IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v163y2016icp41-50.html
   My bibliography  Save this article

Enhancing properties of iron and manganese ores as oxygen carriers for chemical looping processes by dry impregnation

Author

Listed:
  • Haider, S.K.
  • Azimi, G.
  • Duan, L.
  • Anthony, E.J.
  • Patchigolla, K.
  • Oakey, J.E.
  • Leion, H.
  • Mattisson, T.
  • Lyngfelt, A.

Abstract

The use of naturally occurring ores as oxygen carriers in CLC processes is attractive because of their relative abundance and low cost. Unfortunately, they typically exhibit lower reactivity and lack the mechanical robustness required, when compared to synthetically produced carriers. Impregnation is a suitable method for enhancing both the reactivity and durability of natural ores when used as oxygen carriers for CLC systems. This investigation uses impregnation to improve the chemical and mechanical properties of a Brazilian manganese ore and a Canadian iron ore. The manganese ore was impregnated with Fe2O3 and the iron ore was impregnated with Mn2O3 with the goal of forming a combined Fe/Mn oxygen carrier. The impregnated ore’s physical characteristics were assessed by SEM, BET and XRD analysis. Measurements of the attrition resistance and crushing strength were used to investigate the mechanical robustness of the oxygen carriers. The impregnated ore’s mechanical and physical properties were clearly enhanced by the impregnation method, with boosts in crushing strength of 11–26% and attrition resistance of 37–31% for the impregnated iron and manganese ores, respectively. Both the unmodified and impregnated ore’s reactivity, for the conversion of gaseous fuel (CH4 and syngas) and gaseous oxygen release (CLOU potential) were investigated using a bench-scale quartz fluidised-bed reactor. The impregnated iron ore exhibited a greater degree of syngas conversion compared to the other samples examined. Iron ore based oxygen carrier’s syngas conversion increases with the number of oxidation and reduction cycles performed. The impregnated iron ore exhibited gaseous oxygen release over extended periods in an inert atmosphere and remained at a constant 0.2% O2 concentration by volume at the end of this inert period. This oxygen release would help ensure the efficient use of solid fuels. The impregnated iron ore’s reactivity for CH4 conversion was similar to the reactivity of its unmodified counterpart. The unmodified manganese ore converted CH4 to the greatest extent of all the samples tested here, while the impregnated manganese ore exhibited a decrease in reactivity with respect to syngas and CH4 conversion.

Suggested Citation

  • Haider, S.K. & Azimi, G. & Duan, L. & Anthony, E.J. & Patchigolla, K. & Oakey, J.E. & Leion, H. & Mattisson, T. & Lyngfelt, A., 2016. "Enhancing properties of iron and manganese ores as oxygen carriers for chemical looping processes by dry impregnation," Applied Energy, Elsevier, vol. 163(C), pages 41-50.
    • Handle: RePEc:eee:appene:v:163:y:2016:i:c:p:41-50
    DOI: 10.1016/j.apenergy.2015.10.142
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261915013847
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2015.10.142?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Rydén, Magnus & Leion, Henrik & Mattisson, Tobias & Lyngfelt, Anders, 2014. "Combined oxides as oxygen-carrier material for chemical-looping with oxygen uncoupling," Applied Energy, Elsevier, vol. 113(C), pages 1924-1932.
    2. Wang, Jinsheng & Anthony, Edward J., 2008. "Clean combustion of solid fuels," Applied Energy, Elsevier, vol. 85(2-3), pages 73-79, February.
    3. Miller, Duane D. & Siriwardane, Ranjani & Poston, James, 2015. "Fluidized-bed and fixed-bed reactor testing of methane chemical looping combustion with MgO-promoted hematite," Applied Energy, Elsevier, vol. 146(C), pages 111-121.
    4. Imtiaz, Qasim & Broda, Marcin & Müller, Christoph R., 2014. "Structure–property relationship of co-precipitated Cu-rich, Al2O3- or MgAl2O4-stabilized oxygen carriers for chemical looping with oxygen uncoupling (CLOU)," Applied Energy, Elsevier, vol. 119(C), pages 557-565.
    5. Arjmand, Mehdi & Leion, Henrik & Mattisson, Tobias & Lyngfelt, Anders, 2014. "Investigation of different manganese ores as oxygen carriers in chemical-looping combustion (CLC) for solid fuels," Applied Energy, Elsevier, vol. 113(C), pages 1883-1894.
    6. Gu, Haiming & Shen, Laihong & Zhong, Zhaoping & Niu, Xin & Liu, Weidong & Ge, Huijun & Jiang, Shouxi & Wang, Lulu, 2015. "Cement/CaO-modified iron ore as oxygen carrier for chemical looping combustion of coal," Applied Energy, Elsevier, vol. 157(C), pages 314-322.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Do, Jeong Yeon & Son, Namgyu & Park, No-Kuk & Kwak, Byeong Sub & Baek, Jeom-In & Ryu, Ho-Jung & Kang, Misook, 2018. "Reliable oxygen transfer in MgAl2O4 spinel through the reversible formation of oxygen vacancies by Cu2+/Fe3+ anchoring," Applied Energy, Elsevier, vol. 219(C), pages 138-150.
    2. Nakano, Anna & Nakano, Jinichiro & Bennett, James, 2020. "Real-time high temperature investigations of an individual natural hematite ore particle for chemical looping oxygen exchange," Applied Energy, Elsevier, vol. 268(C).
    3. Cho, Won Chul & Lee, Jun Kyu & Nam, Gyeong Duk & Kim, Chang Hee & Cho, Hyun-Seok & Joo, Jong Hoon, 2019. "Degradation analysis of mixed ionic-electronic conductor-supported iron-oxide oxygen carriers for chemical-looping conversion of methane," Applied Energy, Elsevier, vol. 239(C), pages 644-657.
    4. Xing Chen & Shuai Zhang & Rui Xiao & Peng Li, 2017. "Modification of traditionally impregnated Fe 2 O 3 /Al 2 O 3 oxygen carriers by ultrasonic method and their performance in chemical looping combustion," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(1), pages 65-77, February.
    5. Lachén, J. & Herguido, J. & Peña, J.A., 2020. "High purity hydrogen from biogas via steam iron process: Preventing reactor clogging by interspersed coke combustions," Renewable Energy, Elsevier, vol. 151(C), pages 619-626.
    6. Di, Zichen & Yilmaz, Duygu & Biswas, Arijit & Cheng, Fangqin & Leion, Henrik, 2022. "Spinel ferrite-contained industrial materials as oxygen carriers in chemical looping combustion," Applied Energy, Elsevier, vol. 307(C).
    7. Wang, Haiming & Dou, Xiaomin & Veksha, Andrei & Liu, Wen & Giannis, Apostolos & Ge, Liya & Thye Lim, Teik & Lisak, Grzegorz, 2020. "Barium aluminate improved iron ore for the chemical looping combustion of syngas," Applied Energy, Elsevier, vol. 272(C).
    8. Tian, Xin & Zhao, Haibo & Ma, Jinchen, 2017. "Cement bonded fine hematite and copper ore particles as oxygen carrier in chemical looping combustion," Applied Energy, Elsevier, vol. 204(C), pages 242-253.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Lin, Shen & Gu, Zhenhua & Zhu, Xing & Wei, Yonggang & Long, Yanhui & Yang, Kun & He, Fang & Wang, Hua & Li, Kongzhai, 2020. "Synergy of red mud oxygen carrier with MgO and NiO for enhanced chemical-looping combustion," Energy, Elsevier, vol. 197(C).
    2. Di, Zichen & Yilmaz, Duygu & Biswas, Arijit & Cheng, Fangqin & Leion, Henrik, 2022. "Spinel ferrite-contained industrial materials as oxygen carriers in chemical looping combustion," Applied Energy, Elsevier, vol. 307(C).
    3. Gu, Zhenhua & Zhang, Ling & Lu, Chunqiang & Qing, Shan & Li, Kongzhai, 2020. "Enhanced performance of copper ore oxygen carrier by red mud modification for chemical looping combustion," Applied Energy, Elsevier, vol. 277(C).
    4. Galinsky, Nathan & Mishra, Amit & Zhang, Jia & Li, Fanxing, 2015. "Ca1−xAxMnO3 (A=Sr and Ba) perovskite based oxygen carriers for chemical looping with oxygen uncoupling (CLOU)," Applied Energy, Elsevier, vol. 157(C), pages 358-367.
    5. Ping Wang & Nicholas Means & Dushyant Shekhawat & David Berry & Mehrdad Massoudi, 2015. "Chemical-Looping Combustion and Gasification of Coals and Oxygen Carrier Development: A Brief Review," Energies, MDPI, vol. 8(10), pages 1-31, September.
    6. Galinsky, Nathan & Sendi, Marwan & Bowers, Lindsay & Li, Fanxing, 2016. "CaMn1−xBxO3−δ (B=Al, V, Fe, Co, and Ni) perovskite based oxygen carriers for chemical looping with oxygen uncoupling (CLOU)," Applied Energy, Elsevier, vol. 174(C), pages 80-87.
    7. Hu, Wenting & Donat, Felix & Scott, S.A. & Dennis, J.S., 2016. "Kinetics of oxygen uncoupling of a copper based oxygen carrier," Applied Energy, Elsevier, vol. 161(C), pages 92-100.
    8. Xu, Lei & Sun, Hongming & Li, Zhenshan & Cai, Ningsheng, 2016. "Experimental study of copper modified manganese ores as oxygen carriers in a dual fluidized bed reactor," Applied Energy, Elsevier, vol. 162(C), pages 940-947.
    9. Nandy, Anirban & Loha, Chanchal & Gu, Sai & Sarkar, Pinaki & Karmakar, Malay K. & Chatterjee, Pradip K., 2016. "Present status and overview of Chemical Looping Combustion technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 597-619.
    10. Deng, Guixian & Li, Kongzhai & Zhang, Guifang & Gu, Zhenhua & Zhu, Xing & Wei, Yonggang & Wang, Hua, 2019. "Enhanced performance of red mud-based oxygen carriers by CuO for chemical looping combustion of methane," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    11. Tian, Xin & Zhao, Haibo & Ma, Jinchen, 2017. "Cement bonded fine hematite and copper ore particles as oxygen carrier in chemical looping combustion," Applied Energy, Elsevier, vol. 204(C), pages 242-253.
    12. Schmitz, Matthias & Linderholm, Carl Johan, 2016. "Performance of calcium manganate as oxygen carrier in chemical looping combustion of biochar in a 10kW pilot," Applied Energy, Elsevier, vol. 169(C), pages 729-737.
    13. Lei, Zhiping & Yan, Jingchong & Fang, Jia & Shui, Hengfu & Ren, Shibiao & Wang, Zhicai & Li, Zhanku & Kong, Ying & Kang, Shigang, 2021. "Catalytic combustion of coke and NO reduction in-situ under the action of Fe, Fe–CaO and Fe–CeO2," Energy, Elsevier, vol. 216(C).
    14. Kang, Dohyung & Lim, Hyun Suk & Lee, Minbeom & Lee, Jae W., 2018. "Syngas production on a Ni-enhanced Fe2O3/Al2O3 oxygen carrier via chemical looping partial oxidation with dry reforming of methane," Applied Energy, Elsevier, vol. 211(C), pages 174-186.
    15. Li, Shiyuan & Li, Haoyu & Li, Wei & Xu, Mingxin & Eddings, Eric G. & Ren, Qiangqiang & Lu, Qinggang, 2017. "Coal combustion emission and ash formation characteristics at high oxygen concentration in a 1MWth pilot-scale oxy-fuel circulating fluidized bed," Applied Energy, Elsevier, vol. 197(C), pages 203-211.
    16. Zhao, Haibo & Guo, Lei & Zou, Xixian, 2015. "Chemical-looping auto-thermal reforming of biomass using Cu-based oxygen carrier," Applied Energy, Elsevier, vol. 157(C), pages 408-415.
    17. Zhang, Hao & Liu, Xiangyu & Hong, Hui & Jin, Hongguang, 2018. "Characteristics of a 10 kW honeycomb reactor for natural gas fueled chemical-looping combustion," Applied Energy, Elsevier, vol. 213(C), pages 285-292.
    18. Imtiaz, Qasim & Broda, Marcin & Müller, Christoph R., 2014. "Structure–property relationship of co-precipitated Cu-rich, Al2O3- or MgAl2O4-stabilized oxygen carriers for chemical looping with oxygen uncoupling (CLOU)," Applied Energy, Elsevier, vol. 119(C), pages 557-565.
    19. Zhu, Min & Chen, Shiyi & Soomro, Ahsanullah & Hu, Jun & Sun, Zhao & Ma, Shiwei & Xiang, Wenguo, 2018. "Effects of supports on reduction activity and carbon deposition of iron oxide for methane chemical looping hydrogen generation," Applied Energy, Elsevier, vol. 225(C), pages 912-921.
    20. Belhadi, A. & Boumaza, S. & Trari, M., 2011. "Photoassisted hydrogen production under visible light over NiO/ZnO hetero-system," Applied Energy, Elsevier, vol. 88(12), pages 4490-4495.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:163:y:2016:i:c:p:41-50. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.