since life cycle assessment (LCA) of ammonia is higher than biodiesel, the increase in ASR increased LCA by 17.1 % at 75 % load. In energy balance, unburned losses increased with increasing ASR by 5.9 %, 6.0 % and 2.5 % at ASR = 60 %. The energy consumption and equivalent diesel consumption decreased with increasing ASR, resulting in more economical cost.

Suggested Citation

  • Liu, Junheng & Zhao, Wenyao & Ji, Qian & Wang, Zichun & Ma, Hongjie & Sun, Ping & Ao, Chengcheng, 2025. "Effects of ASR on combustion performance, GHG emissions and economic efficiency of ammonia/biodiesel dual-fuel low-carbon engine," Energy, Elsevier, vol. 319(C).
  • Handle: RePEc:eee:energy:v:319:y:2025:i:c:s0360544225006899
    DOI: 10.1016/j.energy.2025.135047
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544225006899
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2025.135047?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to

    for a different version of it.

    References listed on IDEAS

    as
    1. Li, Jing & Yu, Xiao & Xie, Jingcheng & Yang, Wenming, 2020. "Mitigation of high pressure rise rate by varying IVC timing and EGR rate in an RCCI engine with high premixed fuel ratio," Energy, Elsevier, vol. 192(C).
    2. Liu, Junheng & Ma, Haoran & Liang, Wenwen & Yang, Jun & Sun, Ping & Wang, Xidong & Wang, Yongxu & Wang, Pan, 2022. "Experimental investigation on combustion characteristics and influencing factors of PODE/methanol dual-fuel engine," Energy, Elsevier, vol. 260(C).
    3. Doppalapudi, A.T. & Azad, A.K. & Khan, M.M.K., 2023. "Advanced strategies to reduce harmful nitrogen-oxide emissions from biodiesel fueled engine," Renewable and Sustainable Energy Reviews, Elsevier, vol. 174(C).
    4. Kan, Xiang & Wei, Liping & Li, Xian & Li, Han & Zhou, Dezhi & Yang, Wenming & Wang, Chi-Hwa, 2020. "Effects of the three dual-fuel strategies on performance and emissions of a biodiesel engine," Applied Energy, Elsevier, vol. 262(C).
    5. Chen, Yanhui & Zhang, Jian & Zhang, Zhiqing & Zhang, Bin & Hu, Jingyi & Zhong, Weihuang & Ye, Yanshuai, 2024. "Effect of ammonia energy ratio and load on combustion and emissions of an ammonia/diesel dual-fuel engine," Energy, Elsevier, vol. 302(C).
    6. Wei, Wenwen & Li, Gesheng & Zhang, Zunhua & Long, Yanxiang & Zhang, Hanyuyang & Huang, Yong & Zhou, Mengni & Wei, Yi, 2023. "Effects of ammonia addition on the performance and emissions for a spark-ignition marine natural gas engine," Energy, Elsevier, vol. 272(C).
    7. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Doppalapudi, A.T. & Azad, A.K. & Khan, M.M.K., 2023. "Advanced strategies to reduce harmful nitrogen-oxide emissions from biodiesel fueled engine," Renewable and Sustainable Energy Reviews, Elsevier, vol. 174(C).
    2. Pasternak, Michał & Przybyła, Grzegorz & Siddareddy, Reddy & Lewandowski, Michał & Bjørgen, Karl & Mauss, Fabian & Nadimi, Ebrahim & Peczkis, Grzegorz & Zhou, Min-min & Adamczyk, Wojciech, 2025. "Development of ammonia-biodiesel fueled agricultural tractor: Aspects of retrofitting a compression ignition engine to direct ammonia injection," Energy, Elsevier, vol. 327(C).
    3. Arun Teja Doppalapudi & Abul Kalam Azad & Mohammad Masud Kamal Khan, 2023. "Analysis of Improved In-Cylinder Combustion Characteristics with Chamber Modifications of the Diesel Engine," Energies, MDPI, vol. 16(6), pages 1-18, March.
    4. Mahlia, T.M.I. & Syazmi, Z.A.H.S. & Mofijur, M. & Abas, A.E. Pg & Bilad, M.R. & Ong, Hwai Chyuan & Silitonga, A.S., 2020. "Patent landscape review on biodiesel production: Technology updates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).
    5. Andiyappan, Kistan & Ramalingam, Sathiyamoorthi, 2025. "Green synthesis of manganese (Mn) doped zinc oxide (ZnO) nano-additives from biodegradable novel dragon fruit peel extracts and its effect on reactivity controlled compression ignition (RCCI) engine p," Energy, Elsevier, vol. 324(C).
    6. Zareh, Parvaneh & Zare, Ali Asghar & Ghobadian, Barat, 2017. "Comparative assessment of performance and emission characteristics of castor, coconut and waste cooking based biodiesel as fuel in a diesel engine," Energy, Elsevier, vol. 139(C), pages 883-894.
    7. Gupta, Jharna & Agarwal, Madhu & Dalai, A.K., 2019. "Intensified transesterification of mixture of edible and nonedible oils in reverse flow helical coil reactor for biodiesel production," Renewable Energy, Elsevier, vol. 134(C), pages 509-525.
    8. Wang, Shuofeng & Sun, Yu & Yang, Jinxin & Wang, Huaiyu, 2024. "Effect of excess air ratio and ignition timing on the combustion and emission characteristics of the ammonia-hydrogen Wankel rotary engine," Energy, Elsevier, vol. 302(C).
    9. Muteeb ul Haq & Ali Turab Jafry & Muhammad Salman Abbasi & Muhammad Jawad & Saad Ahmad & Taqi Ahmad Cheema & Naseem Abbas, 2022. "Numerical and Experimental Spray Analysis of Castor and Jatropha Biodiesel under Non-Evaporating Conditions," Energies, MDPI, vol. 15(20), pages 1-18, October.
    10. Shi, Guodong & Li, Pengfei & Li, Kesheng & Hu, Fan & Liu, Qian & Zhou, Haoyu & Liu, Zhaohui, 2023. "Insight into NOx formation characteristics of ammonia oxidation in N2 and H2O atmospheres," Energy, Elsevier, vol. 285(C).
    11. Zhao, Wenbin & Wu, Haoqing & Mi, Shijie & Zhang, Yaoyuan & He, Zhuoyao & Qian, Yong & Lu, Xingcai, 2023. "Experimental investigation of the control strategy of high load extension under iso-butanol/biodiesel dual-fuel intelligent charge compression ignition (ICCI) mode," Renewable and Sustainable Energy Reviews, Elsevier, vol. 172(C).
    12. Abul Kalam Azad & Julian Adhikari & Pobitra Halder & Mohammad G. Rasul & Nur M. S. Hassan & Mohammad M. K. Khan & Salman Raza Naqvi & Karthickeyan Viswanathan, 2020. "Performance, Emission and Combustion Characteristics of a Diesel Engine Powered by Macadamia and Grapeseed Biodiesels," Energies, MDPI, vol. 13(11), pages 1-19, May.
    13. Gourich, Wail & Chan, Eng-Seng & Ng, Wei Zhe & Obon, Aaron Anthony & Maran, Kireshwen & Ong, Yi Hui & Lee, Chin Loong & Tan, Jully & Song, Cher Pin, 2022. "Life cycle benefits of enzymatic biodiesel co-produced in palm oil mills from sludge palm oil as renewable fuel for rural electrification," Applied Energy, Elsevier, vol. 325(C).
    14. Marcin Zieliński & Marcin Dębowski & Joanna Kazimierowicz & Ryszard Michalski, 2024. "The Emissions of a Compression-Ignition Engine Fuelled by a Mixture of Crude Oil and Biodiesel from the Lipids Accumulated in the Waste Glycerol-Fed Culture of Schizochytrium sp," Energies, MDPI, vol. 17(20), pages 1-23, October.
    15. Liu, Junheng & Wu, Pengcheng & Ji, Qian & Sun, Ping & Wang, Pan & Meng, Zhongwei & Ma, Hongjie, 2022. "Experimental study on effects of pilot injection strategy on combustion and emission characteristics of diesel/methanol dual-fuel engine under low load," Energy, Elsevier, vol. 247(C).
    16. Yang, Yubeen & Kim, Jisoo & Kim, Namho & Park, Sungwook, 2024. "Effects of continuous variable valve timing and duration on fuel/air mixture formation," Energy, Elsevier, vol. 306(C).
    17. Liu, Junheng & Liang, Wenwen & Ma, Haoran & Ji, Qian & Xiang, Pan & Sun, Ping & Wang, Pan & Wei, Mingliang & Ma, Hongjie, 2023. "Effects of integrated aftertreatment system on regulated and unregulated emission characteristics of non-road methanol/diesel dual-fuel engine," Energy, Elsevier, vol. 282(C).
    18. Wu, Yue & Liu, Long & Wang, Lifeng & Wu, Jie, 2025. "Investigation of performance and emission characteristics in natural gas dual fuel marine engines with a novel Burned Zone Ammonia Combustion strategy," Energy, Elsevier, vol. 324(C).
    19. Jinyi Hu & Yongbao Liu & Xing He & Jianfeng Zhao & Shaojun Xia, 2024. "Application of NH 3 Fuel in Power Equipment and Its Impact on NO x Emissions," Energies, MDPI, vol. 17(12), pages 1-39, June.
    20. Kan, Xiang & Wei, Liping & Li, Xian & Li, Han & Zhou, Dezhi & Yang, Wenming & Wang, Chi-Hwa, 2020. "Effects of the three dual-fuel strategies on performance and emissions of a biodiesel engine," Applied Energy, Elsevier, vol. 262(C).

    More about this item

    Keywords

    ;
    ;
    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:319:y:2025:i:c:s0360544225006899. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.