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Optimization of steam methane reforming coupled with pressure swing adsorption hydrogen production process by heat integration

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  • Song, Chunfeng
  • Liu, Qingling
  • Ji, Na
  • Kansha, Yasuki
  • Tsutsumi, Atsushi

Abstract

Hydrogen has been widely researched as a promising alternative fuel. Steam methane reforming (SMR) coupled with pressure swing adsorption (PSA) is one of the most dominant processes for hydrogen production. In order to reduce the energy consumption, a novel energy saving SMR–PSA H2 production process by combining heat integration technology has been put forward. In SMR section, the waste heat of reformer and water–gas-shift (WGS) reactors is recovered to pre-heat feed gas and H2O. In the view of exergy, a compressor is used to achieve a well heat pairing of sensible and latent heat between hot and cold streams. In PSA section, the generated adsorption heat is recovered by heat pump and reused for regeneration of sorbent. In the total process, optimal heat coupling between hot and cold streams is realized. The simulation results indicated that the SMR and PSA sections in the optimized hydrogen production process can save 55.77kJ/mol H2 and 6.01kJ/mol H2, respectively. The total energy consumption of the novel SMR–PSA process can be reduced to 39.5% that of the conventional process.

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  • Song, Chunfeng & Liu, Qingling & Ji, Na & Kansha, Yasuki & Tsutsumi, Atsushi, 2015. "Optimization of steam methane reforming coupled with pressure swing adsorption hydrogen production process by heat integration," Applied Energy, Elsevier, vol. 154(C), pages 392-401.
  • Handle: RePEc:eee:appene:v:154:y:2015:i:c:p:392-401
    DOI: 10.1016/j.apenergy.2015.05.038
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    9. Xia, Hui & Ye, Qing & Feng, Shenyao & Li, Rui & Suo, Xiaomeng, 2017. "A novel energy-saving pressure swing distillation process based on self-heat recuperation technology," Energy, Elsevier, vol. 141(C), pages 770-781.
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    13. Sirui Tong & Bin Miao & Lan Zhang & Siew Hwa Chan, 2022. "Decarbonizing Natural Gas: A Review of Catalytic Decomposition and Carbon Formation Mechanisms," Energies, MDPI, vol. 15(7), pages 1-30, April.
    14. Abhinav Bhaskar & Mohsen Assadi & Homam Nikpey Somehsaraei, 2020. "Decarbonization of the Iron and Steel Industry with Direct Reduction of Iron Ore with Green Hydrogen," Energies, MDPI, vol. 13(3), pages 1-23, February.
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    17. Situmorang, Yohanes Andre & Zhao, Zhongkai & An, Ping & Yu, Tao & Rizkiana, Jenny & Abudula, Abuliti & Guan, Guoqing, 2020. "A novel system of biomass-based hydrogen production by combining steam bio-oil reforming and chemical looping process," Applied Energy, Elsevier, vol. 268(C).
    18. Wang, Wanrong & Ma, Yingjie & Maroufmashat, Azadeh & Zhang, Nan & Li, Jie & Xiao, Xin, 2022. "Optimal design of large-scale solar-aided hydrogen production process via machine learning based optimisation framework," Applied Energy, Elsevier, vol. 305(C).
    19. Sun, Zhao & Chen, Shiyi & Ma, Shiwei & Xiang, Wenguo & Song, Quanbin, 2016. "Simulation of the calcium looping process (CLP) for hydrogen, carbon monoxide and acetylene poly-generation with CO2 capture and COS reduction," Applied Energy, Elsevier, vol. 169(C), pages 642-651.
    20. Pashchenko, Dmitry & Makarov, Ivan, 2021. "Carbon deposition in steam methane reforming over a Ni-based catalyst: Experimental and thermodynamic analysis," Energy, Elsevier, vol. 222(C).
    21. Xin, Yanbin & Sun, Bing & Zhu, Xiaomei & Yan, Zhiyu & Liu, Yongjun & Liu, Hui, 2016. "Characteristics of hydrogen produced by pulsed discharge in ethanol solution," Applied Energy, Elsevier, vol. 168(C), pages 122-129.
    22. Hwangbo, Soonho & Lee, In-Beum & Han, Jeehoon, 2017. "Mathematical model to optimize design of integrated utility supply network and future global hydrogen supply network under demand uncertainty," Applied Energy, Elsevier, vol. 195(C), pages 257-267.
    23. Song, Chunfeng & Liu, Qingling & Ji, Na & Deng, Shuai & Zhao, Jun & Kitamura, Yutaka, 2017. "Natural gas purification by heat pump assisted MEA absorption process," Applied Energy, Elsevier, vol. 204(C), pages 353-361.

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