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Transforming duck tallow into biodiesel via noncatalytic transesterification

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  • Kwon, Eilhann E.
  • Jeon, Eui-Chan
  • Yi, Haakrho
  • Kim, Sungpyo

Abstract

The transformation of the lipids extracted from duck tallow into biodiesel was achieved using activated alumina and CO2 under ambient pressure (1bar). Crude fatty acids (∼98% assay) were also esterified to help us understand and validate the noncatalytic biodiesel conversion mechanisms. Its conversion efficiency was nearly 93.5(±0.5)%. The transformation of crude fatty acid into biodiesel proves that this newly developed technology for the production of biodiesel combines esterification of free fatty acids and transesterification of triglycerides into a single process that has a 98.5(±0.5)% conversion efficiency to biodiesel within 1min at 350–500°C. This paper addresses the simplest methodology for the production of biodiesel. Herein, it is confirmed that the main driving force of biodiesel conversion in the noncatalytic transesterification reaction is temperature rather than pressure. Noncatalytic biodiesel transformation can be achieved in the presence of a porous material via a thermochemical process in a continuous flow system. This noncatalytic biodiesel transformation was enhanced under the presence of carbon dioxide (CO2).

Suggested Citation

  • Kwon, Eilhann E. & Jeon, Eui-Chan & Yi, Haakrho & Kim, Sungpyo, 2014. "Transforming duck tallow into biodiesel via noncatalytic transesterification," Applied Energy, Elsevier, vol. 116(C), pages 20-25.
  • Handle: RePEc:eee:appene:v:116:y:2014:i:c:p:20-25
    DOI: 10.1016/j.apenergy.2013.11.043
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    3. Avhad, M.R. & Marchetti, J.M., 2015. "A review on recent advancement in catalytic materials for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 696-718.
    4. Zimmerman, William B. & Kokoo, Rungrote, 2018. "Esterification for biodiesel production with a phantom catalyst: Bubble mediated reactive distillation," Applied Energy, Elsevier, vol. 221(C), pages 28-40.
    5. Faleh, Nahla & Khila, Zouhour & Wahada, Zeineb & Pons, Marie-Noëlle & Houas, Ammar & Hajjaji, Noureddine, 2018. "Exergo-environmental life cycle assessment of biodiesel production from mutton tallow transesterification," Renewable Energy, Elsevier, vol. 127(C), pages 74-83.
    6. Badawy, Tawfik & Mansour, Mohy S. & Daabo, Ahmed M. & Abdel Aziz, Mostafa M. & Othman, Abdelrahman A. & Barsoum, Fady & Basouni, Mohamed & Hussien, Mohamed & Ghareeb, Mourad & Hamza, Mahmoud & Wang, C, 2021. "Selection of second-generation crop for biodiesel extraction and testing its impact with nano additives on diesel engine performance and emissions," Energy, Elsevier, vol. 237(C).

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