IDEAS home Printed from https://ideas.repec.org/a/gam/jijerp/v16y2019i11p1976-d237008.html
   My bibliography  Save this article

XRD-Thermal Combined Analyses: An Approach to Evaluate the Potential of Phytoremediation, Phytomining, and Biochar Production

Author

Listed:
  • Dario Fancello

    (Department of Chemical and Geological Sciences, University of Cagliari, Cittadella Universitaria, 09042 Monserrato, Italy)

  • Jessica Scalco

    (Department of Chemical and Geological Sciences, University of Cagliari, Cittadella Universitaria, 09042 Monserrato, Italy)

  • Daniela Medas

    (Department of Chemical and Geological Sciences, University of Cagliari, Cittadella Universitaria, 09042 Monserrato, Italy)

  • Elisa Rodeghero

    (Department of Physics and Earth Sciences, University of Ferrara, I-44100 Ferrara, Italy)

  • Annalisa Martucci

    (Department of Physics and Earth Sciences, University of Ferrara, I-44100 Ferrara, Italy)

  • Carlo Meneghini

    (Department of Sciences, University Roma Tre, 00146 Rome, Italy)

  • Giovanni De Giudici

    (Department of Chemical and Geological Sciences, University of Cagliari, Cittadella Universitaria, 09042 Monserrato, Italy)

Abstract

A method for evaluating the potential of reuse of biomasses for economic purposes is here presented starting from a case study. Juncus acutus plants and rhizospheres were harvested from abandoned Zn–Pb mine areas of southwest Sardinia (Italy). Thermogravimetry and Differential Thermal analyses were performed to evaluate the temperatures at which significant reactions occur. X-ray Diffraction (XRD) analysis was carried out on raw samples and on samples heated ex-situ (by a conventional diffractometer) or in-situ (by synchrotron-based diffraction). Raw samples mainly consist of quartz, phyllosilicates, and feldspars with minor amounts of sulfides, sulfates, and Fe, Pb, and Zn carbonates, concentrated in the rhizosphere. After heating, Zn and Fe oxides and willemite are observed in internal roots and stems, revealing the presence of these metals in the plant tissues. In-situ heating was less effective than ex-situ in revealing minor phases in organic samples, probably because the scarcity of oxygen within the sample holder did not allow the degradation of organic compounds and the oxidation of sulfides, resulting in a low quality XRD signal even if obtained with the high resolution ensured by a synchrotron light source. This method can be applied to plants from polluted sites for metal exploitation, and/or to biomasses from unpolluted sites for biochar production, since both applications take advantage of the knowledge of the minerals formed after heating.

Suggested Citation

  • Dario Fancello & Jessica Scalco & Daniela Medas & Elisa Rodeghero & Annalisa Martucci & Carlo Meneghini & Giovanni De Giudici, 2019. "XRD-Thermal Combined Analyses: An Approach to Evaluate the Potential of Phytoremediation, Phytomining, and Biochar Production," IJERPH, MDPI, vol. 16(11), pages 1-20, June.
    • Handle: RePEc:gam:jijerp:v:16:y:2019:i:11:p:1976-:d:237008
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1660-4601/16/11/1976/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1660-4601/16/11/1976/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Stefano Cuccuru & Stefano Naitza & Francesco Secchi & Antonio Puccini & Leonardo Casini & Pamela Pavanetto & Ulf Linnemann & Mandy Hofmann & Giacomo Oggiano, 2016. "Structural and metallogenic map of late Variscan Arbus Pluton (SW Sardinia, Italy)," Journal of Maps, Taylor & Francis Journals, vol. 12(5), pages 860-865, October.
    2. Mohammad I. Jahirul & Mohammad G. Rasul & Ashfaque Ahmed Chowdhury & Nanjappa Ashwath, 2012. "Biofuels Production through Biomass Pyrolysis —A Technological Review," Energies, MDPI, vol. 5(12), pages 1-50, November.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yongtie, Cai & Zhimin, Zheng & Guang, Zeng & Wen, Wen & Lei, Luo & Wenming, Yang, 2022. "Quantitative phase analysis and rietveld texture determination of minerals in ash deposits in a 11.2 MW moving grate boiler," Energy, Elsevier, vol. 255(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Aboagye, D. & Banadda, N. & Kiggundu, N. & Kabenge, I., 2017. "Assessment of orange peel waste availability in ghana and potential bio-oil yield using fast pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 814-821.
    2. Lane, Blake & Kinnon, Michael Mac & Shaffer, Brendan & Samuelsen, Scott, 2022. "Deployment planning tool for environmentally sensitive heavy-duty vehicles and fueling infrastructure," Energy Policy, Elsevier, vol. 171(C).
    3. Primaz, Carmem T. & Ribes-Greus, Amparo & Jacques, Rosângela A., 2021. "Valorization of cotton residues for production of bio-oil and engineered biochar," Energy, Elsevier, vol. 235(C).
    4. Nabavi-Pelesaraei, Ashkan & Azadi, Hossein & Van Passel, Steven & Saber, Zahra & Hosseini-Fashami, Fatemeh & Mostashari-Rad, Fatemeh & Ghasemi-Mobtaker, Hassan, 2021. "Prospects of solar systems in production chain of sunflower oil using cold press method with concentrating energy and life cycle assessment," Energy, Elsevier, vol. 223(C).
    5. Taghizadeh-Alisaraei, Ahmad & Assar, Hossein Alizadeh & Ghobadian, Barat & Motevali, Ali, 2017. "Potential of biofuel production from pistachio waste in Iran," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 510-522.
    6. Kumar N, Sasi & Grekov, Denys & Pré, Pascaline & Alappat, Babu J., 2020. "Microwave mode of heating in the preparation of porous carbon materials for adsorption and energy storage applications – An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 124(C).
    7. Fabián Vargas & Armando Pérez & Rene Delgado & Emilio Hernández & José Alejandro Suástegui, 2019. "Performance Analysis of a Compression Ignition Engine Using Mixture Biodiesel Palm and Diesel," Sustainability, MDPI, vol. 11(18), pages 1-26, September.
    8. Neves, Renato Cruz & Klein, Bruno Colling & da Silva, Ricardo Justino & Rezende, Mylene Cristina Alves Ferreira & Funke, Axel & Olivarez-Gómez, Edgardo & Bonomi, Antonio & Maciel-Filho, Rubens, 2020. "A vision on biomass-to-liquids (BTL) thermochemical routes in integrated sugarcane biorefineries for biojet fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    9. Jouhara, H. & Nannou, T.K. & Anguilano, L. & Ghazal, H. & Spencer, N., 2017. "Heat pipe based municipal waste treatment unit for home energy recovery," Energy, Elsevier, vol. 139(C), pages 1210-1230.
    10. Kamel, Salah & El-Sattar, Hoda Abd & Vera, David & Jurado, Francisco, 2018. "Bioenergy potential from agriculture residues for energy generation in Egypt," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 28-37.
    11. Kawale, Harshal D. & Kishore, Nanda, 2019. "Production of hydrocarbons from a green algae (Oscillatoria) with exploration of its fuel characteristics over different reaction atmospheres," Energy, Elsevier, vol. 178(C), pages 344-355.
    12. M. N. Uddin & Kuaanan Techato & Juntakan Taweekun & Md Mofijur Rahman & M. G. Rasul & T. M. I. Mahlia & S. M. Ashrafur, 2018. "An Overview of Recent Developments in Biomass Pyrolysis Technologies," Energies, MDPI, vol. 11(11), pages 1-24, November.
    13. Andrew N. Amenaghawon & Chinedu L. Anyalewechi & Charity O. Okieimen & Heri Septya Kusuma, 2021. "Biomass pyrolysis technologies for value-added products: a state-of-the-art review," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(10), pages 14324-14378, October.
    14. Workson Siwale & Stefan Frodeson & Michael Finell & Mehrdad Arshadi & Carina Jonsson & Gunnar Henriksson & Jonas Berghel, 2022. "Understanding Off-Gassing of Biofuel Wood Pellets Using Pellets Produced from Pure Microcrystalline Cellulose with Different Additive Oils," Energies, MDPI, vol. 15(6), pages 1-12, March.
    15. Sánchez, M. & Clifford, B. & Nixon, J.D., 2018. "Modelling and evaluating a solar pyrolysis system," Renewable Energy, Elsevier, vol. 116(PA), pages 630-638.
    16. Farhad Beik & Leon Williams & Tim Brown & Stuart T. Wagland, 2021. "Managing Non-Sewered Human Waste Using Thermochemical Waste Treatment Technologies: A Review," Energies, MDPI, vol. 14(22), pages 1-22, November.
    17. Santos Dalólio, Felipe & da Silva, Jadir Nogueira & Carneiro de Oliveira, Angélica Cássia & Ferreira Tinôco, Ilda de Fátima & Christiam Barbosa, Rúben & Resende, Michael de Oliveira & Teixeira Albino,, 2017. "Poultry litter as biomass energy: A review and future perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 941-949.
    18. Ye-Eun Lee & Jun-Ho Jo & I-Tae Kim & Yeong-Seok Yoo, 2018. "Value-Added Performance and Thermal Decomposition Characteristics of Dumped Food Waste Compost by Pyrolysis," Energies, MDPI, vol. 11(5), pages 1-14, April.
    19. Juan Luis Aguirre & Juan Baena & María Teresa Martín & Leonor Nozal & Sergio González & José Luis Manjón & Manuel Peinado, 2020. "Composition, Ageing and Herbicidal Properties of Wood Vinegar Obtained through Fast Biomass Pyrolysis," Energies, MDPI, vol. 13(10), pages 1-17, May.
    20. Savvas L. Douvartzides & Nikolaos D. Charisiou & Kyriakos N. Papageridis & Maria A. Goula, 2019. "Green Diesel: Biomass Feedstocks, Production Technologies, Catalytic Research, Fuel Properties and Performance in Compression Ignition Internal Combustion Engines," Energies, MDPI, vol. 12(5), pages 1-41, February.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jijerp:v:16:y:2019:i:11:p:1976-:d:237008. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.