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Oxygen transport capacity and kinetic study of ilmenite ores for methane chemical-looping combustion

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  • Khakpoor, Nima
  • Mostafavi, Ehsan
  • Mahinpey, Nader
  • De la Hoz Siegler, Hector

Abstract

Reactivity and oxygen-transport capacity of Canadian and commercial ilmenite ores in the chemical-looping combustion of methane were investigated in a thermogravimetric analyzer (TGA). Oxygen carrier performance was evaluated over multiple cycles during which Canadian ilmenite oxygen transport capacity increased from 2.7% to 14.2% and the commercial sample maintained an approximately constant oxygen transport capacity at 4.5%. XRD and SEM results indicate that new phases were formed, and surface morphology was transformed significantly during cyclic operations. Studies on carbon deposition on the ilmenite surface indicate that lower methane partial pressure and reduction temperatures are favorable to effectively prevent this phenomenon. The kinetic grain model (GM) was found satisfactorily to fit reduction rate data obtained at atmospheric pressure. Intrinsic reaction rates and kinetic parameters were assessed, accordingly. Activation energy were estimated 106.7 ± 10.6 kJ/mol and 95.0 ± 8.5 kJ/mol for the Canadian and commercial samples, respectively.

Suggested Citation

  • Khakpoor, Nima & Mostafavi, Ehsan & Mahinpey, Nader & De la Hoz Siegler, Hector, 2019. "Oxygen transport capacity and kinetic study of ilmenite ores for methane chemical-looping combustion," Energy, Elsevier, vol. 169(C), pages 329-337.
    • Handle: RePEc:eee:energy:v:169:y:2019:i:c:p:329-337
    DOI: 10.1016/j.energy.2018.12.056
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    1. Lu, Chunqiang & Li, Kongzhai & Zhu, Xing & Wei, Yonggang & Li, Lei & Zheng, Min & Fan, Bingbing & He, Fang & Wang, Hua, 2020. "Improved activity of magnetite oxygen carrier for chemical looping steam reforming by ultrasonic treatment," Applied Energy, Elsevier, vol. 261(C).
    2. Güleç, Fatih & Meredith, Will & Sun, Cheng-Gong & Snape, Colin E., 2019. "Selective low temperature chemical looping combustion of higher alkanes with Cu- and Mn- oxides," Energy, Elsevier, vol. 173(C), pages 658-666.
    3. Abad, A. & Pérez-Vega, R. & de Diego, L.F. & Gayán, P. & Izquierdo, M.T. & García-Labiano, F. & Adánez, J., 2019. "Thermochemical assessment of chemical looping assisted by oxygen uncoupling with a MnFe-based oxygen carrier," Applied Energy, Elsevier, vol. 251(C), pages 1-1.

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