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Biocrude oil and hydrochar production and characterization obtained from hydrothermal liquefaction of microalgae in methanol-water system

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  • Masoumi, Shima
  • Boahene, Philip E.
  • Dalai, Ajay K.

Abstract

Hydrothermal liquefaction of microalgae under milder reaction conditions was studied for the production and characterization of high quality biocrude oil and hydrochar confirming its feasibility as sustainable biofuel source. The present study investigates the effects of solvents, temperature and time on the yield of biocrude oil. The comparatively higher yield of biocrude oil (47 wt%) obtained in methanol-water mass ratio of 0.75:0.25 also contained higher amount of ester components resulting in higher biocrude oil quality. Methanol-water co-solvent favored higher biocrude oil yield with lower nitrogen and oxygen contents as compared to pure water. Response surface methodology was applied to study the effects of temperature (222–322 °C), and reaction time (10–60min) at constant pressure of 11.5 MPa for methanol-water and biomass-solvent ratios of 0.75:0.25 and 1:5, respectively. The optimum yield of biocrude oil (57.8 wt%) and highest energy recovery (85.3%) was obtained with 75 wt% of methanol in water at 272 °C and reaction time of 35 min. Subcritical condition (temperature of 222 °C, pressure of 11.5 MPa) resulted in the highest hydrochar yield (19.5 wt%). Hydrochars were also characterized by CHNS, BET, FT-IR and TGA techniques to ascertain their prospective elemental composition, textural properties, functional groups as well as thermal stability.

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  • Masoumi, Shima & Boahene, Philip E. & Dalai, Ajay K., 2021. "Biocrude oil and hydrochar production and characterization obtained from hydrothermal liquefaction of microalgae in methanol-water system," Energy, Elsevier, vol. 217(C).
    • Handle: RePEc:eee:energy:v:217:y:2021:i:c:s0360544220324518
    DOI: 10.1016/j.energy.2020.119344
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    1. Lai, Fa-ying & Chang, Yan-chao & Huang, Hua-jun & Wu, Guo-qiang & Xiong, Jiang-bo & Pan, Zi-qian & Zhou, Chun-fei, 2018. "Liquefaction of sewage sludge in ethanol-water mixed solvents for bio-oil and biochar products," Energy, Elsevier, vol. 148(C), pages 629-641.
    2. Feng, Huan & Zhang, Bo & He, Zhixia & Wang, Shuang & Salih, Osman & Wang, Qian, 2018. "Study on co-liquefaction of Spirulina and Spartina alterniflora in ethanol-water co-solvent for bio-oil," Energy, Elsevier, vol. 155(C), pages 1093-1101.
    3. Toor, Saqib Sohail & Rosendahl, Lasse & Rudolf, Andreas, 2011. "Hydrothermal liquefaction of biomass: A review of subcritical water technologies," Energy, Elsevier, vol. 36(5), pages 2328-2342.
    4. Gollakota, A.R.K. & Kishore, Nanda & Gu, Sai, 2018. "A review on hydrothermal liquefaction of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1378-1392.
    5. Galadima, Ahmad & Muraza, Oki, 2018. "Hydrothermal liquefaction of algae and bio-oil upgrading into liquid fuels: Role of heterogeneous catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1037-1048.
    6. Dimitriadis, Athanasios & Bezergianni, Stella, 2017. "Hydrothermal liquefaction of various biomass and waste feedstocks for biocrude production: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 113-125.
    7. Chiaramonti, David & Prussi, Matteo & Buffi, Marco & Rizzo, Andrea Maria & Pari, Luigi, 2017. "Review and experimental study on pyrolysis and hydrothermal liquefaction of microalgae for biofuel production," Applied Energy, Elsevier, vol. 185(P2), pages 963-972.
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    2. Al-Jabri, Hareb & Das, Probir & Khan, Shoyeb & AbdulQuadir, Mohammad & Thaher, Mehmoud Ibrahim & Hoekman, Kent & Hawari, Alaa H., 2022. "A comparison of bio-crude oil production from five marine microalgae – Using life cycle analysis," Energy, Elsevier, vol. 251(C).
    3. Wądrzyk, Mariusz & Korzeniowski, Łukasz & Plata, Marek & Janus, Rafał & Lewandowski, Marek & Michalik, Marek & Magdziarz, Aneta, 2023. "Pyrolysis of hydrochars obtained from blackcurrant pomace in single and binary solvent systems," Renewable Energy, Elsevier, vol. 214(C), pages 383-394.
    4. Ratha, Sachitra Kumar & Renuka, Nirmal & Abunama, Taher & Rawat, Ismail & Bux, Faizal, 2022. "Hydrothermal liquefaction of algal feedstocks: The effect of biomass characteristics and extraction solvents," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).

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