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Efficient and Selective Catalytic Conversion of Hemicellulose in Rice Straw by Metal Catalyst under Mild Conditions

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  • Xiaorui Yang

    (College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, 30 South Puzhu Road, Nanjing 211800, China)

  • Jing Zhao

    (College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, 30 South Puzhu Road, Nanjing 211800, China)

  • Jinhua Liang

    (College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, 30 South Puzhu Road, Nanjing 211800, China)

  • Jianliang Zhu

    (College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, 30 South Puzhu Road, Nanjing 211800, China)

Abstract

Rice straw is an abundant material with the potential to be converted into a sustainable energy resource. Transition-metal catalysis activated the C–O bond in the hemicellulose of raw rice straw, cleaving it to form monosaccharides. The mechanism of rice straw catalytic conversion had a synergistic effect due to in situ acid catalysis and metal catalysis. The conditions for the hydrogenation of hemicellulose from rice straw were optimized: catalyst to rice straw solid/solid ratio of 3:10, stirring speed of 600 r/min, temperature of 160 °C, time of 3 h, solid/liquid ratio of 1:15, and H 2 gas pressure of 1.5 MPa. An excellent hemicellulose conversion of 97.3% with the yields of xylose and arabinose at 53.0% and 17.3%, respectively, were obtained. The results from FTIR and SEM experiments also confirmed the destruction of the rigidity and reticulate structure of rice straw after the catalytic reaction.

Suggested Citation

  • Xiaorui Yang & Jing Zhao & Jinhua Liang & Jianliang Zhu, 2020. "Efficient and Selective Catalytic Conversion of Hemicellulose in Rice Straw by Metal Catalyst under Mild Conditions," Sustainability, MDPI, vol. 12(24), pages 1-14, December.
  • Handle: RePEc:gam:jsusta:v:12:y:2020:i:24:p:10601-:d:464464
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    References listed on IDEAS

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    Cited by:

    1. Xiaorui Yang & Xiaotong Li & Jinhua Liang & Jianliang Zhu, 2023. "Comparative Study of Effective Pretreatments on the Structural Disruption and Hydrodepolymerization of Rice Straw," Sustainability, MDPI, vol. 15(6), pages 1-18, March.
    2. Xiaorui Yang & Xiaotong Li & Liyan Zhu & Jinhua Liang & Jianliang Zhu, 2023. "Production of Hemicellulose Sugars Combined with the Alkaline Extraction Lignin Increased the Hydro-Depolymerization of Cellulose from Corn Cob," Sustainability, MDPI, vol. 15(11), pages 1-19, June.

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