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Water adsorption on the coated aluminum sheets by composite materials (LiCl + LiBr)/silica gel

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  • Entezari, Akram
  • Ge, T.S.
  • Wang, R.Z.

Abstract

The desiccants made by confined salt in a porous matrix (CSPM) were proposed in the 1990s. Profiting off of a high sorption capacity and a low regeneration temperature made this field very interesting research topic. In absorption refrigeration cycles, adopting multi salts has been investigated widely. LiCl and LiBr are known for their high water adsorption capacity. The combinations of these two salts might be a tool for an intentional modification of CSPMs too. In this study, different ratios of these two salts were impregnated into silica gel pores. The textural properties, water sorption isotherms, and kinetics were analyzed. Four mathematical models were applied for estimating dynamic sorption coefficients. SIM and LDF were well-fitted to describe kinetics. The results showed that impregnated salts molar ratios affect the sorption characteristics. Adding a small amount of LiBr to the LiCl composites intensifies the sorption capacity up to 5.5% while adding LiCl to LiBr decrease this parameter by 12.7%. Besides, a mathematical simulation was used to estimate their performance in a real desiccant cooling heat exchanger. For a standard cooling and dehumidification conditions, the simulation results showed that the binary salt composites might improve the dehumidification if a proper salts ratio was selected.

Suggested Citation

  • Entezari, Akram & Ge, T.S. & Wang, R.Z., 2018. "Water adsorption on the coated aluminum sheets by composite materials (LiCl + LiBr)/silica gel," Energy, Elsevier, vol. 160(C), pages 64-71.
  • Handle: RePEc:eee:energy:v:160:y:2018:i:c:p:64-71
    DOI: 10.1016/j.energy.2018.06.210
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    References listed on IDEAS

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    1. Ge, T.S. & Dai, Y.J. & Wang, R.Z. & Peng, Z.Z., 2010. "Experimental comparison and analysis on silica gel and polymer coated fin-tube heat exchangers," Energy, Elsevier, vol. 35(7), pages 2893-2900.
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    3. L. G. Gordeeva & Yu. I. Aristov, 2012. "Composites ‘salt inside porous matrix’ for adsorption heat transformation: a current state-of-the-art and new trends," International Journal of Low-Carbon Technologies, Oxford University Press, vol. 7(4), pages 288-302, April.
    4. Ge, T.S. & Dai, Y.J. & Li, Y. & Wang, R.Z., 2012. "Simulation investigation on solar powered desiccant coated heat exchanger cooling system," Applied Energy, Elsevier, vol. 93(C), pages 532-540.
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    Cited by:

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    5. Mohamed Zbair & Simona Bennici, 2021. "Survey Summary on Salts Hydrates and Composites Used in Thermochemical Sorption Heat Storage: A Review," Energies, MDPI, vol. 14(11), pages 1-33, May.
    6. Karol Sztekler & Wojciech Kalawa & Łukasz Mika & Agata Mlonka-Medrala & Marcin Sowa & Wojciech Nowak, 2021. "Effect of Additives on the Sorption Kinetics of a Silica Gel Bed in Adsorption Chiller," Energies, MDPI, vol. 14(4), pages 1-13, February.
    7. Vivekh, P. & Bui, D.T. & Wong, Y. & Kumja, M. & Chua, K.J., 2019. "Performance evaluation of PVA-LiCl coated heat exchangers for next-generation of energy-efficient dehumidification," Applied Energy, Elsevier, vol. 237(C), pages 733-750.
    8. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2022. "Salt hydrate–based gas-solid thermochemical energy storage: Current progress, challenges, and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).

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