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Elimination of water flooding of cathode current collector of micro passive direct methanol fuel cell by superhydrophilic surface treatment

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  • Wang, Zhigang
  • Zhang, Xuelin
  • Nie, Li
  • Zhang, Yufeng
  • Liu, Xiaowei

Abstract

To solve the water flooding problem of micro passive direct methanol fuel cell (DMFC), plasma electrolytic oxidation (PEO) was adopted to prepare a superhydrophilic coating on the surface of an aluminum-based cathode current collector which contacts with air. Results data show that liquid water spreads quickly as a plane on the surface of the porous PEO coating that is composed of Al2SiO3 and Al2O3. As a result, water droplet can be prevented from accumulating along the air-breathing channels of the PEO-treated cathode current collector, and thus the water flooding problem of the micro passive DMFC is effectively solved. The cell fabricated with the novel cathode structure gives excellent stability.

Suggested Citation

  • Wang, Zhigang & Zhang, Xuelin & Nie, Li & Zhang, Yufeng & Liu, Xiaowei, 2014. "Elimination of water flooding of cathode current collector of micro passive direct methanol fuel cell by superhydrophilic surface treatment," Applied Energy, Elsevier, vol. 126(C), pages 107-112.
    • Handle: RePEc:eee:appene:v:126:y:2014:i:c:p:107-112
    DOI: 10.1016/j.apenergy.2014.03.029
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    References listed on IDEAS

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    Cited by:

    1. Fang, Shuo & Zhang, Yufeng & Ma, Zezhong & Zou, Yuezhang & Liu, Xiaowei, 2016. "Development of a micro direct methanol fuel cell with heat control," Energy, Elsevier, vol. 116(P1), pages 978-985.
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    5. Zainoodin, A.M. & Kamarudin, S.K. & Masdar, M.S. & Daud, W.R.W. & Mohamad, A.B. & Sahari, J., 2014. "Investigation of MEA degradation in a passive direct methanol fuel cell under different modes of operation," Applied Energy, Elsevier, vol. 135(C), pages 364-372.
    6. Miao Ye & Long Rong & Xu Ma & Weiwei Yang, 2023. "Numerical Optimization of Triple-Phase Components in Order-Structured Cathode Catalyst Layer of a Proton Exchange Membrane Fuel Cell," Energies, MDPI, vol. 16(4), pages 1-19, February.
    7. Chen, Xueye & Li, Tiechuan & Shen, Jienan & Hu, Zengliang, 2017. "From structures, packaging to application: A system-level review for micro direct methanol fuel cell," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 669-678.
    8. Munjewar, Seema S. & Thombre, Shashikant B. & Mallick, Ranjan K., 2017. "Approaches to overcome the barrier issues of passive direct methanol fuel cell – Review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1087-1104.
    9. Kong, Im Mo & Jung, Aeri & Kim, Min Soo, 2016. "Investigations on the double gas diffusion backing layer for performance improvement of self-humidified proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 176(C), pages 149-156.
    10. Deng, Huichao & Zhang, Xuelin & Ma, Zezhong & Chen, Hailong & Sun, Qiu & Zhang, Yufeng & Liu, Xiaowei, 2014. "A micro passive direct methanol fuel cell with high performance via plasma electrolytic oxidation on aluminum-based substrate," Energy, Elsevier, vol. 78(C), pages 149-153.
    11. Abdelkareem, Mohammad Ali & Allagui, Anis & Sayed, Enas Taha & El Haj Assad, M. & Said, Zafar & Elsaid, Khaled, 2019. "Comparative analysis of liquid versus vapor-feed passive direct methanol fuel cells," Renewable Energy, Elsevier, vol. 131(C), pages 563-584.
    12. Yuan, Wei & Wang, Aoyu & Ye, Guangzhao & Pan, Baoyou & Tang, Kairui & Chen, Haimu, 2017. "Dynamic relationship between the CO2 gas bubble behavior and the pressure drop characteristics in the anode flow field of an active liquid-feed direct methanol fuel cell," Applied Energy, Elsevier, vol. 188(C), pages 431-443.
    13. Calabriso, Andrea & Borello, Domenico & Romano, Giovanni Paolo & Cedola, Luca & Del Zotto, Luca & Santori, Simone Giovanni, 2017. "Bubbly flow mapping in the anode channel of a direct methanol fuel cell via PIV investigation," Applied Energy, Elsevier, vol. 185(P2), pages 1245-1255.
    14. Jiang, Jinghui & Li, Yinshi & Liang, Jiarong & Yang, Weiwei & Li, Xianglin, 2019. "Modeling of high-efficient direct methanol fuel cells with order-structured catalyst layer," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    15. Xue, Rui & Zhang, Yufeng & Liu, Xiaowei, 2017. "A novel cathode gas diffusion layer for water management of passive μ-DMFC," Energy, Elsevier, vol. 139(C), pages 535-541.
    16. Yan, X.H. & Zhao, T.S. & An, L. & Zhao, G. & Zeng, L., 2015. "A crack-free and super-hydrophobic cathode micro-porous layer for direct methanol fuel cells," Applied Energy, Elsevier, vol. 138(C), pages 331-336.
    17. Chen, Qing-Yun & Fu, Rong & Fang, Xiao-Wen & Cai, Wen-Fang & Wang, Yun-Hai & Cheng, Shao-An, 2015. "Cr-methanol fuel cell for efficient Cr(VI) removal and high power production," Applied Energy, Elsevier, vol. 138(C), pages 31-35.
    18. Yuan, Wei & Wang, Aoyu & Yan, Zhiguo & Tan, Zhenhao & Tang, Yong & Xia, Hongrong, 2016. "Visualization of two-phase flow and temperature characteristics of an active liquid-feed direct methanol fuel cell with diverse flow fields," Applied Energy, Elsevier, vol. 179(C), pages 85-98.

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