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Development of a membrane-less microfluidic thermally regenerative ammonia battery

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  • Vicari, Fabrizio
  • Galia, Alessandro
  • Scialdone, Onofrio

Abstract

Thermally regenerative ammonia battery is a promising approach to make use of waste heat and generate electrical energy. However, according to literature, the price of the energy obtained by this device is much higher than alternative renewable technologies (such as wind, solar, geothermal, etc.). To make the process more viable for applicative purposes, it would be necessary to reduce dramatically the cost of the membrane or to avoid it. Hence, the aim of the present work is to increase the economic figures of thermally regenerative ammonia battery avoiding the use of membranes. It was concluded that this result can be obtained by developing the process in a microfluidic flow cell with laminar flow conditions. In particular, it has been demonstrated for the first time that it is possible to obtain quite high power densities in the absence of a membrane in a micro cell. By operating the process at proper flow rates and inter-electrode distances, the membrane-less microfluidic thermally regenerative ammonia battery allowed to achieve even higher power densities than conventional TRAB operated under batch mode and similar operating conditions. In addition, it was shown that the process can be improved using copper deposited on carbon electrodes and moderate temperatures. In fact, at 50 °C a power density of 73.4 W m−2 was obtained.

Suggested Citation

  • Vicari, Fabrizio & Galia, Alessandro & Scialdone, Onofrio, 2021. "Development of a membrane-less microfluidic thermally regenerative ammonia battery," Energy, Elsevier, vol. 225(C).
    • Handle: RePEc:eee:energy:v:225:y:2021:i:c:s0360544221004709
    DOI: 10.1016/j.energy.2021.120221
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    References listed on IDEAS

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    1. Tamburini, A. & Tedesco, M. & Cipollina, A. & Micale, G. & Ciofalo, M. & Papapetrou, M. & Van Baak, W. & Piacentino, A., 2017. "Reverse electrodialysis heat engine for sustainable power production," Applied Energy, Elsevier, vol. 206(C), pages 1334-1353.
    2. Lu, Xu & Leung, Dennis Y.C. & Wang, Huizhi & Maroto-Valer, M. Mercedes & Xuan, Jin, 2016. "A pH-differential dual-electrolyte microfluidic electrochemical cells for CO2 utilization," Renewable Energy, Elsevier, vol. 95(C), pages 277-285.
    3. Anthony P. Straub & Ngai Yin Yip & Shihong Lin & Jongho Lee & Menachem Elimelech, 2016. "Harvesting low-grade heat energy using thermo-osmotic vapour transport through nanoporous membranes," Nature Energy, Nature, vol. 1(7), pages 1-6, July.
    4. Michael Papapetrou & George Kosmadakis & Francesco Giacalone & Bartolomé Ortega-Delgado & Andrea Cipollina & Alessandro Tamburini & Giorgio Micale, 2019. "Evaluation of the Economic and Environmental Performance of Low-Temperature Heat to Power Conversion using a Reverse Electrodialysis – Multi-Effect Distillation System," Energies, MDPI, vol. 12(17), pages 1-26, August.
    5. Quoilin, Sylvain & Broek, Martijn Van Den & Declaye, Sébastien & Dewallef, Pierre & Lemort, Vincent, 2013. "Techno-economic survey of Organic Rankine Cycle (ORC) systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 168-186.
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    1. Cross, Nicholas R. & Rau, Matthew J. & Lvov, Serguei N. & Gorski, Christopher A. & Logan, Bruce E. & Hall, Derek M., 2023. "System efficiency and power assessment of the all-aqueous copper thermally regenerative ammonia battery," Applied Energy, Elsevier, vol. 339(C).

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