IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v189y2019ics0360544219318845.html
   My bibliography  Save this article

Syngas: Derived from biodiesel and its influence on CI engine

Author

Listed:
  • Ramalingam, Senthil
  • Ezhumalai, Manikandan
  • Govindasamy, Mohan

Abstract

Nowadays biodiesel usage is widely adopted in internal combustion engine because of availability and lower exhaust emissions. During the biodiesel production around 10% glycerol is obtained as a byproduct, and this can be efficiently used in CI engines. In this paper the crude glycerol obtained from the trans-esterification process of biodiesel is used to produce hydrogen enriched syngas, through water mixture by directly injecting it into a fast thermal cracking reactor at different temperature such as 600 °C, 650 °C, 700 °C and 750 °C. The yield of syngas at different temperatures and different glycerol-water proportions are analyzed. It is seen that the addition of water has improved the syngas yield and also increased the proportion of hydrogen in the syngas up to 80%. Further the performance and emission study of the syngas in a compression ignition engine showed significant reduction in smoke and NO emission simultaneously.

Suggested Citation

  • Ramalingam, Senthil & Ezhumalai, Manikandan & Govindasamy, Mohan, 2019. "Syngas: Derived from biodiesel and its influence on CI engine," Energy, Elsevier, vol. 189(C).
  • Handle: RePEc:eee:energy:v:189:y:2019:i:c:s0360544219318845
    DOI: 10.1016/j.energy.2019.116189
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219318845
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2019.116189?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Markočič, Elena & Kramberger, Boris & van Bennekom, Joost G. & Jan Heeres, Hero & Vos, John & Knez, Željko, 2013. "Glycerol reforming in supercritical water; a short review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 40-48.
    2. Tan, H.W. & Abdul Aziz, A.R. & Aroua, M.K., 2013. "Glycerol production and its applications as a raw material: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 118-127.
    3. Ong, H.C. & Mahlia, T.M.I. & Masjuki, H.H. & Norhasyima, R.S., 2011. "Comparison of palm oil, Jatropha curcas and Calophyllum inophyllum for biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3501-3515.
    4. Nanda, Malaya R. & Zhang, Yongsheng & Yuan, Zhongshun & Qin, Wensheng & Ghaziaskar, Hassan S. & Xu, Chunbao (Charles), 2016. "Catalytic conversion of glycerol for sustainable production of solketal as a fuel additive: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 1022-1031.
    5. Leoneti, Alexandre Bevilacqua & Aragão-Leoneti, Valquiria & de Oliveira, Sonia Valle Walter Borges, 2012. "Glycerol as a by-product of biodiesel production in Brazil: Alternatives for the use of unrefined glycerol," Renewable Energy, Elsevier, vol. 45(C), pages 138-145.
    6. Sahoo, Bibhuti B. & Saha, Ujjwal K. & Sahoo, Niranjan, 2011. "Theoretical performance limits of a syngas–diesel fueled compression ignition engine from second law analysis," Energy, Elsevier, vol. 36(2), pages 760-769.
    7. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Hezaveh, Hadi, 2014. "Glycerol for renewable acrolein production by catalytic dehydration," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 28-59.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Jiang, Yankun & Chen, Yexin & Xie, Man, 2022. "Effects of blending dissociated methanol gas with the fuel in gasoline engine," Energy, Elsevier, vol. 247(C).
    2. Baraiya, Nikhil A. & Ramanan, Vikram & Nagarajan, Baladandayuthapani & Vegad, Chetankumar S. & Chakravarthy, S.R., 2023. "Dynamic mode decomposition of syngas (H2/CO) flame during transition to high-frequency instability in turbulent combustor," Energy, Elsevier, vol. 263(PD).
    3. Vargas-Salgado, Carlos & Águila-León, Jesús & Alfonso-Solar, David & Malmquist, Anders, 2022. "Simulations and experimental study to compare the behavior of a genset running on gasoline or syngas for small scale power generation," Energy, Elsevier, vol. 244(PA).
    4. Zhong, Shenghui & Xu, Shijie & Bai, Xue-Song & Peng, Zhijun & Zhang, Fan, 2021. "Large eddy simulation of n-heptane/syngas pilot ignition spray combustion: Ignition process, liftoff evolution and pollutant emissions," Energy, Elsevier, vol. 233(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Hezaveh, Hadi, 2014. "Glycerol for renewable acrolein production by catalytic dehydration," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 28-59.
    2. He, Quan (Sophia) & McNutt, Josiah & Yang, Jie, 2017. "Utilization of the residual glycerol from biodiesel production for renewable energy generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 63-76.
    3. Hejna, Aleksander & Kosmela, Paulina & Formela, Krzysztof & Piszczyk, Łukasz & Haponiuk, Józef T., 2016. "Potential applications of crude glycerol in polymer technology–Current state and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 66(C), pages 449-475.
    4. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    5. Cornejo, A. & Barrio, I. & Campoy, M. & Lázaro, J. & Navarrete, B., 2017. "Oxygenated fuel additives from glycerol valorization. Main production pathways and effects on fuel properties and engine performance: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1400-1413.
    6. Okoye, P.U. & Hameed, B.H., 2016. "Review on recent progress in catalytic carboxylation and acetylation of glycerol as a byproduct of biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 558-574.
    7. Kong, Pei San & Aroua, Mohamed Kheireddine & Daud, Wan Mohd Ashri Wan, 2016. "Conversion of crude and pure glycerol into derivatives: A feasibility evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 533-555.
    8. Muhammad Harussani Moklis & Shou Cheng & Jeffrey S. Cross, 2023. "Current and Future Trends for Crude Glycerol Upgrading to High Value-Added Products," Sustainability, MDPI, vol. 15(4), pages 1-30, February.
    9. Mohsin Raza & Abrar Inayat & Basim Abu-Jdayil, 2021. "Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review," Sustainability, MDPI, vol. 13(22), pages 1-27, November.
    10. Louise R. Smith & Mark Douthwaite & Karl Mugford & Nicholas F. Dummer & David J. Willock & Graham J. Hutchings & Stuart H. Taylor, 2022. "Recent Advances on the Valorization of Glycerol into Alcohols," Energies, MDPI, vol. 15(17), pages 1-22, August.
    11. Varatharajan, K. & Cheralathan, M., 2012. "Influence of fuel properties and composition on NOx emissions from biodiesel powered diesel engines: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3702-3710.
    12. Sittijunda, Sureewan & Reungsang, Alissara, 2020. "Valorization of crude glycerol into hydrogen, 1,3-propanediol, and ethanol in an up-flow anaerobic sludge blanket (UASB) reactor under thermophilic conditions," Renewable Energy, Elsevier, vol. 161(C), pages 361-372.
    13. Cadavez, Carina Crisp & de Souza-Santos, Marcio L., 2021. "Efficiency of a power generation alternative regarding the composition of feeding biomass-glycerol slurry; theoretical assessment," Energy, Elsevier, vol. 214(C).
    14. Subramaniam, D. & Murugesan, A. & Avinash, A. & Kumaravel, A., 2013. "Bio-diesel production and its engine characteristics—An expatiate view," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 361-370.
    15. Charlotte Stead & Zia Wadud & Chris Nash & Hu Li, 2019. "Introduction of Biodiesel to Rail Transport: Lessons from the Road Sector," Sustainability, MDPI, vol. 11(3), pages 1-20, February.
    16. Mahlia, T.M.I. & Syazmi, Z.A.H.S. & Mofijur, M. & Abas, A.E. Pg & Bilad, M.R. & Ong, Hwai Chyuan & Silitonga, A.S., 2020. "Patent landscape review on biodiesel production: Technology updates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).
    17. Arumugam, A. & Ponnusami, V., 2014. "Biodiesel production from Calophyllum inophyllum oil using lipase producing Rhizopus oryzae cells immobilized within reticulated foams," Renewable Energy, Elsevier, vol. 64(C), pages 276-282.
    18. Jafarmadar, Samad & Nemati, Peyman, 2017. "Analysis of Exhaust Gas Recirculation (EGR) effects on exergy terms in an engine operating with diesel oil and hydrogen," Energy, Elsevier, vol. 126(C), pages 746-755.
    19. Blanco-Marigorta, A.M. & Suárez-Medina, J. & Vera-Castellano, A., 2013. "Exergetic analysis of a biodiesel production process from Jatropha curcas," Applied Energy, Elsevier, vol. 101(C), pages 218-225.
    20. Ishola, Mofoluwake M. & Brandberg, Tomas & Sanni, Sikiru A. & Taherzadeh, Mohammad J., 2013. "Biofuels in Nigeria: A critical and strategic evaluation," Renewable Energy, Elsevier, vol. 55(C), pages 554-560.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:189:y:2019:i:c:s0360544219318845. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.