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PVC Dechlorination for Facilitating Plastic Chemical Recycling: A Systematic Literature Review of Technical Advances, Modeling and Assessment

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  • Yuan Tian

    (Innovation Centre for Environment and Resources, Shanghai University of Engineering Science, No. 333 Longteng Road, Songjiang District, Shanghai 201620, China
    These authors contributed equally to this work.)

  • Mengqi Han

    (Innovation Centre for Environment and Resources, Shanghai University of Engineering Science, No. 333 Longteng Road, Songjiang District, Shanghai 201620, China
    These authors contributed equally to this work.)

  • Dungang Gu

    (Innovation Centre for Environment and Resources, Shanghai University of Engineering Science, No. 333 Longteng Road, Songjiang District, Shanghai 201620, China)

  • Zhujie Bi

    (Shanghai Environmental Sanitary Engineering Design Institute Co., Ltd., Shanghai 200232, China)

  • Nannan Gu

    (Shanghai Environmental Sanitary Engineering Design Institute Co., Ltd., Shanghai 200232, China)

  • Tingting Hu

    (Innovation Centre for Environment and Resources, Shanghai University of Engineering Science, No. 333 Longteng Road, Songjiang District, Shanghai 201620, China)

  • Guanghui Li

    (Innovation Centre for Environment and Resources, Shanghai University of Engineering Science, No. 333 Longteng Road, Songjiang District, Shanghai 201620, China)

  • Nan Zhang

    (Centre for Process Integration, Department of Chemical Engineering and Analytical Science, The University of Manchester, Manchester M13 9PL, UK)

  • Jiaqi Lu

    (Innovation Centre for Environment and Resources, Shanghai University of Engineering Science, No. 333 Longteng Road, Songjiang District, Shanghai 201620, China)

Abstract

Polyvinyl chloride (PVC) resins are widely used in modern society due to their acid and alkali resistance, low cost, and strong insulation properties. However, the high chlorine (Cl) content in PVC poses significant challenges for its recycling. This study reviews the treatment processes, model construction, and economic and environmental assessments to construct a methodological framework for the sustainable development of emerging dechlorination technologies. In terms of treatment processes, this study summarizes three types of processes, pretreatment, simultaneous dechlorination during chemical recycling, product purification, and emphasizes the necessity of dechlorination treatment from a systematic perspective. Additionally, the construction of models for dechlorination processes is investigated from the laboratory to the industrial production system to macro-scale material, in order to evaluate the potential inventory data and material metabolism behaviors. This review also summarized the methodology framework of Techno-Economic Analysis (TEA) and Life Cycle Assessment (LCA), which can be applied for evaluation of the economic and environmental performance of the dechlorination processes. Overall, this review provides readers with a comprehensive perspective on the state-of-the-art for PVC dechlorination technologies, meanwhile offering sustainable guidance for future research and industrial applications of chemical recycling of PVC waste.

Suggested Citation

  • Yuan Tian & Mengqi Han & Dungang Gu & Zhujie Bi & Nannan Gu & Tingting Hu & Guanghui Li & Nan Zhang & Jiaqi Lu, 2024. "PVC Dechlorination for Facilitating Plastic Chemical Recycling: A Systematic Literature Review of Technical Advances, Modeling and Assessment," Sustainability, MDPI, vol. 16(19), pages 1-27, September.
    • Handle: RePEc:gam:jsusta:v:16:y:2024:i:19:p:8331-:d:1485356
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    References listed on IDEAS

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    3. Robert U. Ayres, 1998. "The Life Cycle of Chlorine, Part III," Journal of Industrial Ecology, Yale University, vol. 2(1), pages 93-115, January.
    4. Müller, C. & Hoffrichter, A. & Wyrwoll, L. & Schmitt, C. & Trageser, M. & Kulms, T. & Beulertz, D. & Metzger, M. & Duckheim, M. & Huber, M. & Küppers, M. & Most, D. & Paulus, S. & Heger, H.J. & Schnet, 2019. "Modeling framework for planning and operation of multi-modal energy systems in the case of Germany," Applied Energy, Elsevier, vol. 250(C), pages 1132-1146.
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    Cited by:

    1. Minoo Tehrani & Yu Cui, 2025. "Governance and Innovation in Plastic Waste Management: The Case of Japan," Sustainability, MDPI, vol. 17(21), pages 1-16, October.

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