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Clathrate Hydrates for Thermal Energy Storage in Buildings: Overview of Proper Hydrate-Forming Compounds

Author

Listed:
  • Beatrice Castellani

    (IPASS, Engineering for Environment and Sustainable Development, Via G. Guerra, Perugia 06127, Italy)

  • Elena Morini

    (CIRIAF, Interuniversity Research Center on Pollution and Environment "M. Felli", University of Perugia, Via G. Duranti, Perugia 06125, Italy)

  • Mirko Filipponi

    (CIRIAF, Interuniversity Research Center on Pollution and Environment "M. Felli", University of Perugia, Via G. Duranti, Perugia 06125, Italy)

  • Andrea Nicolini

    (CIRIAF, Interuniversity Research Center on Pollution and Environment "M. Felli", University of Perugia, Via G. Duranti, Perugia 06125, Italy)

  • Massimo Palombo

    (CIRIAF, Interuniversity Research Center on Pollution and Environment "M. Felli", University of Perugia, Via G. Duranti, Perugia 06125, Italy)

  • Franco Cotana

    (CIRIAF, Interuniversity Research Center on Pollution and Environment "M. Felli", University of Perugia, Via G. Duranti, Perugia 06125, Italy)

  • Federico Rossi

    (CIRIAF, Interuniversity Research Center on Pollution and Environment "M. Felli", University of Perugia, Via G. Duranti, Perugia 06125, Italy)

Abstract

Increasing energy costs are at the origin of the great progress in the field of phase change materials (PCMs). The present work aims at studying the application of clathrate hydrates as PCMs in buildings. Clathrate hydrates are crystalline structures in which guest molecules are enclosed in the crystal lattice of water molecules. Clathrate hydrates can form also at ambient pressure and present a high latent heat, and for this reason, they are good candidates for being used as PCMs. The parameter that makes a PCM suitable to be used in buildings is, first of all, a melting temperature at about 25 °C. The paper provides an overview of groups of clathrate hydrates, whose physical and chemical characteristics could meet the requirements needed for their application in buildings. Simulations with a dynamic building simulation tool are carried out to evaluate the performance of clathrate hydrates in enhancing thermal comfort through the moderation of summer temperature swings and, therefore, in reducing energy consumption. Simulations suggest that clathrate hydrates have a potential in terms of improvement of indoor thermal comfort and a reduction of energy consumption for cooling. Cooling effects of 0.5 °C and reduced overheating hours of up to 1.1% are predicted.

Suggested Citation

  • Beatrice Castellani & Elena Morini & Mirko Filipponi & Andrea Nicolini & Massimo Palombo & Franco Cotana & Federico Rossi, 2014. "Clathrate Hydrates for Thermal Energy Storage in Buildings: Overview of Proper Hydrate-Forming Compounds," Sustainability, MDPI, vol. 6(10), pages 1-15, September.
    • Handle: RePEc:gam:jsusta:v:6:y:2014:i:10:p:6815-6829:d:40833
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    References listed on IDEAS

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    Cited by:

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    2. Kim, Hyunho & Zheng, Junjie & Yin, Zhenyuan & Babu, Ponnivalavan & Kumar, Sreekala & Tee, Jackson & Linga, Praveen, 2023. "Semi-clathrate hydrate slurry as a cold energy storage and transport medium: Rheological study, energy analysis and enhancement by amino acid," Energy, Elsevier, vol. 264(C).
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    4. Rossi, Federico & Castellani, Beatrice & Presciutti, Andrea & Morini, Elena & Filipponi, Mirko & Nicolini, Andrea & Santamouris, Matheos, 2015. "Retroreflective façades for urban heat island mitigation: Experimental investigation and energy evaluations," Applied Energy, Elsevier, vol. 145(C), pages 8-20.
    5. Elena Morini & Ali G. Touchaei & Beatrice Castellani & Federico Rossi & Franco Cotana, 2016. "The Impact of Albedo Increase to Mitigate the Urban Heat Island in Terni (Italy) Using the WRF Model," Sustainability, MDPI, vol. 8(10), pages 1-14, October.
    6. Ferdinando Salata & Anna Tarsitano & Iacopo Golasi & Emanuele De Lieto Vollaro & Massimo Coppi & Andrea De Lieto Vollaro, 2016. "Application of Absorption Systems Powered by Solar Ponds in Warm Climates for the Air Conditioning in Residential Buildings," Energies, MDPI, vol. 9(10), pages 1-18, October.
    7. Jyoti Shanker Pandey & Nicolas von Solms, 2022. "Metal–Organic Frameworks and Gas Hydrate Synergy: A Pandora’s Box of Unanswered Questions and Revelations," Energies, MDPI, vol. 16(1), pages 1-30, December.
    8. Satoshi Takeya & Sanehiro Muromachi & Tatsuo Maekawa & Yoshitaka Yamamoto & Hiroko Mimachi & Takahiro Kinoshita & Tetsuro Murayama & Hiroki Umeda & Dong-Hyuk Ahn & Yasunaga Iwasaki & Hidenori Hashimot, 2017. "Design of Ecological CO 2 Enrichment System for Greenhouse Production using TBAB + CO 2 Semi-Clathrate Hydrate," Energies, MDPI, vol. 10(7), pages 1-12, July.
    9. Kim, Hyunho & Zheng, Junjie & Yin, Zhenyuan & Kumar, Sreekala & Tee, Jackson & Seo, Yutaek & Linga, Praveen, 2022. "An electrical resistivity-based method for measuring semi-clathrate hydrate formation kinetics: Application for cold storage and transport," Applied Energy, Elsevier, vol. 308(C).

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