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Study on Anode Catalyst Layer Configuration for Proton Exchange Membrane Fuel Cell with Enhanced Reversal Tolerance and Polarization Performance

Author

Listed:
  • Xia Sheng

    (State Key Laboratory of Engines, 135 Yaguan Rd., Tianjin 300350, China
    Powertrain Department, General Institute of FAW, Changchun 130011, China
    These authors contributed equally to this work.)

  • Chunyu Ru

    (Powertrain Department, General Institute of FAW, Changchun 130011, China
    These authors contributed equally to this work.)

  • Honghui Zhao

    (Powertrain Department, General Institute of FAW, Changchun 130011, China)

  • Shouyi Jin

    (Powertrain Department, General Institute of FAW, Changchun 130011, China)

  • Bowen Wang

    (State Key Laboratory of Engines, 135 Yaguan Rd., Tianjin 300350, China)

  • Yupeng Wang

    (State Key Laboratory of Engines, 135 Yaguan Rd., Tianjin 300350, China
    Powertrain Department, General Institute of FAW, Changchun 130011, China)

  • Linghai Han

    (Powertrain Department, General Institute of FAW, Changchun 130011, China)

  • Kui Jiao

    (State Key Laboratory of Engines, 135 Yaguan Rd., Tianjin 300350, China)

Abstract

Hydrogen starvation leads to the extreme deterioration of fuel cell performance due to the induced voltage reversal and carbon corrosion in the anode catalyst layer (ACL) and gas diffusion layer. In this paper, reversal-tolerant anodes (RTAs) with different ACL configurations are proposed, where IrO x /C is used as a water electrolysis catalyst. Experimental results show that the separate IrO x /C catalyst layer of MEA samples, layered reversal-tolerant catalyst-coated membrane (layered-RTA), and reversal-tolerant gas diffusion electrode (GDE-RTA) significantly enhance the reversal tolerance and cell performance compared to conventional anode and common RTA consisting of a homogeneous catalyst layer mixed with IrO x /C and Pt/C (hybrid-RTA). Of these, GDE-RTA possessed a reversal tolerance time of 86 min, a power density of 1.42 W cm −2 , and a minimum degradation rate of 2.4 mV min −1 , suggesting it to be the best RTA structure. Cyclic voltammetry and electrochemical impedance spectrum were used to detect the properties of each sample. Additionally, the degradation mechanisms of the three RTAs are thoroughly investigated and discussed by means of microstructural characterization through scanning electron microscopy and transmission electron microscopy. This work provides novel ideas for the fabrication of a robust RTA by tuning the ACL configuration, which is practical for the commercialization of fuel cells.

Suggested Citation

  • Xia Sheng & Chunyu Ru & Honghui Zhao & Shouyi Jin & Bowen Wang & Yupeng Wang & Linghai Han & Kui Jiao, 2022. "Study on Anode Catalyst Layer Configuration for Proton Exchange Membrane Fuel Cell with Enhanced Reversal Tolerance and Polarization Performance," Energies, MDPI, vol. 15(8), pages 1-13, April.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:8:p:2732-:d:789463
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    References listed on IDEAS

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    1. Olabi, A.G. & Wilberforce, Tabbi & Abdelkareem, Mohammad Ali, 2021. "Fuel cell application in the automotive industry and future perspective," Energy, Elsevier, vol. 214(C).
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