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Glassy thermal conductivity in Cs3Bi2I6Cl3 single crystal

Author

Listed:
  • Paribesh Acharyya

    (New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR))

  • Tanmoy Ghosh

    (New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR))

  • Koushik Pal

    (Theoretical Science Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR)
    Northwestern University)

  • Kewal Singh Rana

    (Indian Institute of Technology Mandi)

  • Moinak Dutta

    (New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR))

  • Diptikanta Swain

    (Institute of Chemical Technology-IndianOil Odisha Campus)

  • Martin Etter

    (Deutsches Elektronen-Synchrotron (DESY))

  • Ajay Soni

    (Indian Institute of Technology Mandi)

  • Umesh V. Waghmare

    (Theoretical Science Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR)
    School of Advanced Materials and International Centre for Materials Science, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR))

  • Kanishka Biswas

    (New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR)
    School of Advanced Materials and International Centre for Materials Science, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR))

Abstract

As the periodic atomic arrangement of a crystal is made to a disorder or glassy-amorphous system by destroying the long-range order, lattice thermal conductivity, κL, decreases, and its fundamental characteristics changes. The realization of ultralow and unusual glass-like κL in a crystalline material is challenging but crucial to many applications like thermoelectrics and thermal barrier coatings. Herein, we demonstrate an ultralow (~0.20 W/m·K at room temperature) and glass-like temperature dependence (2–400 K) of κL in a single crystal of layered halide perovskite, Cs3Bi2I6Cl3. Acoustic phonons with low cut-off frequency (20 cm−1) are responsible for the low sound velocity in Cs3Bi2I6Cl3 and make the structure elastically soft. While a strong anharmonicity originates from the low energy and localized rattling-like vibration of Cs atoms, synchrotron X-ray pair-distribution function evidence a local structural distortion in the Bi-halide octahedra and Cl vacancy. The hierarchical chemical bonding and soft vibrations from selective sublattice leading to low κL is intriguing from lattice dynamical perspective as well as have potential applications.

Suggested Citation

  • Paribesh Acharyya & Tanmoy Ghosh & Koushik Pal & Kewal Singh Rana & Moinak Dutta & Diptikanta Swain & Martin Etter & Ajay Soni & Umesh V. Waghmare & Kanishka Biswas, 2022. "Glassy thermal conductivity in Cs3Bi2I6Cl3 single crystal," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32773-4
    DOI: 10.1038/s41467-022-32773-4
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    1. Ruijin Sun & Jun Deng & Xiaowei Wu & Munan Hao & Ke Ma & Yuxin Ma & Changchun Zhao & Dezhong Meng & Xiaoyu Ji & Yiyang Ding & Yu Pang & Xin Qian & Ronggui Yang & Guodong Li & Zhilin Li & Linjie Dai & , 2023. "High anisotropy in electrical and thermal conductivity through the design of aerogel-like superlattice (NaOH)0.5NbSe2," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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