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Cr-methanol fuel cell for efficient Cr(VI) removal and high power production

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  • Chen, Qing-Yun
  • Fu, Rong
  • Fang, Xiao-Wen
  • Cai, Wen-Fang
  • Wang, Yun-Hai
  • Cheng, Shao-An

Abstract

A novel Cr-methanol fuel cell was designed to remove Cr(VI) with simultaneous electricity production. In this design, methanol was oxidized on anode, while Cr(VI) was reduced on cathode. With 2molL−1 sodium hydroxide as anolyte and 0.1molL−1 sodium sulfate as catholyte, the power density output of as high as 903Wm−2 with external resistance of 15Ω at 45°C could be obtained. More than 91% Cr(VI) could be reduced in one single cycle of around 400min. What is more, the presented electrochemical cell can steadily run in wide temperature ranges from −14°C to 45°C. Our results also demonstrated that the proposed Cr-methanol fuel cell had potential application for Cr(VI) removal with simultaneous electricity production.

Suggested Citation

  • Chen, Qing-Yun & Fu, Rong & Fang, Xiao-Wen & Cai, Wen-Fang & Wang, Yun-Hai & Cheng, Shao-An, 2015. "Cr-methanol fuel cell for efficient Cr(VI) removal and high power production," Applied Energy, Elsevier, vol. 138(C), pages 31-35.
    • Handle: RePEc:eee:appene:v:138:y:2015:i:c:p:31-35
    DOI: 10.1016/j.apenergy.2014.10.053
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    References listed on IDEAS

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    1. Achmad, F. & Kamarudin, S.K. & Daud, W.R.W. & Majlan, E.H., 2011. "Passive direct methanol fuel cells for portable electronic devices," Applied Energy, Elsevier, vol. 88(5), pages 1681-1689, May.
    2. Wang, Yun-Hai & Wang, Bai-Shi & Pan, Bin & Chen, Qing-Yun & Yan, Wei, 2013. "Electricity production from a bio-electrochemical cell for silver recovery in alkaline media," Applied Energy, Elsevier, vol. 112(C), pages 1337-1341.
    3. An, Myung-Gi & Mehmood, Asad & Ha, Heung Yong, 2014. "Sensor-less control of the methanol concentration of direct methanol fuel cells at varying ambient temperatures," Applied Energy, Elsevier, vol. 129(C), pages 104-111.
    4. Wang, Zhigang & Zhang, Xuelin & Nie, Li & Zhang, Yufeng & Liu, Xiaowei, 2014. "Elimination of water flooding of cathode current collector of micro passive direct methanol fuel cell by superhydrophilic surface treatment," Applied Energy, Elsevier, vol. 126(C), pages 107-112.
    5. Wu, Q.X. & Zhao, T.S. & Chen, R. & An, L., 2013. "A sandwich structured membrane for direct methanol fuel cells operating with neat methanol," Applied Energy, Elsevier, vol. 106(C), pages 301-306.
    6. Kim, Joon-Hee & Yang, Min-Jee & Park, Jun-Young, 2014. "Improvement on performance and efficiency of direct methanol fuel cells using hydrocarbon-based membrane electrode assembly," Applied Energy, Elsevier, vol. 115(C), pages 95-102.
    7. Zainoodin, A.M. & Kamarudin, S.K. & Masdar, M.S. & Daud, W.R.W. & Mohamad, A.B. & Sahari, J., 2014. "High power direct methanol fuel cell with a porous carbon nanofiber anode layer," Applied Energy, Elsevier, vol. 113(C), pages 946-954.
    8. Yuan, Wei & Tang, Yong & Wang, Qinghui & Wan, Zhenping, 2011. "Dominance evaluation of structural factors in a passive air-breathing direct methanol fuel cell based on orthogonal array analysis," Applied Energy, Elsevier, vol. 88(5), pages 1671-1680, May.
    9. Dutta, Kingshuk & Das, Suparna & Kumar, Piyush & Kundu, Patit Paban, 2014. "Polymer electrolyte membrane with high selectivity ratio for direct methanol fuel cells: A preliminary study based on blends of partially sulfonated polymers polyaniline and PVdF-co-HFP," Applied Energy, Elsevier, vol. 118(C), pages 183-191.
    10. Das, Suparna & Kumar, Piyush & Dutta, Kingshuk & Kundu, Patit Paban, 2014. "Partial sulfonation of PVdF-co-HFP: A preliminary study and characterization for application in direct methanol fuel cell," Applied Energy, Elsevier, vol. 113(C), pages 169-177.
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    Cited by:

    1. Kim, Jung Hwan & Park, I Seul & Park, Joo Yang, 2015. "Electricity generation and recovery of iron hydroxides using a single chamber fuel cell with iron anode and air-cathode for electrocoagulation," Applied Energy, Elsevier, vol. 160(C), pages 18-27.

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