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Photocatalytic conversion of sugars to 5-hydroxymethylfurfural using aluminium(III) and fulvic acid

Author

Listed:
  • Tana Tana

    (Inner Mongolia Minzu University
    Queensland University of Technology)

  • Pengfei Han

    (Queensland University of Technology
    Hunan University)

  • Aidan J. Brock

    (Queensland University of Technology)

  • Xin Mao

    (Queensland University of Technology)

  • Sarina Sarina

    (Queensland University of Technology
    The University of Sydney)

  • Eric R. Waclawik

    (Queensland University of Technology)

  • Aijun Du

    (Queensland University of Technology)

  • Steven E. Bottle

    (Queensland University of Technology)

  • Huai-Yong Zhu

    (Queensland University of Technology)

Abstract

5-hydroxymethylfurfural (HMF) is a valuable and essential platform chemical for establishing a sustainable, eco-friendly fine-chemical and pharmaceutical industry based on biomass. The cost-effective production of HMF from abundant C6 sugars requires mild reaction temperatures and efficient catalysts from naturally abundant materials. Herein, we report how fulvic acid forms complexes with Al3+ ions that exhibit solar absorption and photocatalytic activity for glucose conversion to HMF in one-pot reaction, in good yield (~60%) and at moderate temperatures (80 °C). When using representative components of fulvic acid, catechol and pyrogallol as ligands, 70 and 67% HMF yields are achieved, respectively, at 70 °C. Al3+ ions are not recognised as effective photocatalysts; however, complexing them with fulvic acid components as light antennas can create new functionality. This mechanism offers prospects for new green photocatalytic systems to synthesise a range of substances that have not previously been considered.

Suggested Citation

  • Tana Tana & Pengfei Han & Aidan J. Brock & Xin Mao & Sarina Sarina & Eric R. Waclawik & Aijun Du & Steven E. Bottle & Huai-Yong Zhu, 2023. "Photocatalytic conversion of sugars to 5-hydroxymethylfurfural using aluminium(III) and fulvic acid," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-40090-7
    DOI: 10.1038/s41467-023-40090-7
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    References listed on IDEAS

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    1. Yunqing Zhu & Charles Romain & Charlotte K. Williams, 2016. "Sustainable polymers from renewable resources," Nature, Nature, vol. 540(7633), pages 354-362, December.
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