IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i23p9195-d993184.html
   My bibliography  Save this article

Characteristics of Hydrothermal Carbonization Hydrochar Derived from Cattle Manure

Author

Listed:
  • Eunhye Song

    (Bio Resource Center, Institute for Advanced Engineering, Yongin-si 17180, Republic of Korea)

  • Seyong Park

    (Bio Resource Center, Institute for Advanced Engineering, Yongin-si 17180, Republic of Korea)

  • Seongkuk Han

    (Bio Resource Center, Institute for Advanced Engineering, Yongin-si 17180, Republic of Korea)

  • Eusil Lee

    (Bio Resource Center, Institute for Advanced Engineering, Yongin-si 17180, Republic of Korea)

  • Ho Kim

    (Bio Resource Center, Institute for Advanced Engineering, Yongin-si 17180, Republic of Korea)

Abstract

The characteristics of hydrothermal carbonization hydrochar derived from cattle manure including excrements and lignocellulosic biomass were analyzed. The effects of hydrothermal carbonization were evaluated by varying the reaction temperatures in the range of 180~240 °C. The hydrochars were evaluated with respect to their usefulness as renewable fuels via physicochemical analysis and pyrolysis processes. As reaction temperatures increased, the fractions of fixed carbon in proximate analyses, carbon elements in ultimate analyses, and higher heating values of hydrothermally carbonized biochars increased in correlation with the primary reactions of coalification. Various correlations were derived with the characteristics of hydrochars in order to be utilized for operating and designing HTC reactors for cattle manure. The correlation between the O/C and H/C ratios was deduced on the basis of a van Krevelen diagram. The interaction equation was represented with the increased fraction of HHV compared to the reaction temperature of hydrothermal carbonization. The ultimate correlation for the estimation of higher heating values was suggested for HTC hydrochars. Moreover, the pyrolysis characteristics and kinetic parameters of the cattle manure and hydrochar were deduced by utilizing a multi-step kinetic model scheme. As the HTC reaction temperature increased, the global activation energy and the pre-exponential factors of hydrochars decreased in the low-temperature section and increased in the high-temperature section.

Suggested Citation

  • Eunhye Song & Seyong Park & Seongkuk Han & Eusil Lee & Ho Kim, 2022. "Characteristics of Hydrothermal Carbonization Hydrochar Derived from Cattle Manure," Energies, MDPI, vol. 15(23), pages 1-14, December.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:23:p:9195-:d:993184
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/23/9195/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/23/9195/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Marin-Batista, J.D. & Villamil, J.A. & Qaramaleki, S.V. & Coronella, C.J. & Mohedano, A.F. & Rubia, M.A. de la, 2020. "Energy valorization of cow manure by hydrothermal carbonization and anaerobic digestion," Renewable Energy, Elsevier, vol. 160(C), pages 623-632.
    2. Aneta Szymajda & Grażyna Łaska & Magdalena Joka, 2021. "Assessment of Cow Dung Pellets as a Renewable Solid Fuel in Direct Combustion Technologies," Energies, MDPI, vol. 14(4), pages 1-15, February.
    3. Wang, Tengfei & Zhai, Yunbo & Zhu, Yun & Li, Caiting & Zeng, Guangming, 2018. "A review of the hydrothermal carbonization of biomass waste for hydrochar formation: Process conditions, fundamentals, and physicochemical properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 223-247.
    4. Wang, Guangwei & Zhang, Jianliang & Lee, Jui-Yuan & Mao, Xiaoming & Ye, Lian & Xu, Wanren & Ning, Xiaojun & Zhang, Nan & Teng, Haipeng & Wang, Chuan, 2020. "Hydrothermal carbonization of maize straw for hydrochar production and its injection for blast furnace," Applied Energy, Elsevier, vol. 266(C).
    5. Yuan, Xinsong & He, Tao & Cao, Hongliang & Yuan, Qiaoxia, 2017. "Cattle manure pyrolysis process: Kinetic and thermodynamic analysis with isoconversional methods," Renewable Energy, Elsevier, vol. 107(C), pages 489-496.
    6. Michela Lucian & Maurizio Volpe & Luca Fiori, 2019. "Hydrothermal Carbonization Kinetics of Lignocellulosic Agro-Wastes: Experimental Data and Modeling," Energies, MDPI, vol. 12(3), pages 1-20, February.
    7. Aaron E. Brown & Jessica M. M. Adams & Oliver R. Grasham & Miller Alonso Camargo-Valero & Andrew B. Ross, 2020. "An Assessment of Different Integration Strategies of Hydrothermal Carbonisation and Anaerobic Digestion of Water Hyacinth," Energies, MDPI, vol. 13(22), pages 1-26, November.
    8. Gao, Pin & Zhou, Yiyuan & Meng, Fang & Zhang, Yihui & Liu, Zhenhong & Zhang, Wenqi & Xue, Gang, 2016. "Preparation and characterization of hydrochar from waste eucalyptus bark by hydrothermal carbonization," Energy, Elsevier, vol. 97(C), pages 238-245.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Roksana Muzyka & Szymon Sobek & Mariusz Dudziak & Miloud Ouadi & Marcin Sajdak, 2023. "A Comparative Analysis of Waste Biomass Pyrolysis in Py-GC-MS and Fixed-Bed Reactors," Energies, MDPI, vol. 16(8), pages 1-15, April.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Aragón-Briceño, C.I. & Pozarlik, A.K. & Bramer, E.A. & Niedzwiecki, Lukasz & Pawlak-Kruczek, H. & Brem, G., 2021. "Hydrothermal carbonization of wet biomass from nitrogen and phosphorus approach: A review," Renewable Energy, Elsevier, vol. 171(C), pages 401-415.
    2. Eunhye Song & Ho Kim & Kyung Woo Kim & Young-Man Yoon, 2023. "Characteristic Evaluation of Different Carbonization Processes for Hydrochar, Torrefied Char, and Biochar Produced from Cattle Manure," Energies, MDPI, vol. 16(7), pages 1-14, April.
    3. Cheng, Chen & Ding, Lu & Guo, Qinghua & He, Qing & Gong, Yan & Alexander, Kozlov N. & Yu, Guangsuo, 2022. "Process analysis and kinetic modeling of coconut shell hydrothermal carbonization," Applied Energy, Elsevier, vol. 315(C).
    4. Kai Wang & Jianliang Zhang & Shengli Wu & Jianlong Wu & Kun Xu & Jiawen Liu & Xiaojun Ning & Guangwei Wang, 2022. "Feasibility Analysis of Biomass Hydrochar Blended Coal Injection for Blast Furnace," Sustainability, MDPI, vol. 14(17), pages 1-17, August.
    5. Tao Li & Guangwei Wang & Heng Zhou & Xiaojun Ning & Cuiliu Zhang, 2022. "Numerical Simulation Study on the Effects of Co-Injection of Pulverized Coal and Hydrochar into the Blast Furnace," Sustainability, MDPI, vol. 14(8), pages 1-13, April.
    6. Yan, Mi & Liu, Yu & Song, Yucai & Xu, Aiming & Zhu, Gaojun & Jiang, Jiahao & Hantoko, Dwi, 2022. "Comprehensive experimental study on energy conversion of household kitchen waste via integrated hydrothermal carbonization and supercritical water gasification," Energy, Elsevier, vol. 242(C).
    7. Izabella Maj & Sylwester Kalisz & Szymon Ciukaj, 2022. "Properties of Animal-Origin Ash—A Valuable Material for Circular Economy," Energies, MDPI, vol. 15(4), pages 1-15, February.
    8. Liu, Quan & Zhang, Guanyu & Kong, Ge & Liu, Mingyang & Cao, Tianqi & Guo, Zhirui & Zhang, Xuesong & Han, Lujia, 2023. "Valorizing manure waste into green coal-like hydrochar: Parameters study, physicochemical characteristics, combustion behaviors and kinetics," Renewable Energy, Elsevier, vol. 216(C).
    9. Umut Şen & Bruno Esteves & Helena Pereira, 2023. "Pyrolysis and Extraction of Bark in a Biorefineries Context: A Critical Review," Energies, MDPI, vol. 16(13), pages 1-23, June.
    10. Yuchiao Lu & Hanmin Yang & Andrey V. Karasev & Chuan Wang & Pär G. Jönsson, 2022. "Applications of Hydrochar and Charcoal in the Iron and Steelmaking Industry—Part 1: Characterization of Carbonaceous Materials," Sustainability, MDPI, vol. 14(15), pages 1-27, August.
    11. Pecchi, Matteo & Patuzzi, Francesco & Benedetti, Vittoria & Di Maggio, Rosa & Baratieri, Marco, 2020. "Kinetic analysis of hydrothermal carbonization using high-pressure differential scanning calorimetry applied to biomass," Applied Energy, Elsevier, vol. 265(C).
    12. Azzaz, Ahmed Amine & Khiari, Besma & Jellali, Salah & Ghimbeu, Camélia Matei & Jeguirim, Mejdi, 2020. "Hydrochars production, characterization and application for wastewater treatment: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 127(C).
    13. Antonio Picone & Maurizio Volpe & Antonio Messineo, 2021. "Process Water Recirculation during Hydrothermal Carbonization of Waste Biomass: Current Knowledge and Challenges," Energies, MDPI, vol. 14(10), pages 1-14, May.
    14. Aaron E. Brown & James M. Hammerton & Miller Alonso Camargo-Valero & Andrew B. Ross, 2022. "Integration of Hydrothermal Carbonisation and Anaerobic Digestion for the Energy Valorisation of Grass," Energies, MDPI, vol. 15(10), pages 1-21, May.
    15. Samuel Carrasco & Ernesto Pino-Cortés & Andrés Barra-Marín & Alejandro Fierro-Gallegos & Marcelo León, 2022. "Use of Hydrochar Produced by Hydrothermal Carbonization of Lignocellulosic Biomass for Thermal Power Plants in Chile: A Techno-Economic and Environmental Study," Sustainability, MDPI, vol. 14(13), pages 1-17, June.
    16. Wojciech Rzeźnik & Ilona Rzeźnik & Paulina Mielcarek-Bocheńska & Mateusz Urbański, 2023. "Air Pollutants Emission during Co-Combustion of Animal Manure and Wood Pellets in 15 kW Boiler," Energies, MDPI, vol. 16(18), pages 1-17, September.
    17. Sun, Minmin & Zhang, Jianliang & Li, Kejiang & Barati, Mansoor & Liu, Zhibin, 2022. "Co-gasification characteristics of coke blended with hydro-char and pyro-char from bamboo," Energy, Elsevier, vol. 241(C).
    18. Vlachokostas, Ch. & Michailidou, A.V. & Achillas, Ch., 2021. "Multi-Criteria Decision Analysis towards promoting Waste-to-Energy Management Strategies: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    19. Li, Fenghai & Zhao, Chaoyue & Guo, Qianqian & Li, Yang & Fan, Hongli & Guo, Mingxi & Wu, Lishun & Huang, Jiejie & Fang, Yitian, 2020. "Exploration in ash-deposition (AD) behavior modification of low-rank coal by manure addition," Energy, Elsevier, vol. 208(C).
    20. Tiago Teribele & Maria Elizabeth Gemaque Costa & Conceição de Maria Sales da Silva & Lia Martins Pereira & Lucas Pinto Bernar & Douglas Alberto Rocha de Castro & Fernanda Paula da Costa Assunção & Mar, 2023. "Hydrothermal Carbonization of Corn Stover: Structural Evolution of Hydro-Char and Degradation Kinetics," Energies, MDPI, vol. 16(7), pages 1-22, April.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:23:p:9195-:d:993184. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.