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Comparison of organic coolants for boiling cooling of proton exchange membrane fuel cell

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  • Li, Qingshan
  • Wang, Chenfang
  • Wang, Chunmei
  • Zhou, Taotao
  • Zhang, Xianwen
  • Zhang, Yangjun
  • Zhuge, Weilin
  • Sun, Li

Abstract

Cooling and temperature homogeneity are the key technical problems for the proton exchange membrane fuel cell (PEMFC) thermal management. In this paper, a one-dimensional model of a PEMFC with phase-change cooling (flow boiling cooling) is proposed for PEMFC thermal management, and the heat transfer of microchannel flow boiling is integrated with PEMFC cooling. Five organic coolants (Novec 649, HFC-365mfc, HFE-356mec, HFE-347pcf2, and HFE-7100) and single-phase water are compared by the PEMFC average temperature of the catalyst layer (ATCL) and temperature difference of the catalyst layer (TDCL). The PEMFC temperature characteristics with organic coolant are investigated in detail. The results indicate that HFE-7100 exhibited the lowest ATCL and minimum TDCL among the coolants. The maximum TDCL of HFE-7100 is 5.5 K at current density of 1.2 A/cm2, which can completely keep the PEMFC operating temperature at proper and uniform conditions. The minimum ATCL of Novec 649 is over 353 K, which dissatisfies the cooling demand. The TDCLs of PEMFCs with different organic coolants have a minimum value when the coolant outlet vapour mass fraction is 0.4. Temperature uniformity should be the most important factor for mass flow control in PEMFCs using organic coolants.

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  • Li, Qingshan & Wang, Chenfang & Wang, Chunmei & Zhou, Taotao & Zhang, Xianwen & Zhang, Yangjun & Zhuge, Weilin & Sun, Li, 2023. "Comparison of organic coolants for boiling cooling of proton exchange membrane fuel cell," Energy, Elsevier, vol. 266(C).
    • Handle: RePEc:eee:energy:v:266:y:2023:i:c:s0360544222032285
    DOI: 10.1016/j.energy.2022.126342
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    1. Rui, Ziliang & Sun, Hong & Ma, Jie & Peng, Hao, 2023. "Experimental study and prediction on the thermal management performance of SDS aqueous solution based microchannel flow boiling system," Energy, Elsevier, vol. 282(C).
    2. Zhang, Yong & He, Shirong & Jiang, Xiaohui & Wang, Zhuo & Wang, Yonggang & Gu, Meng & Yang, Xi & Zhang, Shuanyang & Cao, Jing & Fang, Haoyan & Li, Qiming, 2024. "Performance and configuration optimization of proton exchange membrane fuel cell considering dual symmetric Tesla valve flow field," Energy, Elsevier, vol. 288(C).
    3. Chen, Ben & Deng, Qihao & Yang, Guanghua & Zhou, Yu & Chen, Wenshang & Cai, Yonghua & Tu, Zhengkai, 2023. "Numerical study on heat transfer characteristics and performance evaluation of PEMFC based on multiphase electrochemical model coupled with cooling channel," Energy, Elsevier, vol. 285(C).
    4. Zhang, Yong & He, Shirong & Jiang, Xiaohui & Wang, Zhuo & Yang, Xi & Fang, Haoyan & Li, Qiming & Cao, Jing, 2024. "Investigation on performance of full-scale proton exchange membrane fuel cell: Porous foam flow field with integrated bipolar plate/gas diffusion layer," Energy, Elsevier, vol. 287(C).
    5. Ni, Song & Pan, Chin & Hibiki, Takashi & Zhao, Jiyun, 2024. "Applications of nucleate boiling in renewable energy and thermal management and recent advances in modeling——a review," Energy, Elsevier, vol. 289(C).

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