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Production and flow behaviors of CO2+TBAB hydrate slurry for cold storage and transport application

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  • Yang, Kairan
  • Chen, Zuozhou
  • Zhang, Peng

Abstract

The CO2+TBAB (tetrabutylammonium bromide) hydrate slurry emerges as a promising phase change slurry for cold storage and transport applications due to its large latent heat, favorable fluidity and adjustable phase change temperature for secondary refrigeration. To investigate the cold storage and transport characteristics of CO2+TBAB hydrate slurry, the production and flow properties are experimentally studied. Furthermore, the system energy efficiency is analyzed based on the determined cold storage capacity and rheological characteristics. The cold storage capacity of CO2+TBAB hydrate slurry is influenced by the quantity of generated TBAB semi-clathrate hydrate and the quantity of encaged CO2. Increasing pressure effectively enhances CO2 absorption quantity due to larger driving force for CO2 diffusion, resulting in greater cage occupancy and larger latent heat. The CO2+TBAB hydrate slurry exhibits shear-thinning behavior for solid mass fractions ranging from 7.1 wt% to 49.2 wt%. The apparent viscosity is modeled using the power-law equation to predict the pressure drop. The energy analysis underscores that the pumping power consumption decreases by 77.9 % at a cooling capacity of 100 kW when the solid mass fraction is increased from 17.1 wt% to 34.1 wt%, and this energy-saving feature is further enhanced with the increase of cooling capacity.

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  • Yang, Kairan & Chen, Zuozhou & Zhang, Peng, 2025. "Production and flow behaviors of CO2+TBAB hydrate slurry for cold storage and transport application," Energy, Elsevier, vol. 316(C).
    • Handle: RePEc:eee:energy:v:316:y:2025:i:c:s0360544225001276
    DOI: 10.1016/j.energy.2025.134485
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    1. Pons, Michel & Hoang, Hong-Minh & Dufour, Thomas & Fournaison, Laurence & Delahaye, Anthony, 2018. "Energy analysis of two-phase secondary refrigeration in steady-state operation, part 1: Global optimization and leading parameter," Energy, Elsevier, vol. 161(C), pages 1282-1290.
    2. Dufour, Thomas & Hoang, Hong Minh & Oignet, Jérémy & Osswald, Véronique & Clain, Pascal & Fournaison, Laurence & Delahaye, Anthony, 2017. "Impact of pressure on the dynamic behavior of CO2 hydrate slurry in a stirred tank reactor applied to cold thermal energy storage," Applied Energy, Elsevier, vol. 204(C), pages 641-652.
    3. Cheng, Zucheng & Sun, Lintao & Liu, Yingying & Xu, Huazheng & Jiang, Lanlan & Wang, Lei & Song, Yongchen, 2023. "Multiscale analysis of the effect of the structural transformation of TBAB semi-clathrate hydrate on CO2 capture efficiency," Energy, Elsevier, vol. 280(C).
    4. Shi, X.J. & Zhang, P., 2013. "A comparative study of different methods for the generation of tetra-n-butyl ammonium bromide clathrate hydrate slurry in a cold storage air-conditioning system," Applied Energy, Elsevier, vol. 112(C), pages 1393-1402.
    5. Kim, Hyunho & Zheng, Junjie & Yin, Zhenyuan & Babu, Ponnivalavan & Kumar, Sreekala & Tee, Jackson & Linga, Praveen, 2023. "Semi-clathrate hydrate slurry as a cold energy storage and transport medium: Rheological study, energy analysis and enhancement by amino acid," Energy, Elsevier, vol. 264(C).
    6. Alva, Guruprasad & Lin, Yaxue & Fang, Guiyin, 2018. "An overview of thermal energy storage systems," Energy, Elsevier, vol. 144(C), pages 341-378.
    7. Yang, Kairan & Chen, Zuozhou & Zhang, Peng, 2024. "State-of-the-art of cold energy storage, release and transport using CO2 double hydrate slurry," Applied Energy, Elsevier, vol. 358(C).
    8. Zhang, P. & Ma, Z.W., 2012. "An overview of fundamental studies and applications of phase change material slurries to secondary loop refrigeration and air conditioning systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5021-5058.
    9. Tiwari, Vipul Kumar & Kumar, Alok & Kumar, Arvind, 2019. "Enhancing ice slurry generation by using inclined cavity for subzero cold thermal energy storage: Simulation, experiment and performance analysis," Energy, Elsevier, vol. 183(C), pages 398-414.
    10. Yang, Kairan & Guo, Weimin & Zhang, Peng, 2024. "Cold energy transport and release characteristics of CO2+TBAB hydrate slurry flow with hydrate dissociation," Energy, Elsevier, vol. 294(C).
    11. Jie, Pengfei & Kong, Xiangfei & Rong, Xian & Xie, Shangqun, 2016. "Selecting the optimum pressure drop per unit length of district heating piping network based on operating strategies," Applied Energy, Elsevier, vol. 177(C), pages 341-353.
    12. Xu, Huazheng & Liu, Yingying & He, Siyuan & Zheng, Jia-nan & Jiang, Lanlan & Song, Yongchen, 2024. "Enhanced CO2 hydrate formation using hydrogen-rich stones, L-Methionine and SDS: Insights from kinetic and morphological studies," Energy, Elsevier, vol. 291(C).
    13. Pons, Michel & Delahaye, Anthony & Fournaison, Laurence & Dalmazzone, Didier, 2018. "Energy analysis of two-phase secondary refrigeration in steady-state operation, part 2: Exergy analysis and effects of phase change kinetics," Energy, Elsevier, vol. 161(C), pages 1291-1299.
    14. Chami, Nada & Salehy, Yasmine & Burgner, Dennis & Clain, Pascal & Dalmazzone, Didier & Delahaye, Anthony & Fournaison, Laurence, 2023. "Rheological study of mixed cyclopentane + CO2 hydrate slurry in a dynamic loop for refrigeration systems," Energy, Elsevier, vol. 263(PA).
    15. Matsuura, Riku & Watanabe, Kosuke & Yamauchi, Yuji & Sato, Haruka & Chen, Li-Jen & Ohmura, Ryo, 2021. "Thermodynamic analysis of hydrate-based refrigeration cycle," Energy, Elsevier, vol. 220(C).
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