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Cadmium (Cd) and Nickel (Ni) Distribution on Size-Fractioned Soil Humic Substance (SHS)

Author

Listed:
  • Sheng-Hsien Hsieh

    (Department of Civil Engineering, National Pingtung University of Science and Technology, Pingtung 91201, Taiwan)

  • Teng-Pao Chiu

    (Department of Civil Engineering, National Pingtung University of Science and Technology, Pingtung 91201, Taiwan)

  • Wei-Shiang Huang

    (Department of Environmental Science and Engineering, National Pingtung University of Science and Technology, Pingtung 91201, Taiwan)

  • Ting-Chien Chen

    (Department of Environmental Science and Engineering, National Pingtung University of Science and Technology, Pingtung 91201, Taiwan)

  • Yi-Lung Yeh

    (Department of Civil Engineering, National Pingtung University of Science and Technology, Pingtung 91201, Taiwan)

Abstract

Soil humic substances (SHS) are heterogeneous, complex mixtures, whose concentration, chemical composition, and structure affect the transport and distribution of heavy metals. This study investigated the distribution behavior of two heavy metals [cadmium (Cd) and nickel (Ni)] in high molecular weight SHS (HMHS, 1 kDa–0.45 μm) and low molecular weight SHS (LMHS, <1 kDa) extracted from agricultural soils. The HMHS mass fractions were 45.1 ± 19.3%, 17.1 ± 6.7%, and 57.7 ± 18.5% for dissolved organic carbon (DOC), Cd, and Ni, respectively. The metal binding affinity, unit organic carbon binding with heavy metal ratios ([Me]/[DOC]), were between 0.41 ± 0.09 μmol/g-C and 7.29 ± 2.27 μmol/g-C. Cd preferred binding with LMHS ( p < 0.001), while Ni preferred binding with HMHS ( p < 0.001). The optical indicators SUVA 254 , S R , and FI were 3.16 ± 1.62 L/mg-C/m, 0.54 ± 0.18 and 1.57 ± 0.15, respectively for HMHS and 2.65 ± 1.25 L/mg-C/m, 0.40 ± 0.17, and 1.68 ± 0.12, respectively for LMHS. The HMHS contained more aromatic and lower FI values than LMHS. Multilinear regression showed a significant positive correlation between the measured predicted [Me]/[DOC] ratios (r = 0.52–0.72, p < 0.001). The results show that the optical indices can distinguish the chemical composition and structure of different size SHS and predict the binding ability of Me-SHS.

Suggested Citation

  • Sheng-Hsien Hsieh & Teng-Pao Chiu & Wei-Shiang Huang & Ting-Chien Chen & Yi-Lung Yeh, 2019. "Cadmium (Cd) and Nickel (Ni) Distribution on Size-Fractioned Soil Humic Substance (SHS)," IJERPH, MDPI, vol. 16(18), pages 1-11, September.
    • Handle: RePEc:gam:jijerp:v:16:y:2019:i:18:p:3398-:d:266949
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    References listed on IDEAS

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    2. Ludovico Pontoni & Eric D. Van Hullebusch & Yoan Pechaud & Massimiliano Fabbricino & Giovanni Esposito & Francesco Pirozzi, 2016. "Colloidal Mobilization and Fate of Trace Heavy Metals in Semi-Saturated Artificial Soil (OECD) Irrigated with Treated Wastewater," Sustainability, MDPI, vol. 8(12), pages 1-13, December.
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