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Superheat limit and micro-explosion in droplets of hydrous ethanol-diesel emulsions at atmospheric pressure and diesel-like conditions

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  • Zhang, Xiaoqing
  • Li, Tie
  • Wang, Bin
  • Wei, Yijie

Abstract

Micro-explosion of emulsified fuels has been studied on promoting the secondary break-up and improving fuel-air mixing. However, most studies are limited to atmospheric conditions, and experimental observation of micro-explosion under diesel-like conditions is rarely reported. The predictive model for the superheat limit of hydrous ethanol-diesel emulsion needs to be re-examined. In this study, firstly, with the molecular kinetics theory a mathematical model for predicting the superheat limit of hydrous ethanol diesel emulsions are established. Then, the model is verified by the experimental results of micro-explosion in the emulsion droplets. The superheat limit is independent of volume fraction of hydrous ethanol in the emulsions. The intensity of micro-explosion obeys the parabolic rule when changing volume fraction of the hydrous ethanol. The intensity of micro-explosion with the homogeneous nucleation is higher than with the heterogeneous nucleation. The emulsions of 30% and 40% hydrous ethanol exhibit the higher probability for the homogeneous nucleation than the other emulsions. Finally, the droplet behaviors of the emulsions under the diesel-like high-pressure conditions are experimentally observed. While the micro-explosions can be clearly observed for some droplets, neither the micro-explosion nor puffing are observable for most other droplets. The mechanism behind the phenomena is discussed.

Suggested Citation

  • Zhang, Xiaoqing & Li, Tie & Wang, Bin & Wei, Yijie, 2018. "Superheat limit and micro-explosion in droplets of hydrous ethanol-diesel emulsions at atmospheric pressure and diesel-like conditions," Energy, Elsevier, vol. 154(C), pages 535-543.
  • Handle: RePEc:eee:energy:v:154:y:2018:i:c:p:535-543
    DOI: 10.1016/j.energy.2018.04.176
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    References listed on IDEAS

    as
    1. Mahla, S.K. & Dhir, Amit & Gill, Kanwar J.S. & Cho, Haeng Muk & Lim, Hee Chang & Chauhan, Bhupendra Singh, 2018. "Influence of EGR on the simultaneous reduction of NOx-smoke emissions trade-off under CNG-biodiesel dual fuel engine," Energy, Elsevier, vol. 152(C), pages 303-312.
    2. Rajesh Kumar, B. & Saravanan, S., 2016. "Use of higher alcohol biofuels in diesel engines: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 84-115.
    3. Watanabe, Hirotatsu & Suzuki, Yoshiyuki & Harada, Takuji & Matsushita, Yohsuke & Aoki, Hideyuki & Miura, Takatoshi, 2010. "An experimental investigation of the breakup characteristics of secondary atomization of emulsified fuel droplet," Energy, Elsevier, vol. 35(2), pages 806-813.
    4. Megaritis, A. & Yap, D. & Wyszynski, M.L., 2007. "Effect of water blending on bioethanol HCCI combustion with forced induction and residual gas trapping," Energy, Elsevier, vol. 32(12), pages 2396-2400.
    5. Yang, S.I. & Wu, M.S. & Hsu, T.C., 2017. "Spray combustion characteristics of kerosene/bio-oil part I: Experimental study," Energy, Elsevier, vol. 119(C), pages 26-36.
    6. Chauhan, Bhupendra Singh & Kumar, Naveen & Cho, Haeng Muk & Lim, Hee Chang, 2013. "A study on the performance and emission of a diesel engine fueled with Karanja biodiesel and its blends," Energy, Elsevier, vol. 56(C), pages 1-7.
    7. Noorollahi, Yaser & Azadbakht, Mohsen & Ghobadian, Barat, 2018. "The effect of different diesterol (diesel–biodiesel–ethanol) blends on small air-cooled diesel engine performance and its exhaust gases," Energy, Elsevier, vol. 142(C), pages 196-200.
    8. Zhang, Yu & Huang, Ronghua & Huang, Yuhan & Huang, Sheng & Ma, Yinjie & Xu, Shijie & Zhou, Pei, 2018. "Effect of ambient temperature on the puffing characteristics of single butanol-hexadecane droplet," Energy, Elsevier, vol. 145(C), pages 430-441.
    9. Yang, S.I. & Wu, M.S. & Wu, C.Y., 2014. "Application of biomass fast pyrolysis part I: Pyrolysis characteristics and products," Energy, Elsevier, vol. 66(C), pages 162-171.
    10. Lee, Sanghoon & Lee, Chang Sik & Park, Sungwook & Gupta, Jai Gopal & Maurya, Rakesh Kumar & Agarwal, Avinash Kumar, 2017. "Spray characteristics, engine performance and emissions analysis for Karanja biodiesel and its blends," Energy, Elsevier, vol. 119(C), pages 138-151.
    11. Wu, M.S. & Yang, S.I., 2016. "Combustion characteristics of multi-component cedar bio-oil/kerosene droplet," Energy, Elsevier, vol. 113(C), pages 788-795.
    12. Campos-Fernández, Javier & Arnal, Juan M. & Gómez, Jose & Dorado, M. Pilar, 2012. "A comparison of performance of higher alcohols/diesel fuel blends in a diesel engine," Applied Energy, Elsevier, vol. 95(C), pages 267-275.
    Full references (including those not matched with items on IDEAS)

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    7. Anastasia Islamova & Pavel Tkachenko & Nikita Shlegel & Genii Kuznetsov, 2023. "Secondary Atomization of Fuel Oil and Fuel Oil/Water Emulsion through Droplet-Droplet Collisions and Impingement on a Solid Wall," Energies, MDPI, vol. 16(2), pages 1-27, January.
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