IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-41467-4.html
   My bibliography  Save this article

A metal-free photoactive nitrogen-doped carbon nanosolenoid with broad absorption in visible region for efficient photocatalysis

Author

Listed:
  • Yu Zhou

    (Dongguan University of Technology
    University of Science and Technology of China)

  • Xinyu Zhang

    (University of Science and Technology of China)

  • Guan Sheng

    (Zhejiang University of Technology)

  • Shengda Wang

    (University of Science and Technology of China)

  • Muqing Chen

    (Dongguan University of Technology)

  • Guilin Zhuang

    (Zhejiang University of Technology)

  • Yihan Zhu

    (Zhejiang University of Technology)

  • Pingwu Du

    (University of Science and Technology of China)

Abstract

Riemann surfaces inspired chemists to design and synthesize such multidimensional curved carbon architectures. It has been predicted that carbon nanosolenoid materials with Riemann surfaces have unique structures and novel physical properties. Here we report the first synthesis of a nitrogen-doped carbon nanosolenoid (N-CNS) using bottom-up approach with a well-defined structure. N-CNS was obtained by a rational Suzuki polymerization, followed by oxidative cyclodehydrogenation. The successful synthesis of N-CNS was fully characterized by GPC, FTIR, solid-state 13C NMR and Raman techniques. The intrinsic single-strand molecular structures of N-CNS helices can be clearly resolved using low-dose integrated differential phase contrast scanning transmission electron microscopy (iDPC-STEM) technique. Possessing unique structural and physical properties, this long π-extended polymer N-CNS can provide new insight towards bottom-up syntheses of curved nanoribbons and potential applications as a metal-free photocatalyst for visible-light-driven H2 evolution and highly efficient photocatalyst for photoredox organic transformations.

Suggested Citation

  • Yu Zhou & Xinyu Zhang & Guan Sheng & Shengda Wang & Muqing Chen & Guilin Zhuang & Yihan Zhu & Pingwu Du, 2023. "A metal-free photoactive nitrogen-doped carbon nanosolenoid with broad absorption in visible region for efficient photocatalysis," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-41467-4
    DOI: 10.1038/s41467-023-41467-4
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-41467-4
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-41467-4?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Boyuan Shen & Xiao Chen & Huiqiu Wang & Hao Xiong & Eric G. T. Bosch & Ivan Lazić & Dali Cai & Weizhong Qian & Shifeng Jin & Xin Liu & Yu Han & Fei Wei, 2021. "A single-molecule van der Waals compass," Nature, Nature, vol. 592(7855), pages 541-544, April.
    2. Jinming Cai & Pascal Ruffieux & Rached Jaafar & Marco Bieri & Thomas Braun & Stephan Blankenburg & Matthias Muoth & Ari P. Seitsonen & Moussa Saleh & Xinliang Feng & Klaus Müllen & Roman Fasel, 2010. "Atomically precise bottom-up fabrication of graphene nanoribbons," Nature, Nature, vol. 466(7305), pages 470-473, July.
    3. Young-Woo Son & Marvin L. Cohen & Steven G. Louie, 2006. "Half-metallic graphene nanoribbons," Nature, Nature, vol. 444(7117), pages 347-349, November.
    4. Boyuan Shen & Huiqiu Wang & Hao Xiong & Xiao Chen & Eric G. T. Bosch & Ivan Lazić & Weizhong Qian & Fei Wei, 2022. "Atomic imaging of zeolite-confined single molecules by electron microscopy," Nature, Nature, vol. 607(7920), pages 703-707, July.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ying Wang & Vinod K. Paidi & Weizhen Wang & Yong Wang & Guangri Jia & Tingyu Yan & Xiaoqiang Cui & Songhua Cai & Jingxiang Zhao & Kug-Seung Lee & Lawrence Yoon Suk Lee & Kwok-Yin Wong, 2024. "Spatial engineering of single-atom Fe adjacent to Cu-assisted nanozymes for biomimetic O2 activation," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mengmeng Ma & Xuliang Zhang & Xiao Chen & Hao Xiong & Liang Xu & Tao Cheng & Jianyu Yuan & Fei Wei & Boyuan Shen, 2023. "In situ imaging of the atomic phase transition dynamics in metal halide perovskites," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    2. Zheng Bo & Rui Wang & Bin Wang & Sanjay Sunny & Yuping Zhao & Kangkang Ge & Kui Xu & Yajing Song & Encarnacion Raymundo-Piñero & Zifeng Lin & Hui Shao & Qian Yu & Jianhua Yan & Kefa Cen & Pierre-Louis, 2025. "Ion desolvation for boosting the charge storage performance in Ti3C2 MXene electrode," Nature Communications, Nature, vol. 16(1), pages 1-11, December.
    3. Mengmeng Ma & Qinnan Yu & Jiayi Zhang & Xiao Chen & Wenbo Li & Xianlin Qu & Xuliang Zhang & Jiale Feng & Fei Wei & Jianyu Yuan & Tao Cheng & Sheng Dai & Yi Wang & Bin Song & Boyuan Shen, 2025. "Imaging molecular structures and interactions by enhanced confinement effect in electron microscopy," Nature Communications, Nature, vol. 16(1), pages 1-9, December.
    4. Jiale Feng & Zhipeng Feng & Liang Xu & Haibing Meng & Xiao Chen & Mengmeng Ma & Lei Wang & Bin Song & Xuan Tang & Sheng Dai & Fei Wei & Tao Cheng & Boyuan Shen, 2024. "Real-space imaging for discovering a rotated node structure in metal-organic framework," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    5. Outhmane Chahib & Yuling Yin & Jung-Ching Liu & Chao Li & Thilo Glatzel & Feng Ding & Qinghong Yuan & Ernst Meyer & Rémy Pawlak, 2024. "Probing charge redistribution at the interface of self-assembled cyclo-P5 pentamers on Ag(111)," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    6. Wenqian Yu & Shengnan Yue & Minghe Yang & Masahiro Hashimoto & Panpan Liu & Li Zhu & Wangjing Xie & Travis Jones & Marc Willinger & Xing Huang, 2025. "Operando TEM study of a working copper catalyst during ethylene oxidation," Nature Communications, Nature, vol. 16(1), pages 1-11, December.
    7. Poudel, Niranjan & Singleton, Patrick A., 2022. "Preferences for roundabout attributes among US bicyclists: A discrete choice experiment," Transportation Research Part A: Policy and Practice, Elsevier, vol. 155(C), pages 316-329.
    8. Austin J. Way & Robert M. Jacobberger & Nathan P. Guisinger & Vivek Saraswat & Xiaoqi Zheng & Anjali Suresh & Jonathan H. Dwyer & Padma Gopalan & Michael S. Arnold, 2022. "Graphene nanoribbons initiated from molecularly derived seeds," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    9. Dasari, Bhagya Lakshmi & Nouri, Jamshid M. & Brabazon, Dermot & Naher, Sumsun, 2017. "Graphene and derivatives – Synthesis techniques, properties and their energy applications," Energy, Elsevier, vol. 140(P1), pages 766-778.
    10. Linjing Tong & Siming Huang & Yujian Shen & Suya Liu & Xiaomin Ma & Fang Zhu & Guosheng Chen & Gangfeng Ouyang, 2022. "Atomically unveiling the structure-activity relationship of biomacromolecule-metal-organic frameworks symbiotic crystal," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    11. Hiroshi Sakaguchi & Takahiro Kojima & Yingbo Cheng & Shunpei Nobusue & Kazuhiro Fukami, 2024. "Electrochemical on-surface synthesis of a strong electron-donating graphene nanoribbon catalyst," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    12. Jinji Zhang & Xiaojing Fang & Weiwei Niu & Yiming Yu & Yanlin Hu & Jiawen Sun & Ying Xu & Zhihua Zhou & Heyuan Liu & Xiaonan Fan & Baishu Zheng & Qing Jiang & Guangwu Li & Wangdong Zeng, 2025. "A stable open-shell peri-hexacene with remarkable diradical character," Nature Communications, Nature, vol. 16(1), pages 1-9, December.
    13. Jens Brede & Nestor Merino-Díez & Alejandro Berdonces-Layunta & Sofía Sanz & Amelia Domínguez-Celorrio & Jorge Lobo-Checa & Manuel Vilas-Varela & Diego Peña & Thomas Frederiksen & José I. Pascual & Di, 2023. "Detecting the spin-polarization of edge states in graphene nanoribbons," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    14. Fouad N. Ajeel & Ali Ben Ahmed, 2023. "Influence of the boron doping and Stone–Wales defects on the thermoelectric performance of graphene nanoribbons," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 96(10), pages 1-10, October.
    15. Ying Wang & Vinod K. Paidi & Weizhen Wang & Yong Wang & Guangri Jia & Tingyu Yan & Xiaoqiang Cui & Songhua Cai & Jingxiang Zhao & Kug-Seung Lee & Lawrence Yoon Suk Lee & Kwok-Yin Wong, 2024. "Spatial engineering of single-atom Fe adjacent to Cu-assisted nanozymes for biomimetic O2 activation," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    16. Dey, Abhijit & Bajpai, Om Prakash & Sikder, Arun K. & Chattopadhyay, Santanu & Shafeeuulla Khan, Md Abdul, 2016. "Recent advances in CNT/graphene based thermoelectric polymer nanocomposite: A proficient move towards waste energy harvesting," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 653-671.
    17. Ignacio Piquero-Zulaica & Eduardo Corral-Rascón & Xabier Diaz de Cerio & Alexander Riss & Biao Yang & Aran Garcia-Lekue & Mohammad A. Kher-Elden & Zakaria M. Abd El-Fattah & Shunpei Nobusue & Takahiro, 2024. "Deceptive orbital confinement at edges and pores of carbon-based 1D and 2D nanoarchitectures," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    18. Talal Yusaf & Abu Shadate Faisal Mahamude & Kaniz Farhana & Wan Sharuzi Wan Harun & Kumaran Kadirgama & Devarajan Ramasamy & Mohd Kamal Kamarulzaman & Sivarao Subramonian & Steve Hall & Hayder Abed Dh, 2022. "A Comprehensive Review on Graphene Nanoparticles: Preparation, Properties, and Applications," Sustainability, MDPI, vol. 14(19), pages 1-32, September.
    19. Zhenzhe Zhang & Hanh D. M. Pham & Dmytro F. Perepichka & Rustam Z. Khaliullin, 2024. "Prediction of highly stable 2D carbon allotropes based on azulenoid kekulene," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    20. Yang Luo & Shaoxiang Sheng & Andrea Schirato & Alberto Martin-Jimenez & Giuseppe Valle & Giulio Cerullo & Klaus Kern & Manish Garg, 2025. "Visualizing hot carrier dynamics by nonlinear optical spectroscopy at the atomic length scale," Nature Communications, Nature, vol. 16(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-41467-4. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.