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Defluidization of the oxygen carrier ilmenite – Laboratory experiments with potassium salts

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  • Zevenhoven, Maria
  • Sevonius, Christoffer
  • Salminen, Patrik
  • Lindberg, Daniel
  • Brink, Anders
  • Yrjas, Patrik
  • Hupa, Leena

Abstract

Use of biomass in combustion and subsequent CO2 capture ideally lead to negative CO2 emissions. New techniques for biomass conversion are Chemical Looping Combustion of Biomass (Bio-CLC) and Oxygen Carrier Aided Combustion (OCAC). In both techniques, the ash-forming elements of biomass, mainly consisting of potassium, calcium, sulfur, phosphorus, and chlorine, may interact with the oxygen carrier bed material, causing agglomeration and defluidization, and thus inhibit the oxidation/reduction reactions. The detailed mechanisms behind this effect are not properly understood. Ilmenite, an iron-titanium mineral, is used as an oxygen carrier in both CLC and OCAC.

Suggested Citation

  • Zevenhoven, Maria & Sevonius, Christoffer & Salminen, Patrik & Lindberg, Daniel & Brink, Anders & Yrjas, Patrik & Hupa, Leena, 2018. "Defluidization of the oxygen carrier ilmenite – Laboratory experiments with potassium salts," Energy, Elsevier, vol. 148(C), pages 930-940.
    • Handle: RePEc:eee:energy:v:148:y:2018:i:c:p:930-940
    DOI: 10.1016/j.energy.2018.01.184
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    References listed on IDEAS

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    1. Lyngfelt, Anders, 2014. "Chemical-looping combustion of solid fuels – Status of development," Applied Energy, Elsevier, vol. 113(C), pages 1869-1873.
    2. Ishida, Masaru & Jin, Hongguang, 1994. "A new advanced power-generation system using chemical-looping combustion," Energy, Elsevier, vol. 19(4), pages 415-422.
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    Cited by:

    1. Garcia, Eduardo & Liu, Hao, 2022. "Ilmenite as alternative bed material for the combustion of coal and biomass blends in a fluidised bed combustor to improve combustion performance and reduce agglomeration tendency," Energy, Elsevier, vol. 239(PA).
    2. Li, Fenghai & Li, Yang & Fan, Hongli & Wang, Tao & Guo, Mingxi & Fang, Yitian, 2019. "Investigation on fusion characteristics of deposition from biomass vibrating grate furnace combustion and its modification," Energy, Elsevier, vol. 174(C), pages 724-734.
    3. Jan-Erik Eriksson & Maria Zevenhoven & Patrik Yrjas & Anders Brink & Leena Hupa, 2022. "Corrosion of Heat Transfer Materials by Potassium-Contaminated Ilmenite Bed Particles in Chemical-Looping Combustion of Biomass," Energies, MDPI, vol. 15(8), pages 1-14, April.

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