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Upgrading the low-grade waste heat from alkaline fuel cells via isopropanol-acetone-hydrogen chemical heat pumps

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  • Zhu, Huichao
  • Zhang, Houcheng

Abstract

To upgrade the quality of low-grade waste heat, a new coupling system integrating isopropanol-acetone-hydrogen chemical heat pump (IAH-CHP) to alkaline fuel cell (AFC) is proposed. The irreversible losses in the electrochemical and thermodynamic processes are quantitatively analyzed, and the energy and exergy performance indicators of each system component and coupling system are obtained based on the steady-state mathematical models and thermodynamic laws. Numerical calculations show that the achievable peak output power density and its corresponding energy efficiency, exergy destruction rate density and exergy efficiency are, respectively, 70.95%, 25.65%, 30.84% and 25.59% greater than that of the sole AFC. Optimal operation regions for various key performance indicators are obtained. The competitiveness of the proposed system is checked by comparing it with the available AFC-based coupling systems. Furthermore, the effects of operating temperature, temperature of exothermic reaction, molar ratio of hydrogen to acetone in the exothermic reactor before exothermic reaction, reflux ratio, thermodynamic loss composite parameter and IAH-CHP regenerator effectiveness on the coupling system performance are analyzed. The results obtained in this paper may provide some theoretical bases for improving the thermodynamic performance of such practical coupling systems.

Suggested Citation

  • Zhu, Huichao & Zhang, Houcheng, 2023. "Upgrading the low-grade waste heat from alkaline fuel cells via isopropanol-acetone-hydrogen chemical heat pumps," Energy, Elsevier, vol. 265(C).
    • Handle: RePEc:eee:energy:v:265:y:2023:i:c:s036054422203208x
    DOI: 10.1016/j.energy.2022.126322
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    1. Jovet, Yoann & Lefèvre, Frédéric & Laurent, Alexis & Clausse, Marc, 2022. "Combined energetic, economic and climate change assessment of heat pumps for industrial waste heat recovery," Applied Energy, Elsevier, vol. 313(C).
    2. Yeo, Lip Siang & Teng, Sin Yong & Ng, Wendy Pei Qin & Lim, Chun Hsion & Leong, Wei Dong & Lam, Hon Loong & Wong, Yat Choy & Sunarso, Jaka & How, Bing Shen, 2022. "Sequential optimization of process and supply chains considering re-refineries for oil and gas circularity," Applied Energy, Elsevier, vol. 322(C).
    3. Tan, Zhimin & Feng, Xiao & Wang, Yufei, 2021. "Performance comparison of different heat pumps in low-temperature waste heat recovery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    4. Ji, Zhengsen & Niu, Dongxiao & Li, Wanying & Wu, Gengqi & Yang, Xiaolong & Sun, Lijie, 2022. "Improving the energy efficiency of China: An analysis considering clean energy and fossil energy resources," Energy, Elsevier, vol. 259(C).
    5. Baz, Khan & Cheng, Jinhua & Xu, Deyi & Abbas, Khizar & Ali, Imad & Ali, Hashmat & Fang, Chuandi, 2021. "Asymmetric impact of fossil fuel and renewable energy consumption on economic growth: A nonlinear technique," Energy, Elsevier, vol. 226(C).
    6. Kim, Gabyong & Jung, Han Sol & Park, Sejun & Kang, Yong Tae, 2022. "Performance analysis of type 1 and type 2 hybrid absorption heat pump using novel working pairs," Energy, Elsevier, vol. 241(C).
    7. Mei, Shuxue & Lu, Xiaorui & Zhu, Yu & Wang, Shixue, 2021. "Thermodynamic assessment of a system configuration strategy for a cogeneration system combining SOFC, thermoelectric generator, and absorption heat pump," Applied Energy, Elsevier, vol. 302(C).
    8. Zhang, Houcheng & Lin, Guoxing & Chen, Jincan, 2011. "The performance analysis and multi-objective optimization of a typical alkaline fuel cell," Energy, Elsevier, vol. 36(7), pages 4327-4332.
    9. Cudok, Falk & Giannetti, Niccolò & Ciganda, José L. Corrales & Aoyama, Jun & Babu, P. & Coronas, Alberto & Fujii, Tatsuo & Inoue, Naoyuki & Saito, Kiyoshi & Yamaguchi, Seiichi & Ziegler, Felix, 2021. "Absorption heat transformer - state-of-the-art of industrial applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    10. Xiong Peng & Devashish Kulkarni & Ying Huang & Travis J. Omasta & Benjamin Ng & Yiwei Zheng & Lianqin Wang & Jacob M. LaManna & Daniel S. Hussey & John R. Varcoe & Iryna V. Zenyuk & William E. Mustain, 2020. "Using operando techniques to understand and design high performance and stable alkaline membrane fuel cells," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    11. Zhang, Xin & Cai, Ling & Liao, Tianjun & Zhou, Yinghui & Zhao, Yingru & Chen, Jincan, 2018. "Exploiting the waste heat from an alkaline fuel cell via electrochemical cycles," Energy, Elsevier, vol. 142(C), pages 983-990.
    12. Guo, Xinru & Zhang, Houcheng & Hu, Ziyang & Hou, Shujin & Ni, Meng & Liao, Tianjun, 2021. "Energetic, exergetic and ecological evaluations of a hybrid system based on a phosphoric acid fuel cell and an organic Rankine cycle," Energy, Elsevier, vol. 217(C).
    13. Ying Wang & Yao Yang & Shuangfeng Jia & Xiaoming Wang & Kangjie Lyu & Yanqiu Peng & He Zheng & Xing Wei & Huan Ren & Li Xiao & Jianbo Wang & David A. Muller & Héctor D. Abruña & Bing Joe Hwang & Junta, 2019. "Synergistic Mn-Co catalyst outperforms Pt on high-rate oxygen reduction for alkaline polymer electrolyte fuel cells," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    14. Wang, Yubo & Quan, Zhenhua & Zhao, Yaohua & Wang, Lincheng & Liu, Zichu, 2022. "Performance and optimization of a novel solar-air source heat pump building energy supply system with energy storage," Applied Energy, Elsevier, vol. 324(C).
    15. Chung, Yonsoo & Kim, Beom-Jae & Yeo, Yeong-Koo & Song, Hyung Keun, 1997. "Optimal design of a chemical heat pump using the 2-propanol/acetone/hydrogen system," Energy, Elsevier, vol. 22(5), pages 525-536.
    16. Zhao, Qin & Zhang, Houcheng & Hu, Ziyang & Li, Yangyang, 2021. "An alkaline fuel cell/direct contact membrane distillation hybrid system for cogenerating electricity and freshwater," Energy, Elsevier, vol. 225(C).
    17. Demir, Hasan & Mobedi, Moghtada & Ülkü, Semra, 2008. "A review on adsorption heat pump: Problems and solutions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(9), pages 2381-2403, December.
    18. You, Xinqiang & Rodriguez-Donis, Ivonne & Gerbaud, Vincent, 2016. "Reducing process cost and CO2 emissions for extractive distillation by double-effect heat integration and mechanical heat pump," Applied Energy, Elsevier, vol. 166(C), pages 128-140.
    19. Xu, Min & Cai, Jun & Guo, Jiangfeng & Huai, Xiulan & Liu, Zhigang & Zhang, Hang, 2017. "Technical and economic feasibility of the Isopropanol-Acetone-Hydrogen chemical heat pump based on a lab-scale prototype," Energy, Elsevier, vol. 139(C), pages 1030-1039.
    20. Guo, Jiangfeng & Huai, Xiulan & Li, Xunfeng & Xu, Mingtian, 2012. "Performance analysis of Isopropanol–Acetone–Hydrogen chemical heat pump," Applied Energy, Elsevier, vol. 93(C), pages 261-267.
    21. Han, Yuan & Lai, Cong & Li, Jiarui & Zhang, Zhufeng & Zhang, Houcheng & Hou, Shujin & Wang, Fu & Zhao, Jiapei & Zhang, Chunfei & Miao, He & Yuan, Jinliang, 2022. "Elastocaloric cooler for waste heat recovery from proton exchange membrane fuel cells," Energy, Elsevier, vol. 238(PA).
    22. Kong, Hui & Wang, Jian & Zheng, Hongfei & Wang, Hongsheng & Zhang, Jun & Yu, Zhufeng & Bo, Zheng, 2022. "Techno-economic analysis of a solar thermochemical cycle-based direct coal liquefaction system for low-carbon oil production," Energy, Elsevier, vol. 239(PC).
    23. Tan, Zhimin & Feng, Xiao & Yang, Minbo & Wang, Yufei, 2022. "Energy and economic performance comparison of heat pump and power cycle in low grade waste heat recovery," Energy, Elsevier, vol. 260(C).
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