IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v87y2010i9p2785-2796.html
   My bibliography  Save this article

Effective transport coefficients in PEM fuel cell catalyst and gas diffusion layers: Beyond Bruggeman approximation

Author

Listed:
  • Das, Prodip K.
  • Li, Xianguo
  • Liu, Zhong-Sheng

Abstract

The Bruggeman approximation has widely been used for estimating the effective conductivity and diffusivity of both the catalyst and gas diffusion layers of polymer electrolyte membrane (PEM) fuel cells. This approximation is based on the Bruggeman's Effective Medium Theory [Bruggeman D. Berechnung verschiedener physikalischer konstanten von heterogenen substanzen. Ann Phys (Leipzig) 1935;24:636-79], which provides empirical correlation for the effective properties of a composite system. Since it is an empirical correlation, a unique correlation based on the Bruggeman approximation does not always hold for the PEM fuel cell effective properties. Rather, the Bruggeman correlation is a cell specific and experiment dependent correlation that depends on structure, phase composition, water saturation, experimental parameters, etc. Further, this correlation needs to be combined with other correlations to estimate the effective diffusivities. In this article, a set of mathematical formulations has been proposed for the effective transport properties in both the catalyst and gas diffusion layers of a PEM fuel cell. The effective conductivity and diffusivity expressions are derived from the mathematical formulations of the Hashin Coated Sphere model [Hashin Z. The elastic moduli of heterogeneous materials. J Appl Mech 1962;29:143-50], which provides an identical mathematical foundation for each of these effective properties rather than an empirical correlation and avoid to use of multiple correlations together. The present model formulations agree well with the results available in literature for the limiting case. Hence, the proposed formulations for the effective transport properties will be a useful estimating tool in the numerical modeling of PEM fuel cells.

Suggested Citation

  • Das, Prodip K. & Li, Xianguo & Liu, Zhong-Sheng, 2010. "Effective transport coefficients in PEM fuel cell catalyst and gas diffusion layers: Beyond Bruggeman approximation," Applied Energy, Elsevier, vol. 87(9), pages 2785-2796, September.
    • Handle: RePEc:eee:appene:v:87:y:2010:i:9:p:2785-2796
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306-2619(09)00197-4
    Download Restriction: Full text for ScienceDirect subscribers only
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Baschuk, J.J. & Li, Xianguo, 2009. "A comprehensive, consistent and systematic mathematical model of PEM fuel cells," Applied Energy, Elsevier, vol. 86(2), pages 181-193, February.
    2. Probert, S. D. & Thomas, C. B., 1979. "Transport properties of some bismuth-antimony alloys," Applied Energy, Elsevier, vol. 5(2), pages 127-140, April.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Durán, E. & Andújar, J.M. & Segura, F. & Barragán, A.J., 2011. "A high-flexibility DC load for fuel cell and solar arrays power sources based on DC-DC converters," Applied Energy, Elsevier, vol. 88(5), pages 1690-1702, May.
    2. Namazi, Mohammadmehdi & Nayebi, Mohammadreza & Isazadeh, Amin & Modarresi, Ali & Marzbali, Iman Ghasemi & Hosseinalipour, Seyed Mostafa, 2022. "Experimental and numerical study of catalytic combustion and pore-scale numerical study of mass diffusion in high porosity fibrous porous media," Energy, Elsevier, vol. 238(PB).
    3. Najiyah Safwa Khashi’ie & Norihan Md Arifin & Ioan Pop, 2020. "Mixed Convective Stagnation Point Flow towards a Vertical Riga Plate in Hybrid Cu-Al 2 O 3 /Water Nanofluid," Mathematics, MDPI, vol. 8(6), pages 1-21, June.
    4. Liu, Huize & Hu, Zunyan & Li, Jianqiu & Xu, Liangfei & Shao, Yangbin & Ouyang, Minggao, 2023. "Investigation on the optimal GDL thickness design for PEMFCs considering channel/rib geometry matching and operating conditions," Energy, Elsevier, vol. 282(C).
    5. Vasile, Nicolò S. & Doherty, Ronan & Monteverde Videla, Alessandro H.A. & Specchia, Stefania, 2016. "3D multi-physics modeling of a gas diffusion electrode for oxygen reduction reaction for electrochemical energy conversion in PEM fuel cells," Applied Energy, Elsevier, vol. 175(C), pages 435-450.
    6. Ferreira, Rui B. & Falcão, D.S. & Oliveira, V.B. & Pinto, A.M.F.R., 2017. "1D+3D two-phase flow numerical model of a proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 203(C), pages 474-495.
    7. Ruzzante, Pascal & Li, Xianguo, 2023. "3D hybrid stochastic reconstruction of catalyst layers in proton exchange membrane fuel cells from 2D images," Energy, Elsevier, vol. 281(C).
    8. Hwang, Jenn-Jiang, 2013. "Thermal control and performance assessment of a proton exchanger membrane fuel cell generator," Applied Energy, Elsevier, vol. 108(C), pages 184-193.
    9. Zamel, Nada & Li, Xianguo & Shen, Jun, 2012. "Numerical estimation of the effective electrical conductivity in carbon paper diffusion media," Applied Energy, Elsevier, vol. 93(C), pages 39-44.
    10. Pan, Mingzhang & Li, Chao & Liao, Jinyang & Lei, Han & Pan, Chengjie & Meng, Xianpan & Huang, Haozhong, 2020. "Design and modeling of PEM fuel cell based on different flow fields," Energy, Elsevier, vol. 207(C).
    11. Zhao, Jian & Shahgaldi, Samaneh & Alaefour, Ibrahim & Xu, Qian & Li, Xianguo, 2018. "Gas permeability of catalyzed electrodes in polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 209(C), pages 203-210.
    12. Shingjiang Jessie Lue & Nai-Yuan Liu & Selvaraj Rajesh Kumar & Kevin Chi-Yang Tseng & Bo-Yan Wang & Chieh-Hsin Leung, 2017. "Experimental and One-Dimensional Mathematical Modeling of Different Operating Parameters in Direct Formic Acid Fuel Cells," Energies, MDPI, vol. 10(12), pages 1-14, November.
    13. Ashorynejad, Hamid Reza & Javaherdeh, Koroush, 2019. "Evaluation of passive and active lattice Boltzmann method for PEM fuel cell modeling," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 535(C).
    14. Aidan Robinson & Prodip K. Das, 2022. "Biomimetic and Constructal Design of Alveolus-Inspired Extended Surfaces for Heat Dispersion," Energies, MDPI, vol. 16(1), pages 1-16, December.
    15. Jiao, Daokuan & Jiao, Kui & Zhong, Shenghui & Du, Qing, 2022. "Investigations on heat and mass transfer in gas diffusion layers of PEMFC with a gas–liquid-solid coupled model," Applied Energy, Elsevier, vol. 316(C).
    16. Zhang, Heng & Xiao, Liusheng & Chuang, Po-Ya Abel & Djilali, Ned & Sui, Pang-Chieh, 2019. "Coupled stress–strain and transport in proton exchange membrane fuel cell with metallic bipolar plates," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    17. Zhang, Hongtao & Li, Xianguo & Liu, Xinzhi & Yan, Jinyue, 2019. "Enhancing fuel cell durability for fuel cell plug-in hybrid electric vehicles through strategic power management," Applied Energy, Elsevier, vol. 241(C), pages 483-490.
    18. Periklis Mountrichas & Wendi Zhao & Mehtab Singh Randeva & Prodip K. Das, 2023. "Entropy Generation of CuO-Water Nanofluid in a Cavity with an Intruded Rectangular Fin," Energies, MDPI, vol. 16(2), pages 1-15, January.
    19. Andersson, M. & Beale, S.B. & Espinoza, M. & Wu, Z. & Lehnert, W., 2016. "A review of cell-scale multiphase flow modeling, including water management, in polymer electrolyte fuel cells," Applied Energy, Elsevier, vol. 180(C), pages 757-778.
    20. Xing, Lei & Das, Prodip K. & Song, Xueguan & Mamlouk, Mohamed & Scott, Keith, 2015. "Numerical analysis of the optimum membrane/ionomer water content of PEMFCs: The interaction of Nafion® ionomer content and cathode relative humidity," Applied Energy, Elsevier, vol. 138(C), pages 242-257.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhao, Jian & Shahgaldi, Samaneh & Alaefour, Ibrahim & Xu, Qian & Li, Xianguo, 2018. "Gas permeability of catalyzed electrodes in polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 209(C), pages 203-210.
    2. Park, Jae Wan & Jiao, Kui & Li, Xianguo, 2010. "Numerical investigations on liquid water removal from the porous gas diffusion layer by reactant flow," Applied Energy, Elsevier, vol. 87(7), pages 2180-2186, July.
    3. Wang, Chin-Tsan & Hu, Yuh-Chung & Zheng, Pei-Lun, 2010. "Novel biometric flow slab design for improvement of PEMFC performance," Applied Energy, Elsevier, vol. 87(4), pages 1366-1375, April.
    4. Wu, Horng-Wen & Ku, Hui-Wen, 2011. "The optimal parameters estimation for rectangular cylinders installed transversely in the flow channel of PEMFC from a three-dimensional PEMFC model and the Taguchi method," Applied Energy, Elsevier, vol. 88(12), pages 4879-4890.
    5. Henriques, T. & César, B. & Branco, P.J. Costa, 2010. "Increasing the efficiency of a portable PEM fuel cell by altering the cathode channel geometry: A numerical and experimental study," Applied Energy, Elsevier, vol. 87(4), pages 1400-1409, April.
    6. Wu, Horng-Wen, 2016. "A review of recent development: Transport and performance modeling of PEM fuel cells," Applied Energy, Elsevier, vol. 165(C), pages 81-106.
    7. Calabriso, Andrea & Borello, Domenico & Romano, Giovanni Paolo & Cedola, Luca & Del Zotto, Luca & Santori, Simone Giovanni, 2017. "Bubbly flow mapping in the anode channel of a direct methanol fuel cell via PIV investigation," Applied Energy, Elsevier, vol. 185(P2), pages 1245-1255.
    8. Ismail, M.S. & Hughes, K.J. & Ingham, D.B. & Ma, L. & Pourkashanian, M., 2012. "Effects of anisotropic permeability and electrical conductivity of gas diffusion layers on the performance of proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 95(C), pages 50-63.
    9. Qin, Yanzhou & Li, Xianguo & Jiao, Kui & Du, Qing & Yin, Yan, 2014. "Effective removal and transport of water in a PEM fuel cell flow channel having a hydrophilic plate," Applied Energy, Elsevier, vol. 113(C), pages 116-126.
    10. Contreras, Alfonso & Posso, Fausto & Guervos, Esther, 2010. "Modelling and simulation of the utilization of a PEM fuel cell in the rural sector of Venezuela," Applied Energy, Elsevier, vol. 87(4), pages 1376-1385, April.
    11. Wang, Yulin & Guan, Chao & Li, Hua & Zhao, Yulong & Wang, Cheng & He, Wei, 2023. "Flow field configuration design for a large-scale hydrogen polymer electrolyte membrane fuel cell," Applied Energy, Elsevier, vol. 351(C).
    12. Hsueh, Ching-Yi & Chu, Hsin-Sen & Yan, Wei-Mon & Chen, Chiun-Hsun, 2010. "Transport phenomena and performance of a plate methanol steam micro-reformer with serpentine flow field design," Applied Energy, Elsevier, vol. 87(10), pages 3137-3147, October.
    13. Perng, Shiang-Wuu & Wu, Horng-Wen, 2011. "Non-isothermal transport phenomenon and cell performance of a cathodic PEM fuel cell with a baffle plate in a tapered channel," Applied Energy, Elsevier, vol. 88(1), pages 52-67, January.
    14. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    15. Perng, Shiang-Wuu & Wu, Horng-Wen, 2010. "Effect of the prominent catalyst layer surface on reactant gas transport and cell performance at the cathodic side of a PEMFC," Applied Energy, Elsevier, vol. 87(4), pages 1386-1399, April.
    16. Yulin Wang & Xiangling Liao & Guokun Liu & Haokai Xu & Chao Guan & Huixuan Wang & Hua Li & Wei He & Yanzhou Qin, 2023. "Review of Flow Field Designs for Polymer Electrolyte Membrane Fuel Cells," Energies, MDPI, vol. 16(10), pages 1-54, May.
    17. Jiao, Kui & Park, Jaewan & Li, Xianguo, 2010. "Experimental investigations on liquid water removal from the gas diffusion layer by reactant flow in a PEM fuel cell," Applied Energy, Elsevier, vol. 87(9), pages 2770-2777, September.
    18. Perng, Shiang-Wuu & Wu, Horng-Wen & Jue, Tswen-Chyuan & Cheng, Kuo-Chih, 2009. "Numerical predictions of a PEM fuel cell performance enhancement by a rectangular cylinder installed transversely in the flow channel," Applied Energy, Elsevier, vol. 86(9), pages 1541-1554, September.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:87:y:2010:i:9:p:2785-2796. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.