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Influence of alkane working fluid decomposition on supercritical organic Rankine cycle systems

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  • Dai, Xiaoye
  • Shi, Lin
  • An, Qingsong
  • Qian, Weizhong

Abstract

The supercritical Organic Rankine Cycle (ORC) develops rapidly due to its low exergy loss, high thermal efficiency and high work output. The thermal stability of working fluid is the major limitation when selecting the working fluid for high temperature heat sources (150–350 °C). The influence mechanisms of the working fluid decomposition are important considerations when evaluating the thermal stability for ORCs. This study analyzed the influence of alkane working fluid decomposition on ORCs with n-pentane as the test fluid. The compositions of the gaseous and solid products were confirmed by experiments. The experiments and ORC system model were designed to analyze the different influence mechanisms of gaseous and solid products on the ORCs. The results showed that the main influence is the condensation pressure rise caused by non-condensable gases in gaseous decomposition products. Studies on methods for predicting the long-term thermal stability are also significant and merit further work.

Suggested Citation

  • Dai, Xiaoye & Shi, Lin & An, Qingsong & Qian, Weizhong, 2018. "Influence of alkane working fluid decomposition on supercritical organic Rankine cycle systems," Energy, Elsevier, vol. 153(C), pages 422-430.
    • Handle: RePEc:eee:energy:v:153:y:2018:i:c:p:422-430
    DOI: 10.1016/j.energy.2018.04.083
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    References listed on IDEAS

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    Cited by:

    1. Huo, Erguang & Hu, Zheng & Wang, Shukun & Xin, Liyong & Bai, Mengna, 2022. "Thermal decomposition and interaction mechanism of HFC-227ea/n-hexane as a zeotropic working fluid for organic Rankine cycle," Energy, Elsevier, vol. 246(C).
    2. Costante M. Invernizzi & Abubakr Ayub & Gioele Di Marcoberardino & Paolo Iora, 2019. "Pure and Hydrocarbon Binary Mixtures as Possible Alternatives Working Fluids to the Usual Organic Rankine Cycles Biomass Conversion Systems," Energies, MDPI, vol. 12(21), pages 1-17, October.
    3. Song, Chongzhi & Gu, Mingyan & Miao, Zheng & Liu, Chao & Xu, Jinliang, 2019. "Effect of fluid dryness and critical temperature on trans-critical organic Rankine cycle," Energy, Elsevier, vol. 174(C), pages 97-109.
    4. Hui-Xing, Zhai & Wei, Dong & Lin, Shi & Qing-Song, An & Sui-Lin, Wang & Bao-Lin, An, 2022. "Theoretical selection criteria of organic Rankine cycle form for different heat sources," Energy, Elsevier, vol. 238(PC).

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