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Influence of an iron-based fuel-borne catalyst on physicochemical and toxicological characteristics of particulate emissions from a diesel engine

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  • Zhang, Zhi-Hui
  • Balasubramanian, Rajasekhar

Abstract

Metal-based fuel-borne catalysts (FBCs) have been used with diesel fuels to effectively reduce soot and diesel particulate matter (DPM) emissions from both on-road and off-road applications. However, there is a lack of detailed investigations on the potential changes in the properties of particulates, when FBCs-doped fuels are combusted in diesel engines. This study fully evaluates the potential impacts of ferrocene-doped ultralow sulfur diesel (ULSD) fuels on physical, chemical and toxicological characteristics of the particulates emitted by a single cylinder, direct-injection diesel engine working at a constant speed and at three engine loads. The results indicated that ferrocene-doped fuels could effectively reduce the particulate mass and elemental carbon (EC) emissions, while increasing the proportion of both organic carbon (OC) and water-soluble organic carbon (WSOC) in particles. Particle-phase PAHs and n-alkanes emissions increased with an increase of Fe in the fuels. Ferrocene addition also led to lower soot ignition temperature and activation energy. However, the total number emissions of particles from ferrocene-doped fuels dramatically increased due to the formation of Fe-rich nuclei mode particles. Compared to pure ULSD, the particles emitted from ferrocene-doped fuels showed a slight decline in cell viability. The Fe in the particles and the changes in chemical composition of particulates are thought to be responsible for the variation of cell viability.

Suggested Citation

  • Zhang, Zhi-Hui & Balasubramanian, Rajasekhar, 2015. "Influence of an iron-based fuel-borne catalyst on physicochemical and toxicological characteristics of particulate emissions from a diesel engine," Applied Energy, Elsevier, vol. 146(C), pages 270-278.
    • Handle: RePEc:eee:appene:v:146:y:2015:i:c:p:270-278
    DOI: 10.1016/j.apenergy.2015.02.029
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    References listed on IDEAS

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    1. Kannan, G.R. & Karvembu, R. & Anand, R., 2011. "Effect of metal based additive on performance emission and combustion characteristics of diesel engine fuelled with biodiesel," Applied Energy, Elsevier, vol. 88(11), pages 3694-3703.
    2. Ma, Yu & Zhu, Mingming & Zhang, Dongke, 2013. "The effect of a homogeneous combustion catalyst on exhaust emissions from a single cylinder diesel engine," Applied Energy, Elsevier, vol. 102(C), pages 556-562.
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    4. Ma, Yu & Zhu, Mingming & Zhang, Dongke, 2014. "Effect of a homogeneous combustion catalyst on the characteristics of diesel soot emitted from a compression ignition engine," Applied Energy, Elsevier, vol. 113(C), pages 751-757.
    5. Zhu, Mingming & Ma, Yu & Zhang, Dongke, 2012. "Effect of a homogeneous combustion catalyst on the combustion characteristics and fuel efficiency in a diesel engine," Applied Energy, Elsevier, vol. 91(1), pages 166-172.
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    1. Zhang, Zhi-Hui & Balasubramanian, Rajasekhar, 2016. "Investigation of particulate emission characteristics of a diesel engine fueled with higher alcohols/biodiesel blends," Applied Energy, Elsevier, vol. 163(C), pages 71-80.
    2. Bazooyar, Bahamin & Hosseini, Seyyed Yaghoob & Moradi Ghoje Begloo, Solat & Shariati, Ahmad & Hashemabadi, Seyed Hassan & Shaahmadi, Fariborz, 2018. "Mixed modified Fe2O3-WO3 as new fuel borne catalyst (FBC) for biodiesel fuel," Energy, Elsevier, vol. 149(C), pages 438-453.
    3. Asadi, Asgar & Kadijani, Omid Nouri & Doranehgard, Mohammad Hossein & Bozorg, Mehdi Vahabzadeh & Xiong, Qingang & Shadloo, Mostafa Safdari & Li, Larry K.B., 2020. "Numerical study on the application of biodiesel and bioethanol in a multiple injection diesel engine," Renewable Energy, Elsevier, vol. 150(C), pages 1019-1029.
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    5. Saxena, Vishal & Kumar, Niraj & Saxena, Vinod Kumar, 2019. "Multi-objective optimization of modified nanofluid fuel blends at different TiO2 nanoparticle concentration in diesel engine: Experimental assessment and modeling," Applied Energy, Elsevier, vol. 248(C), pages 330-353.

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