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Deformation resistant monolithic hierarchical textures inducing stretchable superamphiphobicity with environmental adaptability and flame retardancy

Author

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  • Chun-Bo Li

    (Sichuan University)

  • Fang Wang

    (Sichuan University
    Sichuan University)

  • Yi-Yang Wang

    (Sichuan University)

  • Mei-Lin Guo

    (Sichuan University)

  • Jin-Le Li

    (Sichuan University)

  • Cong Deng

    (Sichuan University)

  • Fei Song

    (Sichuan University)

  • Wei Yang

    (Sichuan University)

  • Yu-Zhong Wang

    (Sichuan University)

Abstract

Superamphiphobic and flame-retardant fabrics offer effective protection for firefighters and industrial workers operating under hazardous conditions. However, limitations in deformation resistance, wear comfort, and environmental adaptability hinder their practical applications. Here, a monolithic hierarchical macro-/micro-/nanostructure is constructed to achieve durable repellency against water and oils, even under significant deformations. This coating integrates fluorinated nanoparticles, flame retardant microparticles, and a cross-linking adhesive. Hydrogen bonding and the adhesive define the coating’s morphology, robustness, and adaptability. The coated surface exhibits an ultralow water adhesion force (0.002 mN) and excellent anti-fouling performance against extreme temperatures (100 °C, −196 °C) and corrosive liquids, including aqua regia and concentrated H2SO4. Upon fire exposure, the coating enables self-extinguishing behavior on cotton fabrics. The coated fabrics also demonstrate remarkable mechanical and UV resistance while preserving wear comfort. Overall, we achieve a balance between desirable properties and wear comfort in superamphiphobic, flame-retardant fabrics, enabling protective clothing applications previously unattainable.

Suggested Citation

  • Chun-Bo Li & Fang Wang & Yi-Yang Wang & Mei-Lin Guo & Jin-Le Li & Cong Deng & Fei Song & Wei Yang & Yu-Zhong Wang, 2025. "Deformation resistant monolithic hierarchical textures inducing stretchable superamphiphobicity with environmental adaptability and flame retardancy," Nature Communications, Nature, vol. 16(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-58191-w
    DOI: 10.1038/s41467-025-58191-w
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    References listed on IDEAS

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    1. Jianing Song & Wenluan Zhang & Zhengnan Sun & Mengyao Pan & Feng Tian & Xiuhong Li & Ming Ye & Xu Deng, 2022. "Durable radiative cooling against environmental aging," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    2. Wancheng Gu & Wanbo Li & Yu Zhang & Yage Xia & Qiaoling Wang & Wei Wang & Ping Liu & Xinquan Yu & Hui He & Caihua Liang & Youxue Ban & Changwen Mi & Sha Yang & Wei Liu & Miaomiao Cui & Xu Deng & Zuank, 2023. "Ultra-durable superhydrophobic cellular coatings," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    3. Jinfei Wei & Jiaojiao Zhang & Xiaojun Cao & Jinhui Huo & Xiaopeng Huang & Junping Zhang, 2023. "Durable superhydrophobic coatings for prevention of rain attenuation of 5G/weather radomes," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    4. Dehui Wang & Qiangqiang Sun & Matti J. Hokkanen & Chenglin Zhang & Fan-Yen Lin & Qiang Liu & Shun-Peng Zhu & Tianfeng Zhou & Qing Chang & Bo He & Quan Zhou & Longquan Chen & Zuankai Wang & Robin H. A., 2020. "Design of robust superhydrophobic surfaces," Nature, Nature, vol. 582(7810), pages 55-59, June.
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