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Synthesis and characterization of geopolymer oxygen carriers for chemical looping combustion

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  • Miccio, Francesco
  • Natali Murri, Annalisa
  • Landi, Elena

Abstract

The present article reports on the first application of geopolymers for the production of oxygen carriers for chemical looping combustion. Granules with different properties and in typical sizes for fluidized bed applications were produced starting from geopolymer/iron oxide slurries. These slurries were prepared according to a previously-developed formulation, modified by adding iron oxides and pore-forming agents to obtain oxygen carriers with different micro- and macrostructures. The performance of these novel oxygen carriers was tested in thermogravimetric equipment, measuring a capacity very close to the theoretical value 1.3 after repeated cycles. Tests conducted in a laboratory-scale differential reactor gave rise to a lower O-carrying capacity (<1.0%), but rather high kinetics (i.e. rate index) by comparison with other materials and published data. The analysis on the sample (ESEM, XRD and MIP) provided a reasonable interpretation of the phenomena observed, attributable mainly to the influence of internal porosity. Fluidization tests, elutriation/attrition results and the lack of any sign of particle agglomeration proved the suitability of the synthesized granules for use in fluidized beds.

Suggested Citation

  • Miccio, Francesco & Natali Murri, Annalisa & Landi, Elena, 2017. "Synthesis and characterization of geopolymer oxygen carriers for chemical looping combustion," Applied Energy, Elsevier, vol. 194(C), pages 136-147.
    • Handle: RePEc:eee:appene:v:194:y:2017:i:c:p:136-147
    DOI: 10.1016/j.apenergy.2017.03.005
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    References listed on IDEAS

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    1. Knutsson, Pavleta & Linderholm, Carl, 2015. "Characterization of ilmenite used as oxygen carrier in a 100kW chemical-looping combustor for solid fuels," Applied Energy, Elsevier, vol. 157(C), pages 368-373.
    2. Siriwardane, Ranjani & Tian, Hanjing & Miller, Duane & Richards, George, 2015. "Fluidized bed testing of commercially prepared MgO-promoted hematite and CuO–Fe2O3 mixed metal oxide oxygen carriers for methane and coal chemical looping combustion," Applied Energy, Elsevier, vol. 157(C), pages 348-357.
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    2. Siriwardane, Ranjani & Riley, Jarrett & Benincosa, William & Bayham, Samuel & Bobek, Michael & Straub, Douglas & Weber, Justin, 2021. "Development of CuFeMnAlO4+δ oxygen carrier with high attrition resistance and 50-kWth methane/air chemical looping combustion tests," Applied Energy, Elsevier, vol. 286(C).
    3. Bendoni, R. & Miccio, F. & Medri, V. & Benito, P. & Vaccari, A. & Landi, E., 2019. "Geopolymer composites for the catalytic cleaning of tar in biomass-derived gas," Renewable Energy, Elsevier, vol. 131(C), pages 1107-1116.
    4. Benincosa, William & Siriwardane, Ranjani & Tian, Hanjing & Riley, Jarrett & Poston, James, 2020. "A particle-scale reduction model of copper iron manganese oxide with CO for chemical looping combustion," Applied Energy, Elsevier, vol. 262(C).

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