IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v10y2017i7p864-d102940.html
   My bibliography  Save this article

Numerical Modeling of Oxygen Carrier Performances (NiO/NiAl 2 O 4 ) for Chemical-Looping Combustion

Author

Listed:
  • Lucia Blas

    (LGRE, Laboratoire Gestion des Risques, Environnement 3 bis, rue Alfred Werner, 68093 Mulhouse, France)

  • Patrick Dutournié

    (IS2M, Institut de Sciences des Matériaux de Mulhouse, UMR 7361 CNRS, Université de Strasbourg, Université de Haute Alsace, 3 bis, rue Alfred Werner, 68098 Mulhouse CEDEX, France)

  • Mejdi Jeguirim

    (IS2M, Institut de Sciences des Matériaux de Mulhouse, UMR 7361 CNRS, Université de Strasbourg, Université de Haute Alsace, 3 bis, rue Alfred Werner, 68098 Mulhouse CEDEX, France)

  • Ludovic Josien

    (IS2M, Institut de Sciences des Matériaux de Mulhouse, UMR 7361 CNRS, Université de Strasbourg, Université de Haute Alsace, 3 bis, rue Alfred Werner, 68098 Mulhouse CEDEX, France)

  • David Chiche

    (IFP Energies Nouvelles, Rond-Point de l’échangeur de Solaize, BP 3, 69360 Solaize, France)

  • Stephane Bertholin

    (IFP Energies Nouvelles, Rond-Point de l’échangeur de Solaize, BP 3, 69360 Solaize, France)

  • Arnold Lambert

    (IFP Energies Nouvelles, Rond-Point de l’échangeur de Solaize, BP 3, 69360 Solaize, France)

Abstract

This work was devoted to study experimentally and numerically the oxygen carrier (NiO/NiAl 2 O 4 ) performances for Chemical-Looping Combustion applications. Various kinetic models including Shrinking Core, Nucleation Growth and Modified Volumetric models were investigated in a one-dimensional approach to simulate the reactive mass transfer in a fixed bed reactor. The preliminary numerical results indicated that these models are unable to fit well the fuel breakthrough curves. Therefore, the oxygen carrier was characterized after several operations using Scanning Electronic Microscopy (SEM) coupled with equipped with an energy dispersive X-ray spectrometer (EDX). These analyses showed a layer rich in nickel on particle surface. Below this layer, to a depth of about 10 µm, the material was low in nickel, being the consequence of nickel migration. From these observations, two reactive sites were proposed relative to the layer rich in nickel (particle surface) and the bulk material, respectively. Then, a numerical model, taking into account of both reactive sites, was able to fit well fuel breakthrough curves for all the studied operating conditions. The extracted kinetic parameters showed that the fuel oxidation was fully controlled by the reaction and the effect of temperature was not significant in the tested operating conditions range.

Suggested Citation

  • Lucia Blas & Patrick Dutournié & Mejdi Jeguirim & Ludovic Josien & David Chiche & Stephane Bertholin & Arnold Lambert, 2017. "Numerical Modeling of Oxygen Carrier Performances (NiO/NiAl 2 O 4 ) for Chemical-Looping Combustion," Energies, MDPI, vol. 10(7), pages 1-16, June.
    • Handle: RePEc:gam:jeners:v:10:y:2017:i:7:p:864-:d:102940
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/10/7/864/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/10/7/864/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Lyngfelt, Anders, 2014. "Chemical-looping combustion of solid fuels – Status of development," Applied Energy, Elsevier, vol. 113(C), pages 1869-1873.
    2. Bhave, Amit & Taylor, Richard H.S. & Fennell, Paul & Livingston, William R. & Shah, Nilay & Dowell, Niall Mac & Dennis, John & Kraft, Markus & Pourkashanian, Mohammed & Insa, Mathieu & Jones, Jenny & , 2017. "Screening and techno-economic assessment of biomass-based power generation with CCS technologies to meet 2050 CO2 targets," Applied Energy, Elsevier, vol. 190(C), pages 481-489.
    3. Zhiyong Liang & Wu Qin & Changqing Dong, 2017. "Experimental and Theoretical Study of the Interactions between Fe 2 O 3 /Al 2 O 3 and CO," Energies, MDPI, vol. 10(5), pages 1-15, April.
    4. Han, Lu & Bollas, George M., 2016. "Chemical-looping combustion in a reverse-flow fixed bed reactor," Energy, Elsevier, vol. 102(C), pages 669-681.
    5. Ping Wang & Nicholas Means & Dushyant Shekhawat & David Berry & Mehrdad Massoudi, 2015. "Chemical-Looping Combustion and Gasification of Coals and Oxygen Carrier Development: A Brief Review," Energies, MDPI, vol. 8(10), pages 1-31, September.
    6. Ohlemüller, Peter & Alobaid, Falah & Gunnarsson, Adrian & Ströhle, Jochen & Epple, Bernd, 2015. "Development of a process model for coal chemical looping combustion and validation against 100kWth tests," Applied Energy, Elsevier, vol. 157(C), pages 433-448.
    7. Alobaid, Falah & Ohlemüller, Peter & Ströhle, Jochen & Epple, Bernd, 2015. "Extended Euler–Euler model for the simulation of a 1 MWth chemical–looping pilot plant," Energy, Elsevier, vol. 93(P2), pages 2395-2405.
    8. Ishida, M. & Zheng, D. & Akehata, T., 1987. "Evaluation of a chemical-looping-combustion power-generation system by graphic exergy analysis," Energy, Elsevier, vol. 12(2), pages 147-154.
    9. Ishida, Masaru & Jin, Hongguang, 1994. "A new advanced power-generation system using chemical-looping combustion," Energy, Elsevier, vol. 19(4), pages 415-422.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Carlos Arnaiz del Pozo & Ángel Jiménez Álvaro & Jan Hendrik Cloete & Schalk Cloete & Shahriar Amini, 2020. "Exergy Analysis of Gas Switching Chemical Looping IGCC Plants," Energies, MDPI, vol. 13(3), pages 1-25, January.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Medrano, J.A. & Potdar, I. & Melendez, J. & Spallina, V. & Pacheco-Tanaka, D.A. & van Sint Annaland, M. & Gallucci, F., 2018. "The membrane-assisted chemical looping reforming concept for efficient H2 production with inherent CO2 capture: Experimental demonstration and model validation," Applied Energy, Elsevier, vol. 215(C), pages 75-86.
    2. Zhang, Hao & Liu, Xiangyu & Hong, Hui & Jin, Hongguang, 2018. "Characteristics of a 10 kW honeycomb reactor for natural gas fueled chemical-looping combustion," Applied Energy, Elsevier, vol. 213(C), pages 285-292.
    3. Xu, Lei & Sun, Hongming & Li, Zhenshan & Cai, Ningsheng, 2016. "Experimental study of copper modified manganese ores as oxygen carriers in a dual fluidized bed reactor," Applied Energy, Elsevier, vol. 162(C), pages 940-947.
    4. Bayham, Samuel & McGiveron, Omar & Tong, Andrew & Chung, Elena & Kathe, Mandar & Wang, Dawei & Zeng, Liang & Fan, Liang-Shih, 2015. "Parametric and dynamic studies of an iron-based 25-kWth coal direct chemical looping unit using sub-bituminous coal," Applied Energy, Elsevier, vol. 145(C), pages 354-363.
    5. Medrano, J.A. & Hamers, H.P. & Williams, G. & van Sint Annaland, M. & Gallucci, F., 2015. "NiO/CaAl2O4 as active oxygen carrier for low temperature chemical looping applications," Applied Energy, Elsevier, vol. 158(C), pages 86-96.
    6. Mendiara, T. & García-Labiano, F. & Abad, A. & Gayán, P. & de Diego, L.F. & Izquierdo, M.T. & Adánez, J., 2018. "Negative CO2 emissions through the use of biofuels in chemical looping technology: A review," Applied Energy, Elsevier, vol. 232(C), pages 657-684.
    7. Zhang, Hao & Hong, Hui & Jiang, Qiongqiong & Deng, Ya'nan & Jin, Hongguang & Kang, Qilan, 2018. "Development of a chemical-looping combustion reactor having porous honeycomb chamber and experimental validation by using NiO/NiAl2O4," Applied Energy, Elsevier, vol. 211(C), pages 259-268.
    8. Siriwardane, Ranjani & Benincosa, William & Riley, Jarrett & Tian, Hanjing & Richards, George, 2016. "Investigation of reactions in a fluidized bed reactor during chemical looping combustion of coal/steam with copper oxide-iron oxide-alumina oxygen carrier," Applied Energy, Elsevier, vol. 183(C), pages 1550-1564.
    9. Basavaraja, R.J. & Jayanti, S., 2015. "Viability of fuel switching of a gas-fired power plant operating in chemical looping combustion mode," Energy, Elsevier, vol. 81(C), pages 213-221.
    10. Fan, Junming & Zhu, Lin & Hong, Hui & Jiang, Qiongqiong & Jin, Hongguang, 2017. "A thermodynamic and environmental performance of in-situ gasification of chemical looping combustion for power generation using ilmenite with different coals and comparison with other coal-driven powe," Energy, Elsevier, vol. 119(C), pages 1171-1180.
    11. Hsieh, Tien-Lin & Xu, Dikai & Zhang, Yitao & Nadgouda, Sourabh & Wang, Dawei & Chung, Cheng & Pottimurphy, Yaswanth & Guo, Mengqing & Chen, Yu-Yen & Xu, Mingyuan & He, Pengfei & Fan, Liang-Shih & Tong, 2018. "250 kWth high pressure pilot demonstration of the syngas chemical looping system for high purity H2 production with CO2 capture," Applied Energy, Elsevier, vol. 230(C), pages 1660-1672.
    12. Lin, Junjie & Luo, Kun & Wang, Shuai & Sun, Liyan & Fan, Jianren, 2022. "Particle-scale study of coal-direct chemical looping combustion (CLC)," Energy, Elsevier, vol. 250(C).
    13. Sreenivasulu, B. & Gayatri, D.V. & Sreedhar, I. & Raghavan, K.V., 2015. "A journey into the process and engineering aspects of carbon capture technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 1324-1350.
    14. Nandy, Anirban & Loha, Chanchal & Gu, Sai & Sarkar, Pinaki & Karmakar, Malay K. & Chatterjee, Pradip K., 2016. "Present status and overview of Chemical Looping Combustion technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 597-619.
    15. Carlos Arnaiz del Pozo & Ángel Jiménez Álvaro & Jan Hendrik Cloete & Schalk Cloete & Shahriar Amini, 2020. "Exergy Analysis of Gas Switching Chemical Looping IGCC Plants," Energies, MDPI, vol. 13(3), pages 1-25, January.
    16. Zhang, Jinzhi & He, Tao & Wang, Zhiqi & Zhu, Min & Zhang, Ke & Li, Bin & Wu, Jinhu, 2017. "The search of proper oxygen carriers for chemical looping partial oxidation of carbon," Applied Energy, Elsevier, vol. 190(C), pages 1119-1125.
    17. Ströhle, Jochen & Orth, Matthias & Epple, Bernd, 2015. "Chemical looping combustion of hard coal in a 1MWth pilot plant using ilmenite as oxygen carrier," Applied Energy, Elsevier, vol. 157(C), pages 288-294.
    18. Tian, Xin & Zhao, Haibo & Ma, Jinchen, 2017. "Cement bonded fine hematite and copper ore particles as oxygen carrier in chemical looping combustion," Applied Energy, Elsevier, vol. 204(C), pages 242-253.
    19. Huang, Liang & Tang, Mingchen & Fan, Maohong & Cheng, Hansong, 2015. "Density functional theory study on the reaction between hematite and methane during chemical looping process," Applied Energy, Elsevier, vol. 159(C), pages 132-144.
    20. Zevenhoven, Maria & Sevonius, Christoffer & Salminen, Patrik & Lindberg, Daniel & Brink, Anders & Yrjas, Patrik & Hupa, Leena, 2018. "Defluidization of the oxygen carrier ilmenite – Laboratory experiments with potassium salts," Energy, Elsevier, vol. 148(C), pages 930-940.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:10:y:2017:i:7:p:864-:d:102940. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.