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Energy and exergy analyses of a new integrated thermochemical copper-chlorine cycle for hydrogen production

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  • Razi, Faran
  • Dincer, Ibrahim
  • Gabriel, Kamiel

Abstract

This paper presents a thermodynamic study on a newly built lab-scale thermochemical copper-chlorine (Cu-Cl) cycle installed at the Clean Energy Research Laboratory (CERL) at the Ontario Tech University. This study analyzes every component of the system through energy and exergy analysis by considering the heat inputs, outputs and exergy destruction within the various units of the Cu–Cl cycle. The system is modeled and simulated using the Aspen-plus software. The mass, energy and exergy balance equations for each system component are written for analysis and assessment purposes. Based on the analysis, the maximum heat input is required for the hydrolysis reactor while the HCl-condenser-1 is found to reject the maximum heat. The results suggest that the thermolysis reactor experienced the highest exergy destruction. The effect of the flow rates of certain species within the cycle on the performance of various system units, such as heat transfer rates and production flow rates are also investigated. The overall energy and exergy efficiencies of the system are evaluated to be 6.8% and 10.4%, respectively.

Suggested Citation

  • Razi, Faran & Dincer, Ibrahim & Gabriel, Kamiel, 2020. "Energy and exergy analyses of a new integrated thermochemical copper-chlorine cycle for hydrogen production," Energy, Elsevier, vol. 205(C).
    • Handle: RePEc:eee:energy:v:205:y:2020:i:c:s0360544220310926
    DOI: 10.1016/j.energy.2020.117985
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    References listed on IDEAS

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    1. Ozbilen, Ahmet & Dincer, Ibrahim & Rosen, Marc A., 2014. "Development of new heat exchanger network designs for a four-step Cu–Cl cycle for hydrogen production," Energy, Elsevier, vol. 77(C), pages 338-351.
    2. Ishaq, H. & Dincer, I. & Naterer, G.F., 2019. "Exergy and cost analyses of waste heat recovery from furnace cement slag for clean hydrogen production," Energy, Elsevier, vol. 172(C), pages 1243-1253.
    3. Yilmaz, Fatih & Selbaş, Reşat, 2017. "Thermodynamic performance assessment of solar based Sulfur-Iodine thermochemical cycle for hydrogen generation," Energy, Elsevier, vol. 140(P1), pages 520-529.
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    3. Fan, Guangli & Ahmadi, A. & Ehyaei, M.A. & Das, Biplab, 2021. "Energy, exergy, economic and exergoenvironmental analyses of polygeneration system integrated gas cycle, absorption chiller, and Copper-Chlorine thermochemical cycle to produce power, cooling, and hyd," Energy, Elsevier, vol. 222(C).
    4. Sadeghi, Shayan & Ghandehariun, Samane & Rosen, Marc A., 2023. "Waste heat recovery potential in the thermochemical copper–chlorine cycle for hydrogen production: Development of an efficient and cost-effective heat exchanger network," Energy, Elsevier, vol. 282(C).
    5. Tariq, Shahzeb & Safder, Usman & Yoo, ChangKyoo, 2022. "Exergy-based weighted optimization and smart decision-making for renewable energy systems considering economics, reliability, risk, and environmental assessments," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    6. Razi, Faran & Dincer, Ibrahim & Gabriel, Kamiel, 2021. "Exergoenvironmental analysis of the integrated copper-chlorine cycle for hydrogen production," Energy, Elsevier, vol. 226(C).
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    9. Gollangi, Raju & K, NagamalleswaraRao, 2022. "Energy, exergy analysis of conceptually designed monochloromethane production process from hydrochlorination of methanol," Energy, Elsevier, vol. 239(PA).
    10. AlZahrani, Abdullah A. & Dincer, Ibrahim, 2022. "Assessment of a thin-electrolyte solid oxide cell for hydrogen production," Energy, Elsevier, vol. 243(C).
    11. Azarpour, Abbas & Mohamadi-Baghmolaei, Mohamad & Hajizadeh, Abdollah & Zendehboudi, Sohrab, 2022. "Systematic energy and exergy assessment of a hydropurification process: Theoretical and practical insights," Energy, Elsevier, vol. 239(PC).
    12. Singh, Neeraj Kumar & Kumari, Priyanka & Singh, Rajesh, 2021. "Intensified hydrogen yield using hydrogenase rich sulfate-reducing bacteria in bio-electrochemical system," Energy, Elsevier, vol. 219(C).
    13. Temiz, Mert & Dincer, Ibrahim, 2021. "Concentrated solar driven thermochemical hydrogen production plant with thermal energy storage and geothermal systems," Energy, Elsevier, vol. 219(C).

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