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Comparison of Bimetallic Fe-Cu and Fe-Ca Oxygen Carriers for Biomass Gasification

Author

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  • Beatrice Muriungi

    (Department of Chemical, Biological, and Bioengineering, North Carolina Agricultural and Technical State University, 1601 East Market Street, Greensboro, NC 27411, USA)

  • Lijun Wang

    (Department of Chemical, Biological, and Bioengineering, North Carolina Agricultural and Technical State University, 1601 East Market Street, Greensboro, NC 27411, USA
    Department of Natural Resources and Environmental Design, North Carolina Agricultural and Technical State University, 1601 East Market Street, Greensboro, NC 27411, USA)

  • Abolghasem Shahbazi

    (Department of Chemical, Biological, and Bioengineering, North Carolina Agricultural and Technical State University, 1601 East Market Street, Greensboro, NC 27411, USA
    Department of Natural Resources and Environmental Design, North Carolina Agricultural and Technical State University, 1601 East Market Street, Greensboro, NC 27411, USA)

Abstract

Two bimetallic Fe-Cu and Fe-Ca oxygen carriers were studied for chemical looping gasification (CLG) of biomass. The SEM results indicated that there was no obvious agglomeration on the bimetallic Fe-Cu oxygen carrier supported on Al 2 O 3 and Fe-Ca oxygen carrier after five redox cycles while agglomeration occurred on CuO supported on Al 2 O 3 due to the low melting point of CuO. The XRD results indicated the presence of copper-ferrite and calcium-ferrite phases in the bimetallic materials. The two bimetallic oxygen carriers can be re-oxidized with air to form a crystalline that is similar to the fresh materials. The Fe-Ca oxide became active at 360 °C which was lower than 380 °C for the Fe-Cu oxygen carrier. The high thermal stability and redox reactivity of bimetallic Fe-Cu and Fe-Ca oxygen carriers make the bimetallic oxygen carriers more suitable for recycling during CLG. The method for preparing Fe-Cu oxygen carriers had no significant impact on biomass conversion efficiency but had significant effect on the quality of syngas. Proper control of the biomass/oxygen carrier mass ratio is critical to achieve high selectivity towards gasification instead of combustion. The Fe-Ca oxygen carrier could achieve higher selectivity towards gasification than the Fe-Cu oxygen carrier.

Suggested Citation

  • Beatrice Muriungi & Lijun Wang & Abolghasem Shahbazi, 2020. "Comparison of Bimetallic Fe-Cu and Fe-Ca Oxygen Carriers for Biomass Gasification," Energies, MDPI, vol. 13(8), pages 1-11, April.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:8:p:2019-:d:347409
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    References listed on IDEAS

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    2. Sansaniwal, S.K. & Pal, K. & Rosen, M.A. & Tyagi, S.K., 2017. "Recent advances in the development of biomass gasification technology: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 363-384.
    3. Siriwardane, Ranjani & Riley, Jarrett & Tian, Hanjing & Richards, George, 2016. "Chemical looping coal gasification with calcium ferrite and barium ferrite via solid–solid reactions," Applied Energy, Elsevier, vol. 165(C), pages 952-966.
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