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Thin film surface modifications of thin/tunable liquid/gas diffusion layers for high-efficiency proton exchange membrane electrolyzer cells

Author

Listed:
  • Kang, Zhenye
  • Mo, Jingke
  • Yang, Gaoqiang
  • Li, Yifan
  • Talley, Derrick A.
  • Retterer, Scott T.
  • Cullen, David A.
  • Toops, Todd J.
  • Brady, Michael P.
  • Bender, Guido
  • Pivovar, Bryan S.
  • Green, Johney B.
  • Zhang, Feng-Yuan

Abstract

A proton exchange membrane electrolyzer cell (PEMEC) is one of the most promising devices for high-efficiency and low-cost energy storage and ultrahigh purity hydrogen production. As one of the critical components in PEMECs, the titanium thin/tunable LGDL (TT-LGDL) with its advantages of small thickness, planar surface, straight-through pores, and well-controlled pore morphologies, achieved superior multifunctional performance for hydrogen and oxygen production from water splitting even at low temperature. Different thin film surface treatments on the novel TT-LGDLs for enhancing the interfacial contacts and PEMEC performance were investigated both in-situ and ex-situ for the first time. Surface modified TT-LGDLs with about 180nm thick Au thin film yielded performance improvement (voltage reduction), from 1.6849V with untreated TT-LGDLs to only 1.6328V with treated TT-LGDLs at 2.0A/cm2 and 80°C. Furthermore, the hydrogen/oxygen production rate was increased by about 28.2% at 1.60V and 80°C. The durability test demonstrated that the surface treated TT-LGDL has good stability as well. The gold electroplating surface treatment is a promising method for the PEMEC performance enhancement and titanium material protection even in harsh environment.

Suggested Citation

  • Kang, Zhenye & Mo, Jingke & Yang, Gaoqiang & Li, Yifan & Talley, Derrick A. & Retterer, Scott T. & Cullen, David A. & Toops, Todd J. & Brady, Michael P. & Bender, Guido & Pivovar, Bryan S. & Green, Jo, 2017. "Thin film surface modifications of thin/tunable liquid/gas diffusion layers for high-efficiency proton exchange membrane electrolyzer cells," Applied Energy, Elsevier, vol. 206(C), pages 983-990.
    • Handle: RePEc:eee:appene:v:206:y:2017:i:c:p:983-990
    DOI: 10.1016/j.apenergy.2017.09.004
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    1. Siracusano, Stefania & Baglio, Vincenzo & Van Dijk, Nicholas & Merlo, Luca & Aricò, Antonino Salvatore, 2017. "Enhanced performance and durability of low catalyst loading PEM water electrolyser based on a short-side chain perfluorosulfonic ionomer," Applied Energy, Elsevier, vol. 192(C), pages 477-489.
    2. Liao, Yu-Te & Huang, Chao-Wei & Liao, Chi-Hung & Wu, Jeffery C.-S. & Wu, Kevin C.-W., 2012. "Synthesis of mesoporous titania thin films (MTTFs) with two different structures as photocatalysts for generating hydrogen from water splitting," Applied Energy, Elsevier, vol. 100(C), pages 75-80.
    3. Dihrab, Salwan S. & Sopian, K. & Alghoul, M.A. & Sulaiman, M.Y., 2009. "Review of the membrane and bipolar plates materials for conventional and unitized regenerative fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1663-1668, August.
    4. Mo, Jingke & Kang, Zhenye & Yang, Gaoqiang & Retterer, Scott T. & Cullen, David A. & Toops, Todd J. & Green, Johney B. & Zhang, Feng-Yuan, 2016. "Thin liquid/gas diffusion layers for high-efficiency hydrogen production from water splitting," Applied Energy, Elsevier, vol. 177(C), pages 817-822.
    5. Desideri, Umberto & Campana, Pietro Elia, 2014. "Analysis and comparison between a concentrating solar and a photovoltaic power plant," Applied Energy, Elsevier, vol. 113(C), pages 422-433.
    6. Duić, Neven & Guzović, Zvonimir & Kafarov, Vyatcheslav & Klemeš, Jiří Jaromír & Mathiessen, Brian vad & Yan, Jinyue, 2013. "Sustainable development of energy, water and environment systems," Applied Energy, Elsevier, vol. 101(C), pages 3-5.
    7. Oh, Hwanyeong & Park, Jaeman & Min, Kyoungdoug & Lee, Eunsook & Jyoung, Jy-Young, 2015. "Effects of pore size gradient in the substrate of a gas diffusion layer on the performance of a proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 149(C), pages 186-193.
    8. Budt, Marcus & Wolf, Daniel & Span, Roland & Yan, Jinyue, 2016. "A review on compressed air energy storage: Basic principles, past milestones and recent developments," Applied Energy, Elsevier, vol. 170(C), pages 250-268.
    9. Ehteshami, S. Mohsen Mousavi & Vignesh, S. & Rasheed, R.K.A. & Chan, S.H., 2016. "Numerical investigations on ethanol electrolysis for production of pure hydrogen from renewable sources," Applied Energy, Elsevier, vol. 170(C), pages 388-393.
    10. Navasa, Maria & Yuan, Jinliang & Sundén, Bengt, 2015. "Computational fluid dynamics approach for performance evaluation of a solid oxide electrolysis cell for hydrogen production," Applied Energy, Elsevier, vol. 137(C), pages 867-876.
    11. Wang, Junye, 2017. "System integration, durability and reliability of fuel cells: Challenges and solutions," Applied Energy, Elsevier, vol. 189(C), pages 460-479.
    12. Yang, Jie & Yu, Xinhai & An, Lin & Tu, Shan-Tung & Yan, Jinyue, 2017. "CO2 capture with the absorbent of a mixed ionic liquid and amine solution considering the effects of SO2 and O2," Applied Energy, Elsevier, vol. 194(C), pages 9-18.
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