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Selective separation of CO2 and CH4 for biogas upgrading on zeolite NaKA and SAPO-56

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  • Bacsik, Zoltán
  • Cheung, Ocean
  • Vasiliev, Petr
  • Hedin, Niklas

Abstract

Several commercial and potential adsorbents were investigated for the separation of CO2 from CH4, which is relevant for the upgrading of raw biogas. The main focus of the paper was on the working capacities and selectivities of the adsorbents for a generic vacuum swing adsorption (VSA) process. Zeolites 4A and 13X had good estimated CO2-over-CH4 selectivities and reasonably high working capacities for the removal of CO2. A variant of zeolite A – |Na12−xKx|-LTA (with 1.8⩽x⩽3.2), had at least the same working capacity as zeolite 4A but with a significantly improved selectivity. Hence, the environmentally important “CH4 slip” can be minimized with this |Na12−xKx|-LTA sorbent. If a high working capacity for CO2 removal is the most important characteristic for a VSA process, then silicoaluminum phosphate, specifically SAPO-56, appeared to be the best candidate among the studied sorbents. In addition, SAPO-56 had a substantially high estimated CO2-over-CH4 selectivity with a value between ∼20 and 30.

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  • Bacsik, Zoltán & Cheung, Ocean & Vasiliev, Petr & Hedin, Niklas, 2016. "Selective separation of CO2 and CH4 for biogas upgrading on zeolite NaKA and SAPO-56," Applied Energy, Elsevier, vol. 162(C), pages 613-621.
    • Handle: RePEc:eee:appene:v:162:y:2016:i:c:p:613-621
    DOI: 10.1016/j.apenergy.2015.10.109
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    Cited by:

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    2. Ma, Chunyan & Liu, Chang & Lu, Xiaohua & Ji, Xiaoyan, 2018. "Techno-economic analysis and performance comparison of aqueous deep eutectic solvent and other physical absorbents for biogas upgrading," Applied Energy, Elsevier, vol. 225(C), pages 437-447.
    3. Zheng, Lei & Cheng, Shikun & Han, Yanzhao & Wang, Min & Xiang, Yue & Guo, Jiali & Cai, Di & Mang, Heinz-Peter & Dong, Taili & Li, Zifu & Yan, Zhengxu & Men, Yu, 2020. "Bio-natural gas industry in China: Current status and development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 128(C).
    4. Ma, Chunyan & Xie, Yujiao & Ji, Xiaoyan & Liu, Chang & Lu, Xiaohua, 2018. "Modeling, simulation and evaluation of biogas upgrading using aqueous choline chloride/urea," Applied Energy, Elsevier, vol. 229(C), pages 1269-1283.
    5. Yan, Cheng & Zhu, Liandong & Wang, Yanxin, 2016. "Photosynthetic CO2 uptake by microalgae for biogas upgrading and simultaneously biogas slurry decontamination by using of microalgae photobioreactor under various light wavelengths, light intensities,," Applied Energy, Elsevier, vol. 178(C), pages 9-18.
    6. Zhou, Kui & Chaemchuen, Somboon & Verpoort, Francis, 2017. "Alternative materials in technologies for Biogas upgrading via CO2 capture," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1414-1441.
    7. Chen, S.J. & Zhu, M. & Fu, Y. & Huang, Y.X. & Tao, Z.C. & Li, W.L., 2017. "Using 13X, LiX, and LiPdAgX zeolites for CO2 capture from post-combustion flue gas," Applied Energy, Elsevier, vol. 191(C), pages 87-98.
    8. Pengfei Guo & Yuejin Zhang & Yongjun Zhao, 2018. "Biocapture of CO 2 by Different Microalgal-Based Technologies for Biogas Upgrading and Simultaneous Biogas Slurry Purification under Various Light Intensities and Photoperiods," IJERPH, MDPI, vol. 15(3), pages 1-18, March.
    9. Cheng, Jun & Wang, Yali & Liu, Niu & Hou, Wen & Zhou, Junhu, 2020. "Enhanced CO2 selectivity of mixed matrix membranes with carbonized Zn/Co zeolitic imidazolate frameworks," Applied Energy, Elsevier, vol. 272(C).

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