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Performance of calcium manganate as oxygen carrier in chemical looping combustion of biochar in a 10kW pilot

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  • Schmitz, Matthias
  • Linderholm, Carl Johan

Abstract

Chemical looping combustion (CLC) and chemical looping with oxygen uncoupling (CLOU) are carbon capture technologies which achieve gas separation by means of cycling oxidation and reduction of a solid oxygen carrier. In this study, the performance and CLOU properties of an oxygen carrier with perovskite structure, CaMn0.9Mg0.1O3−δ, were investigated in a 10kW pilot. The fuel consisted of biochar with very low sulphur content. Around 37h of operation with fuel were carried out in the 10kW chemical looping combustor. Previous operational experience in this unit has been achieved using different natural minerals as oxygen carrier – mainly ilmenite and manganese ore. Parametric studies performed in this work included variation of fuel flow, solids circulation rate, temperature and fluidization gas in the fuel reactor. The oxygen carrier was exposed to a total 73h of hot fluidization (T>600°C). No hard particle agglomerations were formed during the experiments. An oxygen demand as low as 2.1% could be reached under stable operating conditions, with a carbon capture efficiency of up to 98%. CLOU properties were observed at all fuel reactor temperatures, ensuring stable operation even without steam as gasification agent present in the fuel reactor. The results suggest that CaMn0.9Mg0.1O3−δ is suitable for the use as oxygen carrier in chemical looping combustion of solid biochar and offers higher gas conversion than previously tested materials without CLOU properties such as ilmenite. The experiments constitute the first successful operation using a non-copper CLOU oxygen carrier in combustion of solid fuel.

Suggested Citation

  • Schmitz, Matthias & Linderholm, Carl Johan, 2016. "Performance of calcium manganate as oxygen carrier in chemical looping combustion of biochar in a 10kW pilot," Applied Energy, Elsevier, vol. 169(C), pages 729-737.
    • Handle: RePEc:eee:appene:v:169:y:2016:i:c:p:729-737
    DOI: 10.1016/j.apenergy.2016.02.088
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    1. Rydén, Magnus & Leion, Henrik & Mattisson, Tobias & Lyngfelt, Anders, 2014. "Combined oxides as oxygen-carrier material for chemical-looping with oxygen uncoupling," Applied Energy, Elsevier, vol. 113(C), pages 1924-1932.
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    3. Thon, Andreas & Kramp, Marvin & Hartge, Ernst-Ulrich & Heinrich, Stefan & Werther, Joachim, 2014. "Operational experience with a system of coupled fluidized beds for chemical looping combustion of solid fuels using ilmenite as oxygen carrier," Applied Energy, Elsevier, vol. 118(C), pages 309-317.
    4. Markström, Pontus & Linderholm, Carl & Lyngfelt, Anders, 2014. "Operation of a 100kW chemical-looping combustor with Mexican petroleum coke and Cerrejón coal," Applied Energy, Elsevier, vol. 113(C), pages 1830-1835.
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    4. Cabello, Arturo & Abad, Alberto & Gayán, Pilar & García-Labiano, Francisco & de Diego, Luis F. & Adánez, Juan, 2021. "Increasing energy efficiency in chemical looping combustion of methane by in-situ activation of perovskite-based oxygen carriers," Applied Energy, Elsevier, vol. 287(C).
    5. Mendiara, T. & García-Labiano, F. & Abad, A. & Gayán, P. & de Diego, L.F. & Izquierdo, M.T. & Adánez, J., 2018. "Negative CO2 emissions through the use of biofuels in chemical looping technology: A review," Applied Energy, Elsevier, vol. 232(C), pages 657-684.
    6. Iloeje, Chukwunwike O. & Zhao, Zhenlong & Ghoniem, Ahmed F., 2018. "Design and techno-economic optimization of a rotary chemical looping combustion power plant with CO2 capture," Applied Energy, Elsevier, vol. 231(C), pages 1179-1190.
    7. Imponenti, Luca & Albrecht, Kevin J. & Kharait, Rounak & Sanders, Michael D. & Jackson, Gregory S., 2018. "Redox cycles with doped calcium manganites for thermochemical energy storage to 1000 °C," Applied Energy, Elsevier, vol. 230(C), pages 1-18.

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