IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v13y2020i8p2019-d347409.html
   My bibliography  Save this article

Comparison of Bimetallic Fe-Cu and Fe-Ca Oxygen Carriers for Biomass Gasification

Author

Listed:
  • Beatrice Muriungi

    (Department of Chemical, Biological, and Bioengineering, North Carolina Agricultural and Technical State University, 1601 East Market Street, Greensboro, NC 27411, USA)

  • Lijun Wang

    (Department of Chemical, Biological, and Bioengineering, North Carolina Agricultural and Technical State University, 1601 East Market Street, Greensboro, NC 27411, USA
    Department of Natural Resources and Environmental Design, North Carolina Agricultural and Technical State University, 1601 East Market Street, Greensboro, NC 27411, USA)

  • Abolghasem Shahbazi

    (Department of Chemical, Biological, and Bioengineering, North Carolina Agricultural and Technical State University, 1601 East Market Street, Greensboro, NC 27411, USA
    Department of Natural Resources and Environmental Design, North Carolina Agricultural and Technical State University, 1601 East Market Street, Greensboro, NC 27411, USA)

Abstract

Two bimetallic Fe-Cu and Fe-Ca oxygen carriers were studied for chemical looping gasification (CLG) of biomass. The SEM results indicated that there was no obvious agglomeration on the bimetallic Fe-Cu oxygen carrier supported on Al 2 O 3 and Fe-Ca oxygen carrier after five redox cycles while agglomeration occurred on CuO supported on Al 2 O 3 due to the low melting point of CuO. The XRD results indicated the presence of copper-ferrite and calcium-ferrite phases in the bimetallic materials. The two bimetallic oxygen carriers can be re-oxidized with air to form a crystalline that is similar to the fresh materials. The Fe-Ca oxide became active at 360 °C which was lower than 380 °C for the Fe-Cu oxygen carrier. The high thermal stability and redox reactivity of bimetallic Fe-Cu and Fe-Ca oxygen carriers make the bimetallic oxygen carriers more suitable for recycling during CLG. The method for preparing Fe-Cu oxygen carriers had no significant impact on biomass conversion efficiency but had significant effect on the quality of syngas. Proper control of the biomass/oxygen carrier mass ratio is critical to achieve high selectivity towards gasification instead of combustion. The Fe-Ca oxygen carrier could achieve higher selectivity towards gasification than the Fe-Cu oxygen carrier.

Suggested Citation

  • Beatrice Muriungi & Lijun Wang & Abolghasem Shahbazi, 2020. "Comparison of Bimetallic Fe-Cu and Fe-Ca Oxygen Carriers for Biomass Gasification," Energies, MDPI, vol. 13(8), pages 1-11, April.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:8:p:2019-:d:347409
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/13/8/2019/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/13/8/2019/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Nandy, Anirban & Loha, Chanchal & Gu, Sai & Sarkar, Pinaki & Karmakar, Malay K. & Chatterjee, Pradip K., 2016. "Present status and overview of Chemical Looping Combustion technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 597-619.
    2. Sansaniwal, S.K. & Pal, K. & Rosen, M.A. & Tyagi, S.K., 2017. "Recent advances in the development of biomass gasification technology: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 363-384.
    3. Siriwardane, Ranjani & Riley, Jarrett & Tian, Hanjing & Richards, George, 2016. "Chemical looping coal gasification with calcium ferrite and barium ferrite via solid–solid reactions," Applied Energy, Elsevier, vol. 165(C), pages 952-966.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Mohsen Fallah Vostakola & Babak Salamatinia & Bahman Amini Horri, 2022. "A Review on Recent Progress in the Integrated Green Hydrogen Production Processes," Energies, MDPI, vol. 15(3), pages 1-41, February.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, Jinzhi & He, Tao & Wang, Zhiqi & Zhu, Min & Zhang, Ke & Li, Bin & Wu, Jinhu, 2017. "The search of proper oxygen carriers for chemical looping partial oxidation of carbon," Applied Energy, Elsevier, vol. 190(C), pages 1119-1125.
    2. Wang, Haiming & Dou, Xiaomin & Veksha, Andrei & Liu, Wen & Giannis, Apostolos & Ge, Liya & Thye Lim, Teik & Lisak, Grzegorz, 2020. "Barium aluminate improved iron ore for the chemical looping combustion of syngas," Applied Energy, Elsevier, vol. 272(C).
    3. Ramos, Ana & Monteiro, Eliseu & Rouboa, Abel, 2019. "Numerical approaches and comprehensive models for gasification process: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 110(C), pages 188-206.
    4. Zhong, Hanbin & Xiong, Qingang & Yin, Lina & Zhang, Juntao & Zhu, Yuqin & Liang, Shengrong & Niu, Ben & Zhang, Xinyu, 2020. "CFD-based reduced-order modeling of fluidized-bed biomass fast pyrolysis using artificial neural network," Renewable Energy, Elsevier, vol. 152(C), pages 613-626.
    5. Du, Shilin & Shu, Rui & Guo, Feiqiang & Mao, Songbo & Bai, Jiaming & Qian, Lin & Xin, Chengyun, 2022. "Porous coal char-based catalyst from coal gangue and lignite with high metal contents in the catalytic cracking of biomass tar," Energy, Elsevier, vol. 249(C).
    6. Bassey, Uduak & Sarquah, Khadija & Hartmann, Michael & Tom, Abasi-ofon & Beck, Gesa & Antwi, Edward & Narra, Satyanarayana & Nelles, Michael, 2023. "Thermal treatment options for single-use, multilayered and composite waste plastics in Africa," Energy, Elsevier, vol. 270(C).
    7. Patrik Šuhaj & Jakub Husár & Juma Haydary, 2020. "Gasification of RDF and Its Components with Tire Pyrolysis Char as Tar-Cracking Catalyst," Sustainability, MDPI, vol. 12(16), pages 1-14, August.
    8. Teng, Su & Hamrang, Farzad & Ashraf Talesh, Seyed Saman, 2021. "Economic performance assessment of a novel combined power generation cycle," Energy, Elsevier, vol. 231(C).
    9. Kim, Jun Young & Kim, Dongjae & Li, Zezhong John & Dariva, Claudio & Cao, Yankai & Ellis, Naoko, 2023. "Predicting and optimizing syngas production from fluidized bed biomass gasifiers: A machine learning approach," Energy, Elsevier, vol. 263(PC).
    10. Rajabi, Mahsa & Mehrpooya, Mehdi & Haibo, Zhao & Huang, Zhen, 2019. "Chemical looping technology in CHP (combined heat and power) and CCHP (combined cooling heating and power) systems: A critical review," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    11. Lu, Xuao & Rahman, Ryad A. & Lu, Dennis Y. & Ridha, Firas N. & Duchesne, Marc A. & Tan, Yewen & Hughes, Robin W., 2016. "Pressurized chemical looping combustion with CO: Reduction reactivity and oxygen-transport capacity of ilmenite ore," Applied Energy, Elsevier, vol. 184(C), pages 132-139.
    12. Ren, Siyue & Feng, Xiao & Wang, Yufei, 2021. "Emergy evaluation of the integrated gasification combined cycle power generation systems with a carbon capture system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).
    13. Yin, Weijie & Wang, Shuai & Zhang, Kai & He, Yurong, 2020. "Numerical investigation of in situ gasification chemical looping combustion of biomass in a fluidized bed reactor," Renewable Energy, Elsevier, vol. 151(C), pages 216-225.
    14. Monteiro, Eliseu & Ismail, Tamer M. & Ramos, Ana & Abd El-Salam, M. & Brito, Paulo & Rouboa, Abel, 2018. "Experimental and modeling studies of Portuguese peach stone gasification on an autothermal bubbling fluidized bed pilot plant," Energy, Elsevier, vol. 142(C), pages 862-877.
    15. Cerciello, Francesca & Coppola, Antonio & Lacovig, Paolo & Senneca, Osvalda & Salatino, Piero, 2021. "Characterization of surface-oxides on char under periodically changing oxidation/desorption conditions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    16. Mariyam, Sabah & Shahbaz, Muhammad & Al-Ansari, Tareq & Mackey, Hamish. R & McKay, Gordon, 2022. "A critical review on co-gasification and co-pyrolysis for gas production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    17. Perkins, Greg & Bhaskar, Thallada & Konarova, Muxina, 2018. "Process development status of fast pyrolysis technologies for the manufacture of renewable transport fuels from biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 292-315.
    18. Moritz Wegener & Antonio Isalgué & Anders Malmquist & Andrew Martin, 2019. "3E-Analysis of a Bio-Solar CCHP System for the Andaman Islands, India—A Case Study," Energies, MDPI, vol. 12(6), pages 1-19, March.
    19. Andrius Tamošiūnas & Ajmia Chouchène & Pranas Valatkevičius & Dovilė Gimžauskaitė & Mindaugas Aikas & Rolandas Uscila & Makrem Ghorbel & Mejdi Jeguirim, 2017. "The Potential of Thermal Plasma Gasification of Olive Pomace Charcoal," Energies, MDPI, vol. 10(5), pages 1-14, May.
    20. Wang, Haiming & Liu, Guicai & Veksha, Andrei & Giannis, Apostolos & Lim, Teik-Thye & Lisak, Grzegorz, 2021. "Effective H2S control during chemical looping combustion by iron ore modified with alkaline earth metal oxides," Energy, Elsevier, vol. 218(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:13:y:2020:i:8:p:2019-:d:347409. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.