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Cobalt-Based Electrolytes for Dye-Sensitized Solar Cells: Recent Advances towards Stable Devices

Author

Listed:
  • Federico Bella

    (GAME Lab, CHENERGY Group, Department of Applied Science and Technology—DISAT, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy)

  • Simone Galliano

    (Department of Chemistry and NIS Interdepartmental Centre, Università degli Studi di Torino, Via Pietro Giuria 7, 10125 Torino, Italy)

  • Claudio Gerbaldi

    (GAME Lab, CHENERGY Group, Department of Applied Science and Technology—DISAT, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy)

  • Guido Viscardi

    (Department of Chemistry and NIS Interdepartmental Centre, Università degli Studi di Torino, Via Pietro Giuria 7, 10125 Torino, Italy)

Abstract

Redox mediators based on cobalt complexes allowed dye-sensitized solar cells (DSCs) to achieve efficiencies exceeding 14%, thus challenging the emerging class of perovskite solar cells. Unfortunately, cobalt-based electrolytes demonstrate much lower long-term stability trends if compared to the traditional iodide/triiodide redox couple. In view of the large-scale commercialization of cobalt-based DSCs, the scientific community has recently proposed various approaches and materials to increase the stability of these devices, which comprise gelling agents, crosslinked polymeric matrices and mixtures of solvents (including water). This review summarizes the most significant advances recently focused towards this direction, also suggesting some intriguing way to fabricate third-generation cobalt-based photoelectrochemical devices stable over time.

Suggested Citation

  • Federico Bella & Simone Galliano & Claudio Gerbaldi & Guido Viscardi, 2016. "Cobalt-Based Electrolytes for Dye-Sensitized Solar Cells: Recent Advances towards Stable Devices," Energies, MDPI, vol. 9(5), pages 1-22, May.
    • Handle: RePEc:gam:jeners:v:9:y:2016:i:5:p:384-:d:70410
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    References listed on IDEAS

    as
    1. Bandyopadhyay, Poonam & Nandy, Papiya & Basu, Ruma & Das, Sukhen, 2015. "Morphology dependent change in photovoltage generation using dye-Cu doped ZnO nanoparticle mixed system," Energy, Elsevier, vol. 89(C), pages 318-323.
    2. De Rossi, Francesca & Pontecorvo, Tadeo & Brown, Thomas M., 2015. "Characterization of photovoltaic devices for indoor light harvesting and customization of flexible dye solar cells to deliver superior efficiency under artificial lighting," Applied Energy, Elsevier, vol. 156(C), pages 413-422.
    3. Svitlana Karamshuk & Stefano Caramori & Norberto Manfredi & Matteo Salamone & Riccardo Ruffo & Stefano Carli & Carlo A. Bignozzi & Alessandro Abbotto, 2016. "Molecular Level Factors Affecting the Efficiency of Organic Chromophores for p -Type Dye Sensitized Solar Cells," Energies, MDPI, vol. 9(1), pages 1-17, January.
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    Cited by:

    1. Saradh Prasad & Devaraj Durairaj & Mohamad Saleh AlSalhi & Jayaraman Theerthagiri & Prabhakarn Arunachalam & Govindarajan Durai, 2018. "Fabrication of Cost-Effective Dye-Sensitized Solar Cells Using Sheet-Like CoS 2 Films and Phthaloylchitosan-Based Gel-Polymer Electrolyte," Energies, MDPI, vol. 11(2), pages 1-12, January.
    2. Iacopo Benesperi & Reena Singh & Marina Freitag, 2020. "Copper Coordination Complexes for Energy-Relevant Applications," Energies, MDPI, vol. 13(9), pages 1-19, May.
    3. I-Ming Hung & Ripon Bhattacharjee, 2016. "Effect of Photoanode Design on the Photoelectrochemical Performance of Dye-Sensitized Solar Cells Based on SnO 2 Nanocomposite," Energies, MDPI, vol. 9(8), pages 1-11, August.

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