IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v17y2024i4p863-d1337889.html
   My bibliography  Save this article

Optimizing Seaweed ( Ascophyllum nodosum ) Thermal Pyrolysis for Environmental Sustainability: A Response Surface Methodology Approach and Analysis of Bio-Oil Properties

Author

Listed:
  • Zahidul Islam Rony

    (Fuel and Energy Research Group, School of Engineering and Technology, Central Queensland University, Norman Gardens, QLD 4701, Australia)

  • Mohammad Golam Rasul

    (Fuel and Energy Research Group, School of Engineering and Technology, Central Queensland University, Norman Gardens, QLD 4701, Australia)

  • Md Islam Jahirul

    (Fuel and Energy Research Group, School of Engineering and Technology, Central Queensland University, Norman Gardens, QLD 4701, Australia)

  • Mohammad Mehedi Hasan

    (Fuel and Energy Research Group, School of Engineering and Technology, Central Queensland University, Norman Gardens, QLD 4701, Australia)

Abstract

This study focuses on optimizing the thermal pyrolysis process to maximize pyrolysis oil yield using marine biomass or seaweed. The process, conducted in a batch reactor, was optimized using response surface methodology and Box–Behnken design. Variables like temperature, residence time, and stirring speed were adjusted to maximize bio-oil yield. The optimal conditions yielded 42.94% bio-oil at 463.13 °C, with a residence time of 65.75 min and stirring speed of 9.74 rpm. The analysis showed that temperature is the most critical factor for maximizing yield. The bio-oil produced contains 11 functional groups, primarily phenol, aromatics, and alcohol. Its high viscosity and water content make it unsuitable for engines but suitable for other applications like boilers and chemical additives. It is recommended to explore the potential of refining the bio-oil to reduce its viscosity and water content, making it more suitable for broader applications, including in engine fuels. Further research could also investigate the environmental impact and economic feasibility of scaling up this process.

Suggested Citation

  • Zahidul Islam Rony & Mohammad Golam Rasul & Md Islam Jahirul & Mohammad Mehedi Hasan, 2024. "Optimizing Seaweed ( Ascophyllum nodosum ) Thermal Pyrolysis for Environmental Sustainability: A Response Surface Methodology Approach and Analysis of Bio-Oil Properties," Energies, MDPI, vol. 17(4), pages 1-23, February.
  • Handle: RePEc:gam:jeners:v:17:y:2024:i:4:p:863-:d:1337889
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/17/4/863/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/17/4/863/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Hasan, M.M. & Rasul, M.G. & Ashwath, N. & Khan, M.M.K. & Jahirul, M.I., 2022. "Fast pyrolysis of Beauty Leaf Fruit Husk (BLFH) in an auger reactor: Effect of temperature on the yield and physicochemical properties of BLFH oil," Renewable Energy, Elsevier, vol. 194(C), pages 1098-1109.
    2. Nam, Hyungseok & Capareda, Sergio C. & Ashwath, Nanjappa & Kongkasawan, Jinjuta, 2015. "Experimental investigation of pyrolysis of rice straw using bench-scale auger, batch and fluidized bed reactors," Energy, Elsevier, vol. 93(P2), pages 2384-2394.
    3. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Teka Tesfaye Mengesha & Venkata Ramayya Ancha & Abebe Nigussie & Million Merid Afessa & Ramchandra Bhandari, 2025. "Effect of Particle Size and Heating Rate on Formation of Polycyclic Aromatic Hydrocarbons During Corn Cob Biomass Pyrolysis," Sustainability, MDPI, vol. 17(11), pages 1-34, May.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mika Pahnila & Aki Koskela & Petri Sulasalmi & Timo Fabritius, 2023. "A Review of Pyrolysis Technologies and the Effect of Process Parameters on Biocarbon Properties," Energies, MDPI, vol. 16(19), pages 1-27, October.
    2. M. M. Hasan & M. G. Rasul & M. I. Jahirul & M. M. K. Khan, 2024. "Fast Pyrolysis of Municipal Green Waste in an Auger Reactor: Effects of Residence Time and Particle Size on the Yield and Characteristics of Produced Oil," Energies, MDPI, vol. 17(12), pages 1-23, June.
    3. Ayub, Yousaf & Ren, Jingzheng & Shi, Tao & Shen, Weifeng & He, Chang, 2023. "Poultry litter valorization: Development and optimization of an electro-chemical and thermal tri-generation process using an extreme gradient boosting algorithm," Energy, Elsevier, vol. 263(PC).
    4. Elhambakhsh, Abbas & Van Duc Long, Nguyen & Lamichhane, Pradeep & Hessel, Volker, 2023. "Recent progress and future directions in plasma-assisted biomass conversion to hydrogen," Renewable Energy, Elsevier, vol. 218(C).
    5. Zhao, Ming & Memon, Muhammad Zaki & Ji, Guozhao & Yang, Xiaoxiao & Vuppaladadiyam, Arun K. & Song, Yinqiang & Raheem, Abdul & Li, Jinhui & Wang, Wei & Zhou, Hui, 2020. "Alkali metal bifunctional catalyst-sorbents enabled biomass pyrolysis for enhanced hydrogen production," Renewable Energy, Elsevier, vol. 148(C), pages 168-175.
    6. Zang, Guiyan & Zhang, Jianan & Jia, Junxi & Lora, Electo Silva & Ratner, Albert, 2020. "Life cycle assessment of power-generation systems based on biomass integrated gasification combined cycles," Renewable Energy, Elsevier, vol. 149(C), pages 336-346.
    7. Kumar, R. & Strezov, V., 2021. "Thermochemical production of bio-oil: A review of downstream processing technologies for bio-oil upgrading, production of hydrogen and high value-added products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    8. Gupta, Shubhi & Gupta, Goutam Kishore & Mondal, Monoj Kumar, 2019. "Slow pyrolysis of chemically treated walnut shell for valuable products: Effect of process parameters and in-depth product analysis," Energy, Elsevier, vol. 181(C), pages 665-676.
    9. Adnan, Muflih A. & Hossain, Mohammad M. & Kibria, Md Golam, 2020. "Biomass upgrading to high-value chemicals via gasification and electrolysis: A thermodynamic analysis," Renewable Energy, Elsevier, vol. 162(C), pages 1367-1379.
    10. Xing Yang & Hailong Wang & Peter James Strong & Song Xu & Shujuan Liu & Kouping Lu & Kuichuan Sheng & Jia Guo & Lei Che & Lizhi He & Yong Sik Ok & Guodong Yuan & Ying Shen & Xin Chen, 2017. "Thermal Properties of Biochars Derived from Waste Biomass Generated by Agricultural and Forestry Sectors," Energies, MDPI, vol. 10(4), pages 1-12, April.
    11. M. N. Uddin & Kuaanan Techato & Juntakan Taweekun & Md Mofijur Rahman & M. G. Rasul & T. M. I. Mahlia & S. M. Ashrafur, 2018. "An Overview of Recent Developments in Biomass Pyrolysis Technologies," Energies, MDPI, vol. 11(11), pages 1-24, November.
    12. Lech Nowicki & Dorota Siuta & Maciej Markowski, 2020. "Pyrolysis of Rapeseed Oil Press Cake and Steam Gasification of Solid Residues," Energies, MDPI, vol. 13(17), pages 1-12, August.
    13. Pérez, Nestor Proenza & Pedroso, Daniel Travieso & Machin, Einara Blanco & Antunes, Julio Santana & Tuna, Celso Eduardo & Silveira, José Luz, 2019. "Geometrical characteristics of sugarcane bagasse for being used as fuel in fluidized bed technologies," Renewable Energy, Elsevier, vol. 143(C), pages 1210-1224.
    14. Choi, Yujin & Wang, Shuang & Yoon, Young Min & Jang, Jae Jun & Kim, Daewook & Ryu, Ho-Jung & Lee, Doyeon & Won, Yooseob & Nam, Hyungseok & Hwang, Byungwook, 2024. "Sustainable strategy for converting plastic waste into energy over pyrolysis: A comparative study of fluidized-bed and fixed-bed reactors," Energy, Elsevier, vol. 286(C).
    15. Luo, Miaoling & Shao, Shanshan & Cao, Yu & Li, Xiaohua & Wu, Shiliang, 2025. "A study on the characteristics and kinetic of co-catalytic pyrolysis with rape straw and ABS waste plastics," Renewable Energy, Elsevier, vol. 242(C).
    16. Liu, Hui & Liu, Jingyong & Huang, Hongyi & Evrendilek, Fatih & Wen, Shaoting & Li, Weixin, 2021. "Optimizing bioenergy and by-product outputs from durian shell pyrolysis," Renewable Energy, Elsevier, vol. 164(C), pages 407-418.
    17. Pang, Yunji & Wu, Yuting & Chen, Yisheng & Luo, Fuliang & Chen, Junjun, 2020. "Degradation effect of Ce/Al2O3 catalyst on pyrolysis volatility of pine," Renewable Energy, Elsevier, vol. 162(C), pages 134-143.
    18. Burov, Nikita O. & Savelenko, Vsevolod D. & Ershov, Mikhail A. & Vikhritskaya, Anastasia O. & Tikhomirova, Ekaterina O. & Klimov, Nikita A. & Kapustin, Vladimir M. & Chernysheva, Elena A. & Sereda, Al, 2023. "Knowledge contribution from science to technology in the conceptualization model to produce sustainable aviation fuels from lignocellulosic biomass," Renewable Energy, Elsevier, vol. 215(C).
    19. Lacrimioara Senila & Ioan Tenu & Petru Carlescu & Daniela Alexandra Scurtu & Eniko Kovacs & Marin Senila & Oana Cadar & Marius Roman & Diana Elena Dumitras & Cecilia Roman, 2022. "Characterization of Biobriquettes Produced from Vineyard Wastes as a Solid Biofuel Resource," Agriculture, MDPI, vol. 12(3), pages 1-13, February.
    20. Kim, D. & Hadigheh, S.A., 2024. "Oxidative pyrolysis of biosolid: Air concentration effects on biochar formation and kinetics," Renewable Energy, Elsevier, vol. 224(C).

    More about this item

    Keywords

    ;
    ;
    ;
    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:17:y:2024:i:4:p:863-:d:1337889. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.