IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v9y2016i4p229-d66325.html
   My bibliography  Save this article

Gas-Phase Mass-Transfer Resistances at Polymeric Electrolyte Membrane Fuel Cells Electrodes: Theoretical Analysis on the Effectiveness of Interdigitated and Serpentine Flow Arrangements

Author

Listed:
  • Elisabetta Arato

    (Department of Civil, Chemical and Environmental Engineering; University of Genoa, Via Opera Pia 15, Genoa -16145, Italy)

  • Marzia Pinna

    (Department of Civil, Chemical and Environmental Engineering; University of Genoa, Via Opera Pia 15, Genoa -16145, Italy)

  • Michela Mazzoccoli

    (Department of Civil, Chemical and Environmental Engineering; University of Genoa, Via Opera Pia 15, Genoa -16145, Italy)

  • Barbara Bosio

    (Department of Civil, Chemical and Environmental Engineering; University of Genoa, Via Opera Pia 15, Genoa -16145, Italy)

Abstract

Mass transfer phenomena in polymeric electrolyte membrane fuel cells (PEMFC) electrodes has already been analyzed in terms of the interactions between diffusive and forced flows. It was demonstrated that the whole phenomenon could be summarized by expressing the Sherwood number as a function of the Peclet number. The dependence of Sherwood number on Peclet one Sh(Pe) function, which was initially deduced by determining three different flow regimes, has now been given a more accurate description. A comparison between the approximate and the accurate results for a reference condition of diluted reactant and limit current has shown that the former are useful for rapid, preliminary calculations. However, a more precise and reliable estimation of the Sherwood number is worth attention, as it provides a detailed description of the electrochemical kinetics and allows a reliable comparison of the various geometrical arrangements used for the distribution of the reactants.

Suggested Citation

  • Elisabetta Arato & Marzia Pinna & Michela Mazzoccoli & Barbara Bosio, 2016. "Gas-Phase Mass-Transfer Resistances at Polymeric Electrolyte Membrane Fuel Cells Electrodes: Theoretical Analysis on the Effectiveness of Interdigitated and Serpentine Flow Arrangements," Energies, MDPI, vol. 9(4), pages 1-16, March.
    • Handle: RePEc:gam:jeners:v:9:y:2016:i:4:p:229-:d:66325
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/9/4/229/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/9/4/229/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Jian, Qi-fei & Ma, Guang-qing & Qiu, Xiao-liang, 2014. "Influences of gas relative humidity on the temperature of membrane in PEMFC with interdigitated flow field," Renewable Energy, Elsevier, vol. 62(C), pages 129-136.
    2. Chiu, Han-Chieh & Jang, Jer-Huan & Yan, Wei-Mon & Li, Hung-Yi & Liao, Chih-Cheng, 2012. "A three-dimensional modeling of transport phenomena of proton exchange membrane fuel cells with various flow fields," Applied Energy, Elsevier, vol. 96(C), pages 359-370.
    3. Abdollahzadeh, M. & Pascoa, J.C. & Ranjbar, A.A. & Esmaili, Q., 2014. "Analysis of PEM (Polymer Electrolyte Membrane) fuel cell cathode two-dimensional modeling," Energy, Elsevier, vol. 68(C), pages 478-494.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wu, Horng-Wen, 2016. "A review of recent development: Transport and performance modeling of PEM fuel cells," Applied Energy, Elsevier, vol. 165(C), pages 81-106.
    2. Ozen, Dilek Nur & Timurkutluk, Bora & Altinisik, Kemal, 2016. "Effects of operation temperature and reactant gas humidity levels on performance of PEM fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 1298-1306.
    3. Abdin, Z. & Webb, C.J. & Gray, E.MacA., 2016. "PEM fuel cell model and simulation in Matlab–Simulink based on physical parameters," Energy, Elsevier, vol. 116(P1), pages 1131-1144.
    4. Salva, J. Antonio & Iranzo, Alfredo & Rosa, Felipe & Tapia, Elvira, 2016. "Validation of cell voltage and water content in a PEM (polymer electrolyte membrane) fuel cell model using neutron imaging for different operating conditions," Energy, Elsevier, vol. 101(C), pages 100-112.
    5. Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    6. Guo, Hang & Liu, Xuan & Zhao, Jian Fu & Ye, Fang & Ma, Chong Fang, 2014. "Experimental study of two-phase flow in a proton exchange membrane fuel cell in short-term microgravity condition," Applied Energy, Elsevier, vol. 136(C), pages 509-518.
    7. Jiao, Kui & Bachman, John & Zhou, Yibo & Park, Jae Wan, 2014. "Effect of induced cross flow on flow pattern and performance of proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 115(C), pages 75-82.
    8. Saeidfar, Asal & Yesilyurt, Serhat, 2023. "Numerical investigation of the effects of catalyst layer composition and channel to rib width ratios for low platinum loaded PEMFCs," Applied Energy, Elsevier, vol. 339(C).
    9. Tian, Cong & Yuan, Fang & Deng, Tianlun & He, Qianhui & Hu, Cen & Chen, Yong & Liu, Wei, 2024. "Coupled optimization of auxiliary channels and porosity gradient of GDL for PEMFC," Energy, Elsevier, vol. 301(C).
    10. Wang, H.Y. & Yang, W.J. & Kim, Y.B., 2014. "Analyzing in-plane temperature distribution via a micro-temperature sensor in a unit polymer electrolyte membrane fuel cell," Applied Energy, Elsevier, vol. 124(C), pages 148-155.
    11. Hu, Junming & Li, Jianqiu & Xu, Liangfei & Huang, Fusen & Ouyang, Minggao, 2016. "Analytical calculation and evaluation of water transport through a proton exchange membrane fuel cell based on a one-dimensional model," Energy, Elsevier, vol. 111(C), pages 869-883.
    12. Qiu, Diankai & Peng, Linfa & Tang, Jiayu & Lai, Xinmin, 2020. "Numerical analysis of air-cooled proton exchange membrane fuel cells with various cathode flow channels," Energy, Elsevier, vol. 198(C).
    13. Chen, Xi & Wang, Chunxi & Xu, Jianghai & Long, Shichun & Chai, Fasen & Li, Wenbin & Song, Xingxing & Wang, Xuepeng & Wan, Zhongmin, 2023. "Membrane humidity control of proton exchange membrane fuel cell system using fractional-order PID strategy," Applied Energy, Elsevier, vol. 343(C).
    14. Zhang, Qian & Lin, Rui & Técher, Ludovic & Cui, Xin, 2016. "Experimental study of variable operating parameters effects on overall PEMFC performance and spatial performance distribution," Energy, Elsevier, vol. 115(P1), pages 550-560.
    15. Baricci, Andrea & Mereu, Riccardo & Messaggi, Mirko & Zago, Matteo & Inzoli, Fabio & Casalegno, Andrea, 2017. "Application of computational fluid dynamics to the analysis of geometrical features in PEM fuel cells flow fields with the aid of impedance spectroscopy," Applied Energy, Elsevier, vol. 205(C), pages 670-682.
    16. Singdeo, Debanand & Dey, Tapobrata & Gaikwad, Shrihari & Andreasen, Søren Juhl & Ghosh, Prakash C., 2017. "A new modified-serpentine flow field for application in high temperature polymer electrolyte fuel cell," Applied Energy, Elsevier, vol. 195(C), pages 13-22.
    17. Wang, Bowen & Deng, Hao & Jiao, Kui, 2018. "Purge strategy optimization of proton exchange membrane fuel cell with anode recirculation," Applied Energy, Elsevier, vol. 225(C), pages 1-13.
    18. Mojtaba Baghban Yousefkhani & Hossein Ghadamian & Keyvan Daneshvar & Nima Alizadeh & Brendy C. Rincon Troconis, 2020. "Investigation of the Fuel Utilization Factor in PEM Fuel Cell Considering the Effect of Relative Humidity at the Cathode," Energies, MDPI, vol. 13(22), pages 1-11, November.
    19. Xie, Biao & Zhang, Hanyang & Huo, Wenming & Wang, Renfang & Zhu, Ying & Wu, Lizhen & Zhang, Guobin & Ni, Meng & Jiao, Kui, 2023. "Large-scale three-dimensional simulation of proton exchange membrane fuel cell considering detailed water transition mechanism," Applied Energy, Elsevier, vol. 331(C).
    20. Pandu Ranga Tirumalasetti & Fang-Bor Weng & Mangaliso Menzi Dlamini & Chia-Hung Chen, 2024. "Numerical Simulation of Double Layered Wire Mesh Integration on the Cathode for a Proton Exchange Membrane Fuel Cell (PEMFC)," Energies, MDPI, vol. 17(2), pages 1-15, January.

    More about this item

    Keywords

    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:9:y:2016:i:4:p:229-:d:66325. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.